Polymer compositions and method of making pipes
View Patent ↗A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (“LTD”) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolyethylene or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same or different composition (i.e., with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described.
1. A polymer composition, comprising:
a) a low molecular weight polyethylene component, having a density of 0.940 to 0.978 g/cm 3 , a melt index (I 2 ) of >80 to about 1200 g/10 min, a molecular weight (M w ) from about 10,000 to 40,000 g/mole, a molecular weight distribution (M w /M n ) of less than 5, and a melt flow ratio (I 21 /I 2 ) of from about 10 to about 65; and co-crystallized with
b) a high molecular weight polyethylene component, having a density of 0.920 to 0.935 g/cm 3 , a melt flow index (I 21 ) of from about 1.0 to about 5.0 grams per 10 minutes, a molecular weight (M w ) ranging from about 100,000 to about 600,000 g/mole, a molecular weight distribution (M w /M n ) of less than 8, and a melt flow ratio (I 21 /I 2 ) of from about 20 to about 65,
wherein the polymer composition has a single peak in a lamellar thickness distribution curve and a pipe made from the polymer composition has a PENT value according to ASTM F1473 of greater than 9000 hours at 80° C. and 2.4 MPa and a rapid crack propagation (RCP)S4-value of −5 degrees C. or lower at 10 MPa, and
wherein the polymer composition has a density measured according to ASTM D-1505 of 0.940 g/cm 3 or greater and a molecular weight ranging from 200,000 to 350,000 g/mol, a melt index (I 5 ) of from about 0.01 to about 2.0 g/10 m, a flow index (I 21 ) of from about 2 to about 50 g/10 m, a melt flow ratio (I 21 /I 5 ) of from about 10 to about 50, a molecular weight distribution (M w /M n ) ranging from about 18 to about 32, where I 5 is determined according to ASTM D-1238, Condition 190° C./5 kg and I 21 is determined according to ASTM D-1238, Condition 190° C./21.6 kg.
2. The composition of claim 1 , wherein the high molecular weight polyethylene component includes a comonomer selected from the group consisting of C 4 to C 10 olefins.
3. The composition of claim 2 , wherein the comonomer content ranges from greater than 0 to about 40%.
4. The composition of claim 1 , wherein the low molecular weight polyethylene component includes a comonomer selected from the group consisting of C 4 to C 10 olefins.
5. The composition of claim 4 , wherein comonomer content ranges from greater than 0 to about 30%.
6. The composition of claim 1 , wherein the polymer composition is bimodal.
7. The composition of claim 1 , wherein the high molecular weight polyethylene component comprises from about 48 to about 67 percent by weight of the combined weight of the high molecular weight component and the low molecular weight polyethylene component in the polymer composition.
8. The composition of claim 1 , wherein the low molecular weight component comprises from about 33 to about 52 percent by weight of the combined weight of the high molecular weight component and the low molecular weight polyethylene component in the polymer composition.
9. The composition of claim 1 , wherein the composition has
1) a melt flow index (I 5 ) of from about 0.2 to about 1.5 g/10 m;
2) a molecular weight distribution, M w /M n , of from about 15 to about 40; and
wherein the high molecular weight polyethylene component comprises from about 30 to about 70 wt. percent of the composition; has a melt flow index (I 2 ) of from about 0.01 to about 0.2 g/10 min; and a melt flow ratio (I 21 /I 2 ) of from about 20 to about 65; and
wherein the low molecular weight polyethylene component comprises from about 30 to about 70 wt. percent of the composition; has a melt index (I 2 ) of from about 40 to about 2000 g/10 min; and has a melt flow ratio (I 21 /I 2 ) of from about 10 to about 65.