Fire-protection coating
The invention relates to a fire-protection coating which forms an insulating layer, which comprises a flame retardant mixture which comprises a phosphorus/nitrogen flame retardant and comprises a phosphinic salt of the formula (I) and/or comprises a diphosphinic salt of the formula (II) and/or comprises polymers of these, where R 1 , R 2 are identical or different and are C 1 -C 6 -alkyl, linear or branched, and/or aryl; R 3 is C 1 -C 10 -alkylene, linear or branched, C 6 -C 10 -arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4 and x is from 1 to 4.
1 . A fire-protection coating which forms an insulating layer, comprising a flame retardant mixture wherein the flame retardant mixture includes a phosphorus/nitrogen flame retardant and a phosphinic salt of the formula (I) a diphosphinic salt of the formula (II) a polymer of the phosphinic salt, a polymer of the diphosphinic salt, or a mixture thereof,
wherein
R 1 , R 2 are identical or different and are C 1 -C 6 -alkyl, linear or branched, or aryl;
R 3 is C 1 -C 10 -alkylene, linear or branched, C 6 -C 10 -arylene, -alkylarylene or -arylalkylene;
M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K or a protonated nitrogen base;
m is from 1 to 4; n is from 1 to 4 and x is from 1 to 4.
2 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein the phosphorus/nitrogen flame retardant is a nitrogen-containing phosphate of the formulae (NH4)y H3-y PO 4 or (NH4 PO3)z, where y is from 1 to 3 and z is from 1 to 10 000.
3 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein the phosphorus/nitrogen flame retardant is ammonium hydrogenphosphate, ammonium dihydrogenphosphate, ammonium polyphosphate, or a mixture thereof.
4 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein the phosphorus/nitrogen flame retardant is an ammonium polyphosphate of the formula (NH 4 PO 3 ) n , where n is a number from 10 to ≦1000.
5 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein the phosphorus/nitrogen flame retardant is the reaction products of melamine with phosphoric acid or condensed phosphoric acids, the reaction products of condensates of melamine with phosphoric acid or with condensed phosphoric acids, or a mixture of thereof.
6 . The fire-protection coating which forms an insulating layer, as claimed in claim 5 , wherein the phosphorus/nitrogen flame retardant is melam, melem, melon, dimelamine phosphate, dimelamine pyrophosphate, melamine phosphate, melamine pyrophosphate, melamine polyphosphate, melam polyphosphate, melon polyphosphate, melem polyphosphate, mixed polysalts thereof or mixtures thereof.
7 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein the ratio, by weight, of the phosphorus/nitrogen flame retardant to the phosphinic salt of the formula (I), the diphosphinic salt of the formula (II), the polymer of the phosphinic salt, the polymer of the diphosphinic salt or mixtures thereof is from 0.1 to 100 to 100 to 0.1.
8 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein the ratio, by weight, of the phosphorus/nitrogen flame retardant to the phosphinic salt of the formula (I), the diphosphinic salt of the formula (II), the polymer of the phosphinic salt, the polymer of the diphosphinic salt or mixtures thereof is from 1 to 50 to 50 to 1.
9 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 comprising:
A) from 1 to 99% by weight of an epoxy resin,
B) from 1 to 99% by weight of the flame retardant mixture, and
C) from 0 to 60% by weight of an additive.
10 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , comprising:
A) from 10 to 90% by weight of an epoxy resin,
B) from 2 to 60% by weight of a the flame retardant mixture, and
C) from 3 to 45% by weight of an additive.
11 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , comprising
A) from 30 to 85% by weight of an epoxy resin,
B) from 3 to 50% by weight of the flame retardant mixture, and
C) from 5 to 40% by weight of an additive.
12 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , further comprising from 0 to 60% by weight of at least one additive selected from the group consisting of accelerators, fillers, auxiliaries, blowing agents, nitrogen synergists, carbon donors, pigments, flexibilizers, reactive diluents and mixtures thereof.
13 . (canceled)
14 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein M is calcium, aluminum, or zinc.
15 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein R 1 and R 2 are identical or different and are methyl, ethyl, n-propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, or phenyl.
16 . The fire-protection coating which forms an insulating layer, as claimed in claim 1 , wherein R 3 is methylene, ethylene, n-propylene, isopropylene, n-butylene, tert-butylene, n-pentylene, n-octylene, n-dodecylene; phenylene, naphthylene; methylphenylene, ethylphenylene, tert-butylphenylene, methylnaphthylene, ethylnaphthylene, tert-butylnaphthylene; phenylmethylene, phenylethylene, phenylpropylene, or phenylbutylene.
17 . The fire-protection coating which forms an insulating layer, as claimed in claim 4 , wherein n is a number from 200 to ≦1000.
18 . A substrate coated with the fire-protection coating which forms an insulating layer, as claimed in claim 1 .
19 . The substrate as claimed in claimed 18, wherein the substrate is a floorcovering, molding, wall, load-bearing metallic structure or a non-load-bearing metallic structure.