Coating compositions having improved stability
View Patent ↗This invention relates to waterbone coating compositions having improved compatability with metal pigments, i.e., improved shelf life and reduced gassing and gellation. The composition comprise at least one aqueous dispersion of (1) at least one emulsion copolymer polymerized from (a) at least one ethylenically unsaturated anionic monomer and (b) at least one other olefinically unsaturated monomer, said copolymer being made using at least one phosphate surfactant having at least one phosphorus acid group or salt thereof, said copolymer being crosslinked, and (2) at least one non-water soluble metal pigment. The compositions are useful in paints and other coatings.
1. A composition comprising:
An aqueous dispersion of (1) at least one emulsion copolymer polymerized from (a) at least one ethylenically unsaturated anionic monomer and (b) at least one other olefinically unsaturated monomer, said monomers being polymerized in the presence of at least one phosphate ester surfactant having at least one phosphate group or salt thereof, said copolymer optionally being crosslinked, and (2) at least one non-water soluble metal pigment.
2. A composition of according to claim 1 , wherein said ethylenically unsaturated anionic monomer is selected from include acrylic acid, methacrylic acid, crotonic acid, itaconic acid, furnaric acid, maleic acid, rnonomethyl itaconate, monomethyl fumarate, monobutyl fumarate, maleic anhydride, 2-acrylamido-2-methyl- 1 -propanesulfonic acid, sodium salt of 2-acrylamnido-2-methyl-1-propanesulfonic acid, ammonium salt of 2-aciylamnido- 2-methyl-1-propanesulfonic acid, sodium vinyl sulfonate, sodium salt of allyl ether sulfonate, phosphoethyl methacrylate, vinyl phosphonic acid, allyl phosphonic acid; and salts thereof; and mixtures thereof.
3. A composition according to claim 1 , wherein said other olefinically unsaturated monomer is selected from alkyl acrylates or mnethacrylates having from 1 to 10 carbon atoms in the alkyl moiety, glycidyl methacrylate, glycol mono- or diacrylates, glycol mono and dimnethacrylates, aromatic vinyl compounds, vinyl halides, vinylidene chloride, C 1 -C 12 vinyl esters, vinyl pyridine, N-vinyl pyrrolidone, N,N′-dimethylamino (meth)acrylate, chloroprene, acrylonitrile, methacrylonitrile; ethylenically unsaturated monomers having amine-reactive, carbonyl-functional groups; allyl-, vinyl-, and crotyl- esters of acrylic, methacrylic, maleic, and fumnaric acids, di- and tri-(mneth)acrylates, divinylbenzene, diallylphthalate, triallylcyanurate, polyvinyl ethers of glycols, glycerols; and mixtures thereof.
4. A composition according to claim 1 , wherein said phosphate ester surfactant is selected from mono- and di- phosphate esters of nonyl phenol ethoxylates, phosphate esters of tridecyl alcohol ethoxylates, phosphate esters of isodecyl alcohol ethoxylates, phosphate esters of aromatic ethoxylates, phosphate esters aliphatic ethoxylates, phosphate esters of C 10 −C 16 alkyl ethoxylates/propoxylates; and mixtures thereof.
5. A composition according to claim 1 , wherein said non-water soluble metal pigments are selected from aluminum, zinc, silver, copper, and alloys thereof.
6. A composition according to clalin 5 , wherein said metallic pigment is in flake or powder form.
7. A composition according to claim 6 , wherein said pigment is aluminum flake.
8. A composition according to claim 3 , wherein said olefinically unsaturated monomer is selected from diacetone acrylamide, (meth)acryloxyalkyl benzophenone, (meth)acrolein, crotonaldehyde, 2-butanone(meth)acrylate, vinyl acetoacetate, acetoacetoxyethyl (meth)acrylate, acetoacetoxypropyl (meth)acrylate, allyl acetoacetate, acetoacetoxybutyl (meth)acrylate, 2,3 -di(acetoacetoxy)propyl (meth)acmylate, vinyl acetoacetamide, acetoacetoxyethyl (meth)acrylarnide; and mixtures thereof.
9. A composition according to claim 8 , wherein said at least one emulsion copolymer is crosslinked with a nitrogen-containing crosslinking agent having at least two amine nitrogens.
10. A composition according to claim 9 , wherein said crosslinking agent is selected from ethylenediamine, propylenediamine, tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, piperazine, anminoethylpiperazine, diethylenetriamine, triethylenetetrainine, tetraethylenepentamine, cyclohexyldiamine, isopheronediamine, triaminoethylamine, diaminoethanolamine, phenylenediarnine, biphenyldiamine, hydrazine, aliphatic dihydrazines having from 2 to 4 carbon atoms, alkylene dioxime ethers, and water soluble dihydrazides of dicarboxylic acids.
11. A composition according to claim 1 , further comprising co-solvents, pigments, fillers, dispersants, wetting agents, anti-foam agents, rheology modifiers, pH control agents, UV absorbers, antioxidants, biocides, stabilizers; and mixtures thereof.
12. A method for making a pigmented aqueous dispersion comprising:
(a) providing an emulsion copolymer polymerized from (i) at least one ethylenically unsaturated anionic monomer and (ii) at least one other olefinically unsaturated monomer in the presence of at least one phosphate ester surfactant having at least one phosphate group or salt thereof; and
(b) combining said copolymner with at least one non-water soluble metal pigment.
13. A method according to claim 12 , wherein said ethylenically unsaturated anionic monomer is selected from include acmylic acid, methacrylic acid, crotonic acid, itaconic acid, fumaric acid, maleic acid, monomethyl itaconate, monomethyl fumarate, monobutyl fumarate, maleic anhydride, 2-acrylamido-2-methyl-1-propanesulfonic acid, sodium salt of 2-acrylamido-2-methyl-1-propanesulfonic acid, ammonium salt of 2-acrylamido-2-methyl-1-propanesulfonic acid, sodium vinyl sulfonate, sodium salt of allyl ether sulfonate, phosphoethyl methacrylate, vinyl phosphonic acid, allyl phosphonic acid; and salts thereof and mixtures thereof.
14. A mnethod according to claim 12 , wherein said other olefinically unsaturated monomer is selected from alkyl acrylates or methacrylates having from 1 to 10 carbon atoms in the alkyl moiety, glycidyl methacrylate, glycol mono- or diacrylates, glycol mono and dimethacrylates, aromatic vinyl compounds, vinyl halides, vinylidene chloride, C 1 −C 12 vinyl esters, vinyl pyridine, N-vinyl pyrrolidone, N,N′-dimethylamino (meth)acrylate, chloroprene, acrylonitrile, methacrylonitrile; ethylenically unsaturated monomers having amine-reactive, carbonyl-functional groups; allyl-, vinyl-, and crotyl- esters of acrylic, methacrylic, maleic, and fumaric acids, di- and tri-(meth)acrylates, divinylbenzene, diallylphthalate, triallylcyanurate, polyvinyl ethers of glycols, glycerols; and mixtures thereof.
15. A method according to claim 12 , wherein said phosphate ester surfactant is selected from mono- and di- phosphate esters of nonyl phenol ethoxylates, phosphate esters of tridecyl alcohol ethoxylates, phosphate esters of isodecyl alcohol ethoxylates, phosphate esters of aromatic ethoxylates, phosphate esters aliphatic ethoxylates, phosphate esters of C 10 −C 16 alkyl ethoxylates/propoxylates; and mixtures thereof.
16. A method according to claim 12 , wherein said non-water soluble metal pigments are selected from aluminum, zinc, silver, copper, and alloys thereof.
17. A method according to claim 16 , wherein said metallic pigment is in flake or powder form.
18. A method according to claim 17 , wherein said pigment is aluminum flake.
19. A method according to claim 12 , wherein said copolymer is crosslinked.