IP Library Granted Patent US 7,845,351
Granted Patent B2
US 7,845,351 · App. 11/215,986 · Granted Dec 7, 2010

Germicidal face mask

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Quick Facts
Patent No.
US 7,845,351
App. No.
11/215,986
Granted
Dec 7, 2010
Kind
B2
Abstract

A face mask for reducing the amount of microbes to which a wearer is exposed is provided. The face mask includes a body portion that has an outer layer that has been treated with a germicidal agent in an effective amount. The layer may be a nonwoven fabric like a spunbond, meltblown or coform layer and may be a laminate of such layers. The face mask having such a germicidal treatment can result in a reduction in microbial activity as compared to another face mask, identical but for the germicidal agent.

Claims (16)

1. A face mask comprising:

a fastening member for attaching a body portion of the face mask to the users; and

a body portion joined to the fastening member and configured to be placed over a mouth and at least part of a nose of a user in such that respiration air is drawn through said body portion,

the body portion comprising a plurality of layers with at least an outermost layer having a germicidal agent comprising polyhexamethylene biguanide, citric acid and N-alkyl polyglycoside and wherein the germicidal agent containing layers of the body portion have a percent solids add-on of polyhexamethylene biguanide between 0.01 and 20 weight percent, a percent solids add-on of citric acid between 0.01 and 10 weight percent; and a percent solids add-on of N-alkyl polyglycoside between 0.01 and 10 weight percent.

2. The face mask as set forth in claim 1 , wherein the germicidal agent on the body portion of the face mask further includes at least one additional ingredient selected from quaternary ammonium compounds, quaternary ammonium siloxanes, polyquaternary amines, metal-containing species and oxides thereof, halogens, halogen-releasing agents, halogen-containing polymers, bromo-compounds, chlorine dioxides, thiazoles, thiocynates, isothiazolins, cyanobutanes, dithiocarbamates, thiones, alkylsulfosuccinates, alkyl-amino-alkyl glycines, dialkyl-dimethyl-phosphonium salts, cetrimides, hydrogen peroxide, 1-alkyl-1,5-diazapentane, cetyl pyridinium chloride, stabilized oxidants, stabilized peroxides, sulfides, bis-phenols, polyphenols, chitosan, anatase TiO 2 , tourmaline, bamboo extract, neem oil, hydrotropes, chaotropic agents and combinations thereof.

3. The face mask as set forth in claim 1 , wherein at least the body portion of the face mask is treated with said germicidal agent by the method selected from the group consisting of dipping and squeezing, spraying, ink jet printing and combinations thereof.

4. The face mask as set forth in claim 1 , wherein the outermost layer comprises a nonwoven web.

5. The face mask as set forth in claim 4 , wherein said nonwoven web is selected from the group consisting of spunbond webs and wet laid polyester webs.

6. The face mask of claim 1 wherein the germicidal agent on the body portion of the face mask further includes an ingredient selected from chitosan glycolate, octadecylaminodimethyl trimethoxysilylpropyl ammonium chloride, PG-hydroxyethylcellulose cocodimonium chloride, xylitol, benzoic acid, salycilic acid, acetic acid, glutaric acid, iodine, ethyl hydroxyethyl cellulose, polyvinyl pyrrolidone, poly(vinyl pyrrolidone-co-vinyl acetate), polyvinyl pyrrolidone-Iodine complex, guanidine hydrochloride and sorbitol, acrylic co-polymer compound and isopropyl alcohol, copper oxide, silver sodium hydrogen zirconium phosphate, silver zinc glass, barium sulfate and combinations thereof.

7. The face mask of claim 1 wherein said mask has a particle filtration efficiency as measured by ASTM F-2299 greater than 85%, a bacteria filtration efficiency as measured by ASTM F-2101 greater than 85%, and a differential pressure drop as measured by ASTM F-2101 less than 8 mm water/square cm.

8. The mask of claim 1 wherein said mask exhibits a 3 log 10 reduction of microbes on the surface of said mask when said mask is insulted with an innoculum selected from the group consisting of MRSA Staphylococcus aureus (ATCC#33591), VRE Enterococcus faecalis (ATCC#51299), Moraxella catarrhalis (ATCC #8176), Klebsiella pneumoniae (ATCC#4352), Candida albicans (ATCC#10231), Rhinovirus 1A (ATCC# VR-1364), Influenza A (ATCC# VR-1469) within 30 minutes of contact with said mask.

9. The face mask of claim 1 wherein said mask exhibits a 3 log 10 reduction in contact transfer of an innoculum selected from the group consisting of MRSA Staphylococcus aureus (ATCC#33591), VRE Enterococcus faecalis (ATCC#51299), Moraxella catarrhalis (ATCC #8176), Klebsiella pneumoniae (ATCC#4352), Candida albicans (ATCC#10231), Rhinovirus 1A (ATCC# VR-1364), Influenza A (ATCC# VR-1469) within 30 minutes of contact with said mask.

10. A face mask comprising:

a fastening member for attaching a body portion of the face mask to the users; and

a body portion joined to the fastening member and configured to be placed over a mouth and at least part of a nose of a user in such that respiration air is drawn through said body portion, the body portion comprising a plurality of layers with at least an outermost layer being a polyolefin nonwoven web having a germicidal agent comprising polyhexamethylene biguanide, citric acid and N-alkyl polyglycoside and wherein the germicidal agent containing layers of the body portion have a percent solids add-on of polyhexamethylene biguanide between 0.01 and 20 weight percent, percent solids add-on of citric acid between 0.01 and 10 weight percent; and a percent solids add-on of N-alkyl polyglocoside a between 0.01 and 10 weight percent.

11. The face mask of claim 10 , wherein the polyolefin nonwoven web is a spunbonded nonwoven web made from a polyolefin selected from polyethylene and polypropylene.

Assignments (15)
SECURITY INTEREST Recorded May 19, 2026
From: O&M HALYARD, INC.; MEDICAL ACTION INDUSTRIES INC.; OWENS & MINOR DISTRIBUTION, INC.
To: PLC AGENT LLC
Reel/Frame 075647/0354 →
RELEASE OF SECURITY INTEREST Recorded Jan 6, 2026
From: BANK OF AMERICA, N.A.
To: MEDICAL ACTION INDUSTRIES INC.; O&M HALYARD, INC.; OWENS & MINOR DISTRIBUTION, INC.
Reel/Frame 074203/0026 →
RELEASE OF SECURITY INTEREST Recorded Jan 6, 2026
From: JPMORGAN CHASE BANK, N.A.
To: O&M HALYARD, INC.; OWENS & MINOR DISTRIBUTION, INC.
Reel/Frame 074212/0570 →
SECURITY AGREEMENT (ABL) Recorded Dec 31, 2025
From: MEDICAL ACTION INDUSTRIES INC.; O&M HALYARD, INC.; OWENS & MINOR MEDICAL, LLC
To: BANK OF AMERICA, N.A., AS LEAD COLLATERAL AGENT; PNC BANK, NATIONAL ASSOCIATION, AS CO-COLLATERAL AGENT; WELLS FARGO BANK, NATIONAL ASSOCIATION, AS CO-COLLATERAL AGENT
Reel/Frame 074161/0401 →
RELEASE OF SECURITY INTEREST Recorded Jun 30, 2022
From: CITIBANK, N.A.
To: AVENT, INC.; AVANOS MEDICAL SALES, LLC
Reel/Frame 060557/0062 →
PATENT SECURITY AGREEMENT Recorded Mar 29, 2022
From: O&M HALYARD, INC.; OWENS & MINOR DISTRIBUTION, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 059541/0024 →
PATENT SECURITY AGREEMENT Recorded Mar 12, 2021
From: MEDICAL ACTION INDUSTRIES INC.; OWENS & MINOR DISTRIBUTION, INC.; O&M HALYARD, INC.
To: BANK OF AMERICA, N.A.
Reel/Frame 055582/0407 →
RELEASE OF SECURITY INTEREST Recorded Mar 12, 2021
From: BANK OF AMERICA, N.A.
To: OWENS & MINOR DISTRIBUTION, INC.; MEDICAL ACTION INDUSTRIES, INC.; O&M HALYARD, INC.
Reel/Frame 055583/0722 →
INTELLECTUAL PROPERTY SECURITY INTEREST ASSIGNMENT AGREEMENT Recorded Jan 23, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: CITIBANK, N.A.
Reel/Frame 048173/0137 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2018
From: AVENT, INC.
To: O&M HALYARD, INC.
Reel/Frame 046324/0227 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded May 8, 2018
From: O&M HALYARD, INC.
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 046100/0646 →
RELEASE OF SECURITY INTEREST Recorded May 1, 2018
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: AVENT, INC.
Reel/Frame 046476/0710 →
SECURITY INTEREST Recorded Apr 6, 2015
From: AVENT, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 035375/0867 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 13, 2015
From: KIMBERLY-CLARK WORLDWIDE, INC.
To: AVENT, INC.
Reel/Frame 034753/0360 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 15, 2005
From: MATHIS, MICHAEL P.; BOWEN, JR., UYLES W.; STEINDORF, ERIC C.; SCHORR, PHILLIP A.; DOBSON, ANGELA; YAHIAOUI, ALI; HOFFMAN, DOUGLAS R.; KOENIG, DAVID; SPENCER, ANTHONY STEVE
To: KIMBERLY-CLARK WORLDWIDE, INC.
Reel/Frame 017018/0577 →