Method for production of high solids silicone resin coating solution
View Patent ↗An improved method for concentrating solids in silicone resin coating compositions is provided, said compositions comprising higher solids levels that are often needed in order to increase the thickness of the final coated film when applied to a given substrate.
1. A method for increasing the concentration of solids in silicone resin coating composition comprising:
(a) extracting a solution of silicone resin containing an initial concentration of resin solids with an aqueous extractant to provide an upper aqueous layer and a lower layer containing silicone resin solids, the concentration of solids in the lower layer being greater than the initial concentration of the solution of silicone resin prior to extraction; and
(b) separating the lower layer from the upper layer,
wherein the concentration of solids is obtained in the substantial absence of added heat and/or vacuum.
2. The method of claim 1 , wherein the aqueous extractant comprises water, and optionally at least one water soluble solvent.
3. The method of claim 2 , wherein the water soluble solvent is selected from the group consisting of aliphatic alcohols having from about 1 to about 6 carbon atoms, glycol mono-ethers, acids, and mixtures thereof.
4. The method of claim 2 , wherein the water soluble solvent is selected from the group consisting of aliphatic alcohols having from about 3 to about 6 carbon atoms.
5. The method of claim 4 , wherein the aliphatic alcohol is selected from the group consisting of methanol, ethanol, n-propanol, iso-propanol, n-butanol, sec-butanol, and tertiary butanol, and mixture thereof.
6. The method of claim 5 , wherein the alcohol is selected from the group consisting of iso-propanol, n-butanol, iso-butanol, and 2-methyl-2-butanol and mixture thereof.
7. The method of claim 3 , wherein the mono-ether is selected from the group consisting of ethylene glycol monoethylether, ethylene glycol monobutylether, diethylene glycol monoethylether, methoxypropanol, and mixtures thereof.
8. The method of claim 3 , wherein the acid is selected from the group consisting of hydrochloric, phosphoric, carboxylic acids, sulfonic acids, and mixture thereof.
9. The method of claim 8 , wherein the acid is acetic acid.
10. The method of claim 2 , wherein the aqueous extractant comprises from about 80 to about 100 weight percent water.
11. The method of claim 10 , wherein the aqueous extractant comprises 100 weight percent water.
12. The method of claim 2 , wherein the aqueous extractant comprises from about 0 to about 20 weight percent water soluble solvent.
13. The method of claim 12 , wherein the aqueous extractant comprises from about 0 to about 10 weight percent water soluble solvent.
14. The method of claim 2 , wherein the aqueous extractant comprises from about 0 to about 5 weight percent acid.
15. The method of claim 1 , wherein the weight ratio of aqueous extractant is from about 0.34 parts to about 1.98 parts to each part of the solution of silicone resin.
16. The method of claim 1 , wherein the ratio of aqueous extractant to solution of silicone resin is about 1 to 1.
17. The method of claim 1 wherein the solution of silicone resin has a pH in the range of from about 3.5 to about 7.0.
18. The method of claim 1 , wherein the solution of silicone resin has a pH in the range of from about 4.5 to about 6.5.
19. The method of claim 1 , wherein the solution of silicone resin has a pH of about 4.5.
20. The method of claim 1 , wherein the aqueous extractant has a pH in the range of from about 3.5 to about 7.0.
21. The method of claim 1 , wherein the aqueous extractant has a pH in the range of from about 4.5 to about 6.5.
22. The method of claim 1 , wherein the aqueous extractant has a pH of about 4.5.
23. The method of claim 1 , wherein the lower layer containing silicone resin comprises from about 40 to about 70 weight percent solids.
24. The method of claim 1 , wherein the lower layer containing silicone resin comprises about 60 weight percent solids.
25. The method of claim 1 , wherein the silicone resin coating composition of the lower layer has a shelf life of at least 4 weeks at ambient temperatures.
26. The method of claim 1 , wherein the initial solution of silicone resin prior to extraction has a T 3 :T 2 ratio greater than about 0.5.
27. The method of claim 26 , wherein the initial solution resin prior to extraction has a T 3 :T 2 ratio of about 0.52 to about 1.70.
28. The method of claim 1 , wherein the lower layer containing silicone resin is diluted with a polar organic solvent prior to application to a substrate.