Process for producing fine particles of bismuth titanate
View Patent ↗It is an object to provide fine particles of bismuth titanate having excellent dielectric characteristics, high crystallinity and a small particle diameter, and a process for their production. The object is accomplished by a process which comprises a step of obtaining a melt comprising, as represented by mol % based on oxides, from 23 to 72% of Bi 2 O 3 , from 4 to 64% of TiO 2 and from 6 to 50% of B 2 O 3 , a step of quickly quenching this melt to obtain an amorphous material, a step of crystallization of bismuth titanate crystals from the above amorphous material, and a step of separating the bismuth titanate crystals from the obtained crystallized material, in this order.
1. A process for producing fine particles of bismuth titanate, which comprises a step of obtaining a melt comprising, as represented by mol % based on oxides, from 23 to 72% of Bi 2 O 3 , from 4 to 64% of TiO 2 and from 6 to 50% of B 2 O 3 , a step of quickly cooling this melt to obtain an amorphous material, a step of crystallization of bismuth titanate crystals from the above amorphous material, and a step of separating the bismuth titanate crystals from the obtained crystallized material, in this order.
2. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the melt is quickly quenched to obtain a flaky or fibrous amorphous material.
3. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the step of crystallization of bismuth titanate crystals from the amorphous material, is carried out from 500 to 700° C.
4. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the compositional formula of the bismuth titanate crystals is at least one type selected from Bi 8 TiO 14 , Bi 4 Ti 3 O 12 , Bi 2 Ti 2 O 7 and Bi 2 Ti 4 O 11 .
5. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the shape of the bismuth titanate crystals is a plate-shape or a needle-shape.
6. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the step of separating the bismuth titanate crystals is carried out by using an acid or water.
7. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the average particle diameter of the fine particles of bismuth titanate is from 5 to 1,000 nm.
8. The process for producing fine particles of bismuth titanate according to claim 1 , wherein the average particle diameter of the fine particles of bismuth titanate is from 10 to 200 nm.
9. Fine particles of bismuth titanate, characterized in that they have at least one compositional formula selected from the group consisting of Bi 8 TiO 14 , Bi 4 Ti 3 O 12 , Bi 2 Ti 2 O 7 and Bi 2 Ti 4 O 11 , and they have an average particle diameter of from 5 to 1,000 nm and an aspect ratio of at least 2.
10. The process for producing fine particles of bismuth titanate according to claim 9 , wherein the average particle diameter of the fine particles of bismuth titanate is from 10 to 200 nm.