Organic electroluminescent element including blue phosphorescent luminescent material
View Patent ↗The present invention provides an organic electroluminescent element that includes a pair of electrodes and a plurality of organic compound layers being disposed between the pair of electrodes. The organic compound layers include a luminescent layer containing a blue phosphorescent luminescent material and a host material having the lowest excited triplet energy (T 1 ) of 272 kJ/mol (65 kcal/mol) or more, and hole transport layers. One of the hole transport layers is a layer adjacent to the luminescent layer, and when the ionization potentials of the luminescent layer, the hole transport layer adjacent to the luminescent layer, and another of the hole transport layers, respectively, designated to Ip 1 , Ip 2 and Ip 3 , the relationship Ip 1 >Ip 2 >Ip 3 is satisfied.
1. An organic electroluminescent element comprising:
a pair of electrodes, and
a plurality of organic compound layers being disposed between the pair of electrodes and which include a luminescent layer containing a blue phosphorescent luminescent material and only one kind of host material having the lowest excited triplet energy (T 1 ) of 272 kJ/mol (65 kcal/mol) or more, hole transport layers, and electron transport layers,
wherein one of the hole transport layers is a layer adjacent to the luminescent layer, and when the ionization potentials of the luminescent layer, the hole transport layer adjacent to the luminescent layer, and another of the hole transport layers, respectively, are designated to Ip 1 , Ip 2 and Ip 3 , the relationship Ip 1 >Ip 2 >Ip 3 is satisfied,
wherein Ip 2 is in the range of 6.0 to 5.5 eV,
wherein one of the electron transport layers is a layer adjacent to the luminescent layer, and when the electron affinities of the luminescent layer, the electron transport layer adjacent to the luminescent layer, and another of the electron transport layers, respectively, are designated to Ea 1 , Ea 2 and Ea 3 , the relationship Ea 1 <Ea 2 <Ea 3 is satisfied, and the lowest excited triplet energy T 1 ) of the electron transport layer adjacent to the luminescent layer is 272kJ/mol (65kcal/mol) or more, and
wherein the Ea 1 is 2.1 eV or more, the Ea 2 is in the range of 2.2 to 3.1 eV, and the Ea 3 is 2.6 eV or more.
2. The organic electroluminescent element of claim 1 , wherein the lowest excited triplet energy (T 1 ) of the hole transport layer adjacent to the luminescent layer is 272 kJ/mol (65 kcal/mol) or more.
3. The organic electroluminescent element of claim 1 , wherein the Ip 1 is 6.4 eV or less and the Ip 3 is 5.8 eV or less.
4. An organic electroluminescent element comprising:
a pair of electrodes, and
a plurality of organic compound layers being disposed between the electrodes and which include a luminescent layer containing a blue phosphorescent luminescent material and only one kind of host material having the lowest excited triplet energy (T 1 ) of 272 kJ/mol (65 kcal/mol) or more, and electron transport layers,
wherein one of the electron transport layer is a layer adjacent to the luminescent layer, and when the electron affinities of the luminescent layer, the electron transport layer adjacent to the luminescent layer, and another of the electron transport layers, respectively, are designated to Ea 1 , Ea 2 and Ea 3 , the relationship Ea 1 <Ea 2 <Ea 3 is satisfied, and the lowest excited triplet energy (T 1 ) of the electron transport layer adjacent to the luminescent layer is 272 kJ/mol (65 kcal/mol) or more, and
wherein the Ea 1 is 2.1 eV or more, the Ea 2 is in the range of 2.2 to 3.1 eV and the Ea 3 is 2.6 eV or more.
5. The organic electroluminescent element of claim 1 , wherein the Ip 1 is 6.4 eV or less, the Ip 2 is in the range of 6.2 to 5.3 eV, and the Ip 3 is 5.8 eV or less.
6. The organic electroluminescent element of claim 1 , wherein
the plurality of organic compound layers include the luminescent layer comprising first and second luminescent layers each containing a blue phosphorescent luminescent material and only one kind of host material having the lowest excited triplet energy (T 1 ) of 272 kJ/mol (65 kcal/mol) or more, hole transport layers, and electron transport layers,
one of the hole transport layers is a layer adjacent to the first luminescent layer, one of the electron transport is a layer adjacent to the second luminescent layer, the first and second luminescent layers each contain a host material different from each other, and
when the ionization potentials of the first luminescent layer, the hole transport layer adjacent to the first luminescent layer, and another of the hole transport layers, respectively, are designated to Ip 1 , Ip 2 and Ip 3 , and when the electron affinities of the second luminescent layer, the electron transport layer adjacent to the second luminescent layer, and another of the electron transport layers, respectively, are designated to Ea 1 , Ea 2 and Ea 3 , the relationships Ip 1 >Ip 2 >Ip 3 and Ea 1 <Ea 2 <Ea 3 are satisfied.
7. The organic electroluminescent element of claim 6 , wherein both the lowest excited triplet energies (T 1 ) of the electron transport layer adjacent to the second luminescent layer and the hole transport layer adjacent to the first luminescent layer are 272 kJ/mol (65 kcal/mol) or more.
8. The organic electroluminescent element of claim 6 , wherein the Ip 1 is 6.4 eV or less, the Ip 2 is in the range of 6.2 to 5.3 eV, and the Ip 3 is 5.8 eV or less.
9. The organic electroluminescent element of claim 6 , wherein the Ea 1 is 2.1 eV or more, the Ea 2 is in the range of 2.2 to 3.1 eV, and the Ea 3 is 2.6 eV or more.
10. The organic electroluminescent element of claim 6 , wherein the Ip 1 is 6.4 eV or less, the Ip 2 is in the range of 6.2 to 5.3 eV, the Ip 3 is 5.8 eV or less, the Ea 1 is 2.1 eV or more, the Ea 2 is in the range of 2.2 to 3.1 eV, and the Ea 3 is 2.6 eV or more.
11. The organic electroluminescent element of claim 1 , wherein the Ip 1 is 6.3 eV or less, the Ip 2 is in the range of 6.1 to 5.4 eV and the Ip 3 is 5.7 eV or less.
12. The organic electroluminescent element of claim 1 , wherein the lowest excited triplet energy (T 1 ) of the only one kind of host material is 276 kJ/mol (66 kcal/mol) or more.
13. The organic electroluminescent element of claim 1 , wherein the lowest excited triplet energy (T 1 ) of the hole transporting layer adjacent to the luminescent layer is 276 kJ/mol (66 kcal/mol) or more.
14. The organic electroluminescent element of claim 1 , wherein the lowest excited triplet energy (T 1 ) of the electron transporting layer adjacent to the luminescent layer is 276 kJ/mol (66 kcal/mol) or more.
15. The organic electroluminescent element of claim 4 , wherein the lowest excited triplet energy (T 1 ) of the only one kind of host material is 276 kJ/mol (66 kcal/mol) or more.
16. The organic electroluminescent element of claim 4 , wherein the lowest excited triplet energy (T 1 ) of the electron transporting layer adjacent to the luminescent layer is 276 kJ/mol (66 kcal/mol) or more.