IP Library Granted Patent US 7,388,082
Granted Patent B2
US 7,388,082 · App. 11/226,310 · Granted Jun 17, 2008

Alkoxyalcohol adduct of rare earth monocarboxylate

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Quick Facts
Patent No.
US 7,388,082
App. No.
11/226,310
Granted
Jun 17, 2008
Kind
B2
Abstract

An alkoxyalcohol adduct of rare earth monocarboxylate has the formula (I): M(R 2 —COO) 3 .(R 1 O(CH 2 ) n OH) p   (I) in which M is a rare earth element such as Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; R 1 is an aliphatic hydrocarbon group having 1 to 4 carbon atoms or a substituted aliphatic hydrocarbon group having 3 to 6 carbon atoms; R 2 is a hydrogen atom or an aliphatic hydrocarbon group having 1 to 4 carbon atoms which has or does not have a substituent; n is 2 or 3; and p is a number in the range of 0.5 to 3.

Claims (13)

1. A process for preparation of an alkoxyalcohol adduct of rare earth monocarboxylate, represented by the formula (I):

M(R 2 —COO) 3 .(R 1 O(CH 2 ) n OH) p   (I)

in which M is at least one rare earth element selected from the group consisting of Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; R 1 is an aliphatic hydrocarbon group having 1 to 4 carbon atoms or a substituted aliphatic hydrocarbon group having 3 to 6 carbon atoms; R 2 is a hydrogen atom or an aliphatic hydrocarbon group having 1 to 4 carbon atoms which has or does not have a substituent; n is 2 or 3; and p is a number in the range of 0.5 to 3 comprising the step of:

heating a rare earth carboxylate represented by the formula (II):

M(R 2 —COO) 2 .mH 2 O  (II)

in which M and R 2 are the same as those defined above and

m is a number satisfying the condition 0<m<4,

together with an alkoxyalcohol represented by the formula (III):

R 1 —O—(CH 2 ) n OH  (III)

in which R 1 and n are the same as those defined above, to remove water together with the alkoxyalcohol by distillation.

2. The process of claim 1 , wherein R 2 in the formula (II) is methyl.

3. The process of claim 1 , wherein the alkoxy-alcohol represented by the formula (III) is at least one compound selected from the group consisting of 2-methoxyethanol, 2-ethoxyethanol, 1-methoxy-2-propanol, 1-ethoxy 2-propanol and 3-ethoxy-1-propanol.

4. The process of claim 1 , wherein the rare earth carboxylate is a rare earth acetate and the rare earth acetate is heated together with ethoxyethanol so that water is distilled off together with the ethoxyethanol.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 15, 2007
From: FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO., LTD.)
To: FUJIFILM CORPORATION
Reel/Frame 018904/0001 →