Phthalocyanine compound
View Patent ↗The present invention provides a phthalocyanine compound represented by the following formula (PC-1): Formula (PC-1) (wherein M represents a hydrogen atom or a metal atom, R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 each represents independently a hydrogen atom or a substituent, at least one of R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 is a group represented by formula (II), and R 2 , R 3 , R 6 , R 7 , R 10 , R 11 , R 14 , and R 15 each independently represent a hydrogen atom or a substituent); —SO 2 R 17 Formula (II) (wherein R 17 represents an alkyl group, aryl group or a heterocyclic group having a hydrophilic group). A novel phthalocyanine compound having high durability and useful as a functional dye is provided.
1. A phthalocyanine compound represented by the following formula (PC-1):
wherein, M represents a hydrogen atom or a metal atom; R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 each independently represent a hydrogen atom or a group represented by formula (II); at least one of R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 represents a group represented by formula (II); and R 2 , R 3 , R 6 , R 7 , R 10 , R 11 , R 14 , and R 15 each independently represent a hydrogen atom, a halogen atom, or a sulfo group;
—SO 2 R 17 Formula (II)
wherein, R 17 represents an alkyl group having a hydrophilic group, an aryl group having a hydrophilic group, or a heterocyclic group having a hydrophilic group.
2. The phthalocyanine compound according to claim 1 , wherein the hydrophilic group of R 17 is one selected from a sulfo group, a carboxy group, or a phosphate group.
3. The phthalocyanine compound according to claim 2 , wherein the hydrophilic group of R 17 is a sulfo group or a carboxy group.
4. The phthalocyanine compound according to claim 3 , wherein the hydrophilic group of R 17 is a sulfo group.
5. A phthalocyanine compound represented by the following formula (PC-1):
wherein M represents a hydrogen atom or a metal atom; R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 each independently represent a hydrogen atom or a group represented by formula (II); at least one of R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 represents a group represented by formula (II); and R 2 , R 3 , R 6 , R 7 , R 10 , R 11 , R 14 , and R 15 each independently represent a hydrogen atom, a halogen atom, or a sulfo group;
—SO 2 R 17 Formula (II)
wherein, R 17 represents an alkyl group having a hydrophilic group.
6. The phthalocyanine compound according to claim 5 , wherein the hydrophilic group of R 17 is one selected from a sulfo group, a carboxy group, or a phosphate group.
7. The phthalocyanine compound according to claim 6 , wherein the hydrophilic group of R 17 is a sulfo group or a carboxy group.
8. The phthalocyanine compound according to claim 7 , wherein the hydrophilic group of R 17 is a sulfo group.
9. A phthalocyanine compound represented by the following formula (PC-1):
wherein M represents a hydrogen atom or a metal atom; R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 each independently represent a atom or a group represented by formula (II); four from among R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 are a group represented by formula (II); R 2 , R 3 , R 6 , R 7 , R 10 , R 11 , R 14 , and R 15 each independently represent a hydrogen atom, a halogen atom, or a sulfo group;
—SO 2 R 17 Formula (II)
and wherein R 17 represents an alkyl group having a hydrophilic group, an aryl group having a hydrophilic group, or a heterocyclic group having a hydrophilic group.
10. The phthalocyanine compound according to claim 9 , wherein R 1 or R 4 , R 5 or R 8 , R 9 or R 12 , and R 13 or R 16 are each a group represented by formula (II).
11. A phthalocyanine compound represented by the following formula (PC-1):
wherein R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 each independently represent a hydrogen atom or a group represented by formula (II); at least one of R 1 , R 4 , R 5 , R 8 , R 9 , R 12 , R 13 , and R 16 represents a group represented by formula (II); and R 2 , R 3 , R 6 , R 7 , R 10 , R 11 , R 14 , and R 15 each independently represent a hydrogen atom, a halogen atom, or a sulfo group;
—SO 2 R 17 Formula (II)
wherein R 17 represents an alkyl group having a hydrophilic group, an aryl group having a hydrophilic group, or a heterocyclic group having a hydrophilic group;
and wherein M is a copper atom.
12. A metal phthalocyanine compound represented by the following formula:
wherein M′ independently represents one selected from Li, Na or NH 4 .
13. A metal phthalocyanine compound represented by the following formula:
wherein M′ independently represents one selected from Li, Na or NH 4 .
14. A metal phthalocyanine compound represented by the following formula:
wherein M′ independently represents one selected from Li, Na or NH 4 .
15. A metal phthalocyanine compound represented by the following formula:
wherein M′ independently represents one selected from Li, Na or NH 4 .
16. A metal phthalocyanine compound represented by the following formula:
wherein M′ independently represents one selected from Li, Na or NH 4 .
17. A metal phthalocyanine compound represented by the following formula:
wherein M′ independently represents one selected from Li, Na or NH 4 .