IP Library Granted Patent US 7,144,693
Granted Patent B2
US 7,144,693 · App. 11/230,644 · Granted Dec 5, 2006

Photothermographic material

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Quick Facts
Patent No.
US 7,144,693
App. No.
11/230,644
Granted
Dec 5, 2006
Kind
B2
Abstract

A photothermographic material comprising a support and an image-forming layer, a non-photosensitive intermediate layer A, and an outermost layer provided in this order on at least one side of the support, wherein the image-forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least 50 mass % of a binder in the non-photosensitive intermediate layer A is a polymer latex having a film water absorption of 5 % or lower.

Claims (24)

1. A photothermographic material comprising a support and an image-forming layer, a non-photosensitive intermediate layer A, and an outermost layer provided in this order on at least one side of the support, wherein the image-forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least 50 mass % of a binder in the non-photosensitive intermediate layer A is a polymer latex having a film water absorption of 5% or lower.

2. The photothermographic material according to claim 1 , wherein the non-photosensitive intermediate layer A is disposed adjacent to the image-forming layer.

3. The photothermographic material according to claim 1 , wherein a non-photosensitive intermediate layer B is provided between the non-photosensitive intermediate layer A and the outermost layer, and a binder of at least one of the outermost layer and the non-photosensitive intermediate layer B includes at least 50 mass % of a hydrophilic polymer derived from animal protein.

4. The photothermographic material according to claim 3 , wherein at least 50 mass % of the binder of the non-photosensitive intermediate layer B is a hydrophilic polymer derived from animal protein and at least 50 mass % of the binder of the outermost layer is a hydrophobic polymer.

5. The photothermographic material according to claim 3 , wherein the non-photosensitive intermediate layer B comprises a first non-photosensitive intermediate layer and a second non-photosensitive intermediate layer, the first non-photosensitive intermediate layer B includes at least 50 mass % of a hydrophilic polymer which is not derived from animal protein, the second non-photosensitive intermediate layer includes at least 50 mass % of a hydrophilic polymer derived from animal protein, and the first non-photosensitive intermediate layer is nearer to the intermediate layer A than the second non-photosensitive intermediate layer is.

6. The photothermographic material according to claim 1 , wherein at least 50 mass % of the binder of the non-photosensitive intermediate layer A is a polymer including 10 mass % to 70 mass % of a monomer component represented by the following formula (M):

CH 2 ═CR 01 —CR 02 ═CH 2   Formula (M)

wherein in the formula (M), R 01 and R 02 each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.

7. The photothermographic material according to claim 6 , wherein R 01 and R 02 both represent hydrogen atoms, or one of R 01 and R 02 represents a hydrogen atom and the other represents a methyl group.

8. The photothermographic material according to claim 1 , wherein a binder of the outermost layer comprises a hydrophobic polymer or a hydrophilic polymer derived from animal protein.

9. The photothermographic material according to claim 8 , wherein the binder of the outermost layer comprises a hydrophilic polymer derived from animal protein.

10. The photothermographic material according to claim 3 , wherein the hydrophilic polymer derived from animal protein is gelatin.

11. A photothermographic material comprising a support and an image-forming layer, a non-photosensitive intermediate layer A, and an outermost layer provided in this order on at least one side of the support, wherein the image-forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least 50 mass % of a binder in the non-photosensitive intermediate layer A is a polymer latex having a film moisture absorption of 3% or lower.

12. The photothermographic material according to claim 11 , wherein the non-photosensitive intermediate layer A is disposed adjacent to the image-forming layer.

13. The photothermographic material according to claim 11 , wherein a non-photosensitive intermediate layer B is provided between the non-photosensitive intermediate layer A and the outermost layer, and a binder of at least one of the outermost layer and the non-photosensitive intermediate layer B includes at least 50 mass % of a hydrophilic polymer derived from animal protein.

14. The photothermographic material according to claim 13 , wherein at least 50 mass % of the binder of the non-photosensitive intermediate layer B is a hydrophilic polymer derived from animal protein and at least 50 mass % of the binder of the outermost layer is a hydrophobic polymer.

15. The photothermographic material according to claim 13 , wherein the non-photosensitive intermediate layer B comprises a first non-photosensitive intermediate layer and a second non-photosensitive intermediate layer, the first non-photosensitive intermediate layer B includes at least 50 mass % of a hydrophilic polymer which is not derived from animal protein, the second non-photosensitive intermediate layer includes at least 50 mass % of a hydrophilic polymer derived from animal protein, and the first non-photosensitive intermediate layer is nearer to the intermediate layer A than the second non-photosensitive intermediate layer is.

16. The photothermographic material according to claim 11 , wherein at least 50 mass % of the binder of the non-photosensitive intermediate layer A is a polymer including 10 mass % to 70 mass % of a monomer component represented by the following formula (M):

CH 2 ═CR 01 —CR 02 ═CH 2   Formula (M)

wherein in the formula (M), R 01 and R 02 each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.

17. The photothermographic material according to claim 16 , wherein R 01 and R 02 both represent hydrogen atoms, or one of R 01 and R 02 represents a hydrogen atom and the other represents a methyl group.

18. The photothermographic material according to claim 11 , wherein a binder of the outermost layer comprises a hydrophobic polymer or a hydrophilic polymer derived from animal protein.

19. The photothermographic material according to claim 18 , wherein the binder of the outermost layer comprises a hydrophilic polymer derived from animal protein.

20. A photothermographic material comprising a support and an image-forming layer, a non-photosensitive intermediate layer A, and an outermost layer provided in this order on at least one side of the support, wherein the image-forming layer comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, and a binder, and at least 50 mass % of a binder in the non-photosensitive intermediate layer A is a polymer latex having a film water absorption of 5% or lower and a film moisture absorption of 3% or lower.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2007
From: FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO. LTD.)
To: FUJIFILM CORPORATION
Reel/Frame 019331/0493 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 21, 2005
From: OYAMADA, TAKAYOSHI
To: FUJI PHOTO FILM CO., LTD.
Reel/Frame 017023/0875 →