Optical compensation film, elliptical polarizing plate and liquid crystal display
An optical compensation film and an elliptical polarizing plate, for realizing a liquid crystal display improved in gray-scale inversion, having a wider viewing angle property and being excellent in industrial production is provided. An embodiment of the optical compensation film is characterized in that a liquid crystal composition capable of expressing a biaxial nematic phase has a twisted hybrid alignment. Another embodiment includes a transparent substrate, a first optically anisotropic layer and a second optically anisotropic layer in an arbitrary order, and is characterized in that the first optically anisotropic layer is formed by a liquid crystal composition capable of expressing a biaxial nematic phase, and the second optically anisotropic layer is formed by monoaxial liquid crystalline molecules.
1 . An optical compensation film comprising an optically anisotropic layer containing a liquid crystal composition capable of expressing a biaxial nematic phase, wherein the liquid crystal composition in the optically anisotropic layer is in a state where a hybrid alignment and a twisted alignment are provided.
2 . An optical compensation film comprising an optically anisotropic layer containing a liquid crystal composition capable of expressing a biaxial nematic phase, wherein the optically anisotropic layer is formed by fixing the biaxial nematic phase in which a twisted alignment is provided to a hybrid alignment.
3 . The optical compensation film according to claim 1 , wherein the liquid crystal composition has refractive indexes nx, ny and nz in a decreasing order of three axes thereof, an angle of an axis of nx to a planar direction of the optical compensation film scarcely changes in a thickness direction of the optically anisotropic layer, and an angle of an axis of nz to the planar direction changes in the thickness direction.
4 . The optical compensation film according to claim 1 , wherein the twisted alignment has a twist angle of less than 10°.
5 . The optical compensation film according to claim 1 , wherein the liquid crystal composition comprises: a liquid crystal compound capable of expressing a rod-shape liquid crystal phase; and a liquid crystal compound capable of expressing a discotic liquid crystal phase.
6 . The optical compensation film according to claim 1 , wherein the liquid crystal composition comprises: an optically active compound; and a liquid crystal compound capable of expressing a biaxial nematic phase, the optical compensation film further comprises: a substrate; and an alignment film between the substrate and the optically anisotropoc layer, and the optically anisotropic layer is formed by: stacking a layer containing the liquid crystal composition; and expressing and fixing the biaxial nematic phase.
7 . An optical compensation film comprising: a transparent substrate; a first optically anisotropic layer; and a second optically anisotropic layer in an arbitrary order, wherein the first optically anisotropic layer contains a liquid crystal composition capable of expressing a biaxial nematic phase, and the second optically anisotropic layer contains a monoaxial liquid crystalline molecule.
8 . The optical compensation film according to claim 7 , wherein the biaxial nematic phase expressed in the first optically anisotropic layer has a principal axis inclined to a surface of the transparent substrate.
9 . The optical compensation film according to claim 8 , wherein an inclination angle of the principal axis to the surface of the transparent substrate changes unidirectionally according to a distance to the surface of the transparent substrate.
10 . The optical compensation film according to claim 7 , wherein the monoaxial liquid crystalline molecule has an optical axis thereof inclined to a surface of the transparent substrate, and an inclination angle of the optical axis changes unidirectionally according to a distance to the surface of the transparent substrate.
11 . The optical compensation film according to claim 7 , wherein the first optically anisotropic layer, the transparent substrate and the second optically anisotropic layer are stacked in this order.
12 . The optical compensation film according to claim 7 , wherein the transparent substrate, the first optically anisotropic layer, and the second optically anisotropic layer are stacked in this order.
13 . The optical compensation film according to claim 7 , wherein the first optically anisotropic layer contains a rod-shape liquid crystalline molecule.
14 . The optical compensation film according to claim 7 , wherein the first optically anisotropic layer contains a discotic liquid crystalline molecule.
15 . An elliptical polarizing plate comprises: a transparent substrate; an optical compensation film according to claim 1; and a polarizing film.
16 . An elliptical polarizing plate comprising: at least an optical compensation film according to claim 7; a polarizing film; and a transparent protective film, wherein the second optically anisotropic layer is stacked in a position closer to the polarizing film than the first optically anisotropic layer.
17 . A liquid crystal display comprising: a liquid crystal cell of TN mode; and two polarizing elements positioned on both sides of the liquid crystal cell, wherein the two polarizing elements each comprises an elliptical polarizing plate according to claim 16 .
18 . A liquid crystal display comprising an optical compensation film according to claim 1.