Interface conditioning to improve efficiency and lifetime of organic electroluminescence devices
View Patent ↗In at least one embodiment of the invention, an OLED device is disclosed in which the surface of one or more layers of the OLED are conditioned with metal nano-particles such that they are disposed along the interface between adjacent layers.
1. An electroluminescent device, comprising:
an anode layer;
a cathode layer; and
a stack of layers between said anode layer and said cathode layer, said stack of layers including at least one layer comprising organic material, wherein nano-particles are disposed in at least one interface between layers in said stack of layers or between said stack of layers and said cathode layer, the nano-particles being confined to the interface, the nano-particles not being mixed throughout any of the layers defining the interface wherein the nano-particles are disposed, wherein any layer within the stack of layers includes at least one small molecule material having not more than five linear repeating units.
2. An electroluminescent device, comprising:
an anode layer;
a cathode layer; and
a stack of layers between said anode layer and said cathode layer, said stack of layers including at least one layer comprising organic material, wherein nano-particles are disposed in at least one interface between layers in said stack of layers or between said stack of layers and said cathode layer, the nano-particles being confined to the interface, the nano-particles not being mixed throughout any of the layers defining the interface wherein the nano-particles are disposed, wherein the stack of layers includes an electroluminescent layer and at least one small molecule material in the electroluminescent layer, the small molecule material being one of tris(8-hydroxyquinolate) aluminum, anthracene, rubrene, tris(2-phenylpyridine) iridium, triazine, or any metal-chelate compound or derivative thereof.
3. The device according to claim 2 wherein said stack of layers includes at least one of:
an anode buffer layer disposed over said anode layer;
an emissive layer, said emissive layer capable of emitting light; and
a hole transporting interlayer.
4. The device according to claim 3 wherein said emissive layer comprises a conjugated poly-p-phenylenevinylene polymer.
5. The device according to claim 3 wherein said emissive layer comprises a conjugated polyspiro polymer.
6. The device according to claim 3 wherein said emissive layer comprises a conjugated fluorene polymer.
7. The device according to claim 2 wherein at least one of said layers in said stack of layers comprises a light emissive component.
8. The device according to claim 7 wherein said light emissive component comprises at least one phosphorescence-based emitter.
9. The device according to claim 7 wherein said light emissive component comprises at least one fluorescence-based emitter.
10. The device according to claim 7 wherein said light emissive component comprises at least one phosphorescence-based emitter and at least one fluorescence-based emitter.
11. The device according to claim 2 wherein any layer within said stack of layers is formed at least in part using at least one polymer organic material.
12. The device according to claim 2 wherein said nano-particles comprise at least one of Ag, Au, Ni, Fe, Co, Ge, Cu, Pt, Pd, Os, Ti, Si or compounds thereof.
13. The device according to claim 2 wherein said nano-particles are disposed by at least one of sputtering, spin coating, spray coating, or thermal evaporation.
14. The device according to claim 2 wherein said nano-particles form an ultra-thin layer of nano-particles upon being disposed.
15. The device according to claim 2 wherein each of said nano-particles has a size ranging from 0.01 to 10 nano-meters.
16. The device according to claim 2 wherein said nano-particles comprise a core of a first material and a shell of a second different material.
17. The device according to claim 16 wherein said first material is silica.
18. The device according to claim 17 wherein said second material comprises at least one of Ag, Au, Ni, Fe, Co, Ge, Cu, Pt, Pd, Os, Ti, Si or compounds thereof.
19. The device of claim 2 wherein said nano-particles have an absorption spectrum which overlaps the triplet exciton state of the material in either one of the layers defining the interface wherein said nano-particles are disposed.
20. The device of claim 19 wherein said nano-particles have a resonance with the triplet exciton state of the material in either one of the layers defining the interface wherein said nano-particles are disposed.
21. The device of claim 2 wherein the nano-particles are in more than one interface between adjacent layers in the stack of layers or in an interface between adjacent layers in the stack of layers and between the stack of layers and the cathode layer.
22. The device of claim 2 wherein the stack of layers includes an electroluminescent layer and the at least one small molecule material in the electroluminescent layer is one of tris(8-hydroxyquinolate) aluminum, anthracene, rubrene, tris(2-phenylpyridine) iridium, triazine, or any metal-chelate compound or derivative thereof.