Organic electroluminescent element
View Patent ↗An organic electroluminescent element including a pair of electrodes and one or more organic compound layers including at least one light-emitting layer disposed between the pair of electrodes, wherein the at least one light-emitting layer contains at least one luminescent dopant and a plurality of host compounds. The ionization potential of the dopant is Ip(D), the minimum value out of the ionization potentials of the plurality of host compounds is Ip(H)min, and ΔIp is defined by ΔIp=Ip(D)−Ip(H)min and satisfies a relationship of ΔIp>0 eV. The electron affinity of the dopant is Ea(D), the maximum value out of the electron affinities of the plurality of host compounds is Ea(H)max, and ΔEa is defined by ΔEa=EA(H)max−Ea(D) and satisfies a relationship of ΔEa>0 eV.
1. An organic electroluminescent element comprising:
a pair of electrodes and one or more organic compound layers including at least one light-emitting layer disposed between the pair of electrodes,
wherein the at least one light-emitting layer contains at least one luminescent dopant and a plurality of host compounds;
the ionization potential of the dopant is Ip(D), the minimum value out of the ionization potentials of the plurality of host compounds is Ip(H)min, and ΔIp is defined by ΔIp=Ip(D)−Ip(H)min and satisfies a relationship of ΔIp>0 eV;
the electron affinity of the dopant is Ea(D), the maximum value out of the electron affinities of the plurality of host compounds is Ea(H)max, and ΔEa is defined by ΔEa=Ea(H)max−Ea(D) and satisfies a relationship of ΔEa>0 eV; and
wherein when the minimum value out of the minimum triplet excitation energies of the plurality of host compounds is T1(H)min, the minimum value satisfies a relationship of T1(H)min>T1(D), where T1(D) is the minimum triplet excitation energy of the dopant.
2. The organic electroluminescent element of claim 1 , wherein at least one of the relationships of 1.2 eV>ΔIp>0.2 eV and 1.2 eV>ΔEa>0.2 eV is satisfied.
3. The organic electroluminescent element of claim 2 , wherein, when a single layer film of only the plurality of host compounds contained in the light-emitting layer is formed under the same conditions as in the formation of the light-emitting layer, the fluorescent phosphorescent spectrum of the film is assigned to the respective light emission spectra of the individual host compounds each as measured alone.
4. The organic electroluminescent element of claim 2 , wherein the one or more organic compound layers comprise a carrier transporting layer adjacent to the at least one light-emitting layer.
5. The organic electroluminescent element of claim 4 , wherein the carrier transporting layer is at least one of an electron transporting layer and a hole transporting layer.
6. The organic electroluminescent element of claim 4 , wherein the carrier transporting layer is an electron transporting layer and the electron affinity Ea(ETL) of the electron transporting layer is larger than the electron affinity Ea(D) of the dopant contained in the at least one light-emitting layer.
7. The organic electroluminescent element of claim 4 , wherein the carrier transporting layer is a hole transporting layer and the ionization potential Ip(HTL) of the hole transporting layer is smaller than the ionization potential Ip(D) of the dopant contained in the at least one light-emitting layer.
8. The organic electroluminescent element of claim 1 , wherein, when a single layer film of only the plurality of host compounds contained in the light-emitting layer is formed under the same conditions as in the formation of the light-emitting layer, the fluorescent phosphorescent spectrum of the film is assigned to the respective light emission spectra of the individual host compounds each as measured alone.
9. The organic electroluminescent element of claim 1 , wherein the one or more organic compound layers comprise a carrier transporting layer adjacent to the at least one light-emitting layer.
10. The organic electroluminescent element of claim 9 , wherein the carrier transporting layer is at least one of an electron transporting layer and a hole transporting layer.
11. The organic electroluminescent element of claim 9 , wherein the carrier transporting layer is an electron transporting layer and the electron affinity Ea(ETL) of the electron transporting layer is larger than the electron affinity Ea(D) of the dopant contained in the at least one light-emitting layer.
12. The organic electroluminescent element of claim 9 , wherein the carrier transporting layer is a hole transporting layer and the ionization potential Ip(HTL) of the hole transporting layer is smaller than the ionization potential Ip(D) of the dopant contained in the at least one light-emitting layer.
13. The organic electroluminescent element of claim 1 , wherein the content of each of the plurality of host compounds is from 15 to 85 mass % based on the mass of all compounds constituting the light-emitting layer.
14. The organic electroluminescent element of claim 1 , wherein at least one of the conditions of Ip(H)min being 5.1 eV or more and Ea(H)max being 3.0 eV or less is satisfied.
15. An organic electroluminescent element comprising:
a pair of electrodes and one or more organic compound layers including at least one light-emitting layer disposed between the pair of electrodes,
wherein the at least one light-emitting layer contains at least one luminescent dopant and a plurality of host compounds;
the ionization potential of the dopant is Ip(D), the minimum value out of the ionization potentials of the plurality of host compounds is Ip(H)min, and ΔIp is defined by ΔIp=Ip(D)−Ip(H)min and satisfies a relationship of ΔIp>0 eV;
the electron affinity of the dopant is Ea(D), the maximum value out of the electron affinities of the plurality of host compounds is Ea(H)max, and ΔEa is defined by ΔEa=Ea(H)max−Ea(D) and satisfies a relationship of ΔEa>0 eV, and wherein the plurality of host compounds include a hole transporting host and an electron transporting host; and
wherein when the minimum value out of the minimum triplet excitation energies of the plurality of host compounds is T1(H)min, the minimum value satisfies a relationship of T1(H)min>T1(D), where T1(D) is the minimum triplet excitation energy of the dopant.
16. The organic electroluminescent element of claim 15 , wherein the dopant is an iridium complex, a platinum complex or a rhenium complex containing at least one coordination bond of a metal-carbon bond, metal-nitrogen bond, metal-oxygen bond or metal-sulfur bond.
17. The organic electroluminescent element of claim 15 , wherein the hole transporting host is a compound having a plurality of carbazole skeletons and/or aromatic tertiary amine skeletons within the molecule.
18. The organic electroluminescent element of claim 15 , wherein the electron transporting host is a metal complex, an azole derivative or an azine derivative, the azole derivative being a benzimidazole derivative or an imidazopyridine derivative, and the azine derivative being a pyridine derivative, a pyrimidine derivative or a triadine derivative.
19. An organic electroluminescent element comprising:
a pair of electrodes and one or more organic compound layers including at least one light-emitting layer disposed between the pair of electrodes,
wherein the at least one light-emitting layer contains at least one luminescent dopant and a plurality of host compounds;
the ionization potential of the dopant is Ip(D), the minimum value out of the ionization potentials of the plurality of host compounds is Ip(H)min, and ΔIp is defined by ΔIp=Ip(D)−Ip(H)min and satisfies a relationship of ΔIp>0 eV;
the electron affinity of the dopant is Ea(D), the maximum value out of the electron affinities of the plurality of host compounds is Ea(H)max, and ΔEa is defined by ΔEa=Ea(H)max−Ea(D) and satisfies a relationship of ΔEa>0 eV,
wherein the plurality of host compounds include a hole transporting host and an electron transporting host;
the hole transporting host is selected from H-1, H-3, H-4, H-7or H-8 represented by thefollowing formulae;
the electron transporting host is selected from E-1 or E-11 represented by the following formulae;
and the luminescent dopant is selected from D-1 or D-3 represented by the following formulae
and
wherein when the minimum value out of the minimum triplet excitation energies of the plurality of host compounds is T1(H)min, the minimum value satisfies a relationship of T1(H)min>T1(D), where T1(D) is the minimum triplet excitation energy of the dopant.