Niobium compound
View Patent ↗The present invention relates to novel, water-soluble niobium compounds, a process for their preparation and their formulations.
1. A process for the preparation of a niobium compound, comprising the steps of:
dissolving niobium hydroxide and oxalic acid in water;
adding ammonia
cooling the reaction mixture.
2. The process according to claim 1 , wherein the niobium compound is (NH 4 )Nb(O)(C 2 O 4 ) 2 (H 2 O) 2 and hydrates thereof.
3. Process according to claim 1 , wherein the niobium concentration in the reaction mixture is less than about 2 g Nb/1.
4. Process according to claim 1 or 2 , wherein the reaction mixture has temperature of about 35° C. to about 80° C.
5. Process according to claim 1 , wherein the reaction mixture is cooled to a temperature of about 25° C. or less.
6. Process according to claim 1 , wherein the addition of ammonia is carried out by addition of aqueous ammonia or passing gaseous ammonia though the reaction mixture.
7. Process according to claim 1 , wherein the process further comprises a filtration step.
8. Process according to claim 6 , wherein the process further comprises a drying step.
9. Process according to claim 7 , wherein the drying step is carried out at a temperature of less than about 80° C.
10. A formulation comprising a defined amount of (NH 4 )[Nb(O)(C 2 O 4 ) 2 (H 2 O) 2 ] compound in a bag.
11. A formulation according to claim 9 , wherein the bag is a bag soluble in water or a reaction medium.
12. A formulation comprising a container made of a soluble polymeric film comprising the compound (NH 4 )[Nb(O)(C 2 O 4 ) 2 (H 2 O) 2 ], its solution or its slurry.
13. A formulation according to claim 11 , the polymeric film comprising polyvinyl alcohol.
14. A formulation according to claim 11 , said formulation being a solid (NH 4 )[Nb(O)(C 2 O 4 ) 2 (H 2 O) 2 ] compound inside a closed bag comprising a film of polyvinyl alcohol.