IP Library Granted Patent US 7,374,661
Granted Patent B2
US 7,374,661 · App. 11/247,033 · Granted May 20, 2008

Thermal cracking

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Quick Facts
Patent No.
US 7,374,661
App. No.
11/247,033
Granted
May 20, 2008
Kind
B2
Abstract

A method for thermally cracking a hydrocarbonaceous feed material using a combustion fuel fired furnace wherein at least part of the combustion fuel employed in the furnace is syngas.

Claims (13)

1. In a process for the thermal cracking of at least one hydrocarbonaceous material wherein a combustion fuel fired furnace is employed, and wherein plant fuel gas is formed, said process producing at least one individual product for export from said process comprising the removal of at least part of hydrogen content and the addition of at least one BTU enhancing component, and comprising employing syngas as at least part of said combustion fuel.

2. The method of claim 1 wherein at least part of said plant fuel gas is recovered from said process and is further processed to produce an individual fuel gas product for export from said process in addition to said at least one individual product.

3. The method of claim 1 wherein said furnace is fired at least in part with at least one of natural gas and plant fuel gas, and said syngas is employed as a furnace combustion fuel in place of at least part of at least one of said natural gas and plant fuel gas.

4. The method of claim 1 wherein said syngas contains in major amount a mixture of hydrogen and carbon monoxide.

5. The method of claim 4 wherein said syngas contains from about 50 to about 65 mol % carbon monoxide, from about 25 to about 35 mol % hydrogen, from about 1 to about 15 mol % carbon dioxide, from about 1 to about 5 mol % nitrogen, and less than about 2 mol % methane, all mol % based on the total moles of said syngas.

6. The method of claim 1 wherein said plant fuel gas formed in said process contains methane in major amount and hydrogen in minor amount.

7. The method of claim 6 wherein said methane is present in an amount of from about 70 to about 95 mol %, said hydrogen is present in an amount of from about 3 to about 28 mol %, with the remainder being essentially a mixture of ethane and ethylene.

8. The method of claim 2 wherein said individual fuel gas product for export from said process contains at least about 80 mol % methane, and at least about 3 mol % hydrogen, with the remainder being essentially a mixture of ethane and ethylene.

9. The method of claim 2 wherein said plant fuel gas is processed to meet pipeline specifications for transport in said pipeline.

10. The method of claim 9 wherein said individual fuel gas product has a Btu content of at least about 950 Btu/SCF and is at a pressure of at least about 400 psig.

11. The method of claim 1 wherein said Btu enhancing component is methane.

12. The method of claim 1 wherein said further processing to produce said individual fuel gas product for export from said process excludes desulfurization of said fuel gas.

13. The method of claim 1 wherein said syngas is diluted with at least one gas to alter the flame temperature of said combustion fuel.

Assignments (18)
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032112/0786 →
APPOINTMENT OF SUCCESSOR ADMINISTRATIVE AGENT Recorded Jan 22, 2014
From: UBS AG, STAMFORD BRANCH
To: BANK OF AMERICA, N.A.
Reel/Frame 032112/0863 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: CITIBANK, N.A.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0644 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0684 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: BANK OF AMERICA, N.A.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0730 →
SECURITY AGREEMENT Recorded May 19, 2010
From: EQUISTAR CHEMICALS, LP
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 024402/0655 →
SECURITY AGREEMENT Recorded May 18, 2010
From: EQUISTAR CHEMICALS, LP
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 024397/0861 →
SECURITY AGREEMENT Recorded May 7, 2010
From: EQUISTAR CHEMICALS. LP
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 024351/0001 →
SECURITY AGREEMENT Recorded May 6, 2010
From: EQUISTAR CHEMICALS, LP
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024342/0443 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0705 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
To: EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0186 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0856 →
RELEASE OF SECURITY INTEREST Recorded May 4, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: EQUISTAR CHEMICALS, LP
Reel/Frame 024329/0535 →
SECURITY AGREEMENT Recorded Oct 30, 2009
From: EQUISTAR CHEMICALS, LP
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 023449/0687 →
SECURITY AGREEMENT Recorded Apr 9, 2009
From: EQUISTAR CHEMICALS, LP
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT AND COLLATERAL AGENT
Reel/Frame 022678/0860 →
SECURITY AGREEMENT Recorded Aug 4, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; BASELL POLYOLEFIN GMBH; LYONDELL CHEMICAL COMPANY; EQUISTAR CHEMICALS, L.P.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 021354/0708 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS AND PATENT APPLICATIONS Recorded Mar 26, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; EQUISTAR CHEMICALS. LP.; LYONDELL CHEMICAL COMPANY; LYONDELL CHEMICAL TECHNOLOGY, L.P.; LYONDELL PETROCHEMICAL COMPANY; NATIONAL DISTILLERS AND CHEMICAL CORPORATION; OCCIDENTAL CHEMICAL CORPORATION; OLIN CORPORATION; QUANTUM CHEMICAL CORPORATION; BASELL POLYOLEFIN GMBH
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 020704/0562 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 11, 2005
From: BRIDGES, ROBERT S.; CHELLAPPAN, SELLAMUTHU G.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 017112/0512 →