Enhanced boron nitride composition and polymer-based compositions made therewith
View Patent ↗A boron nitride composition having its surface treated with a coating layer comprising a zirconate coupling agent. The boron nitride composition can be used as fillers in polymeric compounds at levels of up to 90 wt. %, giving thermal conductivity of up to 35 W/mK.
1. A boron nitride composition comprising boron nitride powder, the boron nitride powder having its surface treated with a coating layer, wherein the coating layer comprises about 0.5 to about 10 wt. % of at least one of a zirconate coupling agent, a zirconium aluminate coupling agent, and mixtures thereof.
2. The boron nitride composition of claim 1 , wherein the coating layer comprising about 1 to about 5 wt. % of a zirconate coupling agent.
3. The boron nitride composition of claim 1 , wherein the zirconate coupling agent is selected from the group of an ethyleneically unsaturated zirconate containing compound, a neoalkoxy zirconate containing compound, and mixtures thereof.
4. The boron nitride composition of claim 1 , wherein the zirconate coupling agent is an organo functional alkoxide of zirconium, and wherein the alkoxide is compatible and active in water.
5. The boron nitride composition of claim 1 , wherein the boron nitride powder has an average particle size of at least 50 microns.
6. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises spherically shaped agglomerates of irregular non-spherical particles bound together by a binder and subsequently spray-dried.
7. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises hexagonal boron nitride platelets having an aspect ratio of from about 50 to about 300.
8. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises hexagonal boron nitride platelets having an average diameter of from about 2 :m to about 20 :m.
9. The boron nitride composition of claim 1 , wherein the boron nitride powder comprises irregularly shaped agglomerates of hexagonal boron nitride platelets, having an average particle size of above 10 microns.
10. A polymer composite comprising a polymer matrix selected from the group of a thermoplastic resin, an epoxy resin, a silicone resin, and a filler material comprising particles of boron nitride treated with a coating layer comprising 0.5 to 10 wt. % of at least one of a zirconate coupling agent, a zirconium aluminate coupling agent, and mixtures thereof.
11. The polymer composite of claim 10 , wherein the polymer matrix comprises a silicone resin.
12. The polymer composite of claim 10 , wherein the polymer matrix comprises at least one of a liquid crystal polymer; polyethylene naphthalate, polyethylene terephthalate, polybutylene terephthalate; a polyamide; a polyimide; a polyphthalamide; a polyphenylene sulfide; a polycarbonate; a polyetheretherketone; apolyaryletherketone; a polyphenylene oxide; and a mixture thereof.
13. A polymer composite comprising a polymer matrix selected from the group of a thermoplastic resin, an epoxy resin, a silicone resin, and a filler material comprising particles of boron nitride, wherein the boron nitride is treated with a coating layer comprising about 1 to about 5 wt. % of a zirconate coupling agent.
14. The polymer composite of claim 13 , wherein the zirconate coupling agent is selected from the group of an ethyleneically unsaturated zirconate containing compound, a neoalkoxy zirconate containing compound, and mixtures thereof.
15. An article comprising the boron nitride composition of claim 1 .
16. A method for producing boron nitride powder for forming polymer composites having reduced viscosity, said process comprises the step of coating the boron nitride powder with a composition comprising a zirconate coupling agent for a sufficient amount of time for the boron nitride powder to be coated with a sufficient amount of the zirconate coupling agent.
17. The method of claim 16 , wherein the boron nitride is coated with the zirconate coupling agent by at least one of tumbling, prilling, or spray coating.
18. The method of claim 16 , wherein the zirconate coupling agent is an organo functional alkoxide of zirconium, and wherein the alkoxide is compatible and active in water.
19. The boron nitride composition of claim 1 , wherein said composition when blended into a polymeric composition, lowers the viscosity of the polymeric composition at least 20% over the viscosity of the polymeric composition containing the same amount of boron nitride powder not treated with the zirconate coupling agent.
20. The boron nitride composition of claim 1 wherein the coupling agent is a zirconate selected from the group consisting of neoalkoxytrisneodecanoyl zirconate, neoalkoxytris(dodecyl)benzenesulfonyl zirconate, neoalkoxytris(dioctyl)phosphate zirconate, neoalkoxytris(dioctyl)pyrophosphate zirconate, neoalkoxytris (ethylenediamino)ethyl zirconate, neoalkoxytris(m-amino)phenyl zirconate, tetra(2,2 diallyloxymethyl)butyl, di(ditridecyl)phosphito zirconate, neopentyl(diallyl)oxy trineodecanoyl zirconate, neopentyl(diallyl)oxy tri(dodecyl)benzene-sulfonyl zirconate, neopentyl(diallyl)oxy tri(dioctyl)phosphato zirconate, neopentyl(diallyl)oxy tri(dioctyl)pyro-phosphato zirconate, neopentyl(diallyl)oxy tri(N-ethylenediamino)ethyl zirconate, neopentyl(diallyl)oxy tri(m-amino)phenyl zirconate, neopentyl(diallyl)oxy trimethacryl zirconate, neopentyl(diallyl)oxy triacryl zirconate, dineopentyl(diallyl)oxy diparamino benzoyl zirconate, dineopentyl(aiallyl)oxy di(3-mercapto) propionic zirconate, zirconium IV 2,2-bis(2-propenolatomethyl) butanolato cyclo di [2,2-(bis 2-propenolatomethyl) butanolato]pyrophosphato-O,O, neoalkoxytrisneodecanoyl zirconate, neoalkoxytris(dodecyl) benzenesulfonyl zirconate, neoalkoxytris(dioctyl) phosphate zirconate, neoalkoxytris(dioctyl) pyrophosphate zirconate, neoalkoxytris(ethylenediamino) ethyl zirconate, neoalkoxytris (m-amino)phenyl zirconate and combinations thereof.
21. The boron nitride composition of claim 1 wherein the coupling agent further includes one or more additives selected from the group consisting of thermal initiators, chemical initiators, electron beam initiators, photoinitiators, dispersants, defoaming agents and adhesion promoters.
22. The method of claim 16 wherein the boron nitride and coupling agent are combined in an aqueous or organic solvent, wherein the solvent is subsequently removed.
23. The method of claim 22 wherein the solvent is an organic liquid selected from the group consisting of toluene, xylene, hexane, octane, ethyl acetate, butyl acetate and ethyl ether.
24. A boron nitride composition comprising boron nitride powder, the boron nitride powder having its surface treated with a coating layer comprising at least one of a zirconate coupling agent, a zirconium aluminate coupling agent, an organo-aluminate coupling agent selected from the group consisting of diisobutyl (oleyl) aceto acetyl aluminate and alkylacetoacetate aluminum diisopropylate, and mixtures thereof.
25. The boron nitride composition of claim 24 , wherein the boron nitride powder has an average particle size of at least 50 microns.
26. The boron nitride composition of claim 24 , wherein the boron nitride powder comprises spherically shaped agglomerates of irregular non-spherical particles bound together by a binder and subsequently spray-dried.
27. The boron nitride composition of claim 24 , wherein the boron nitride powder comprises hexagonal boron nitride platelets having an aspect ratio of from about 50 to about 300.
28. The boron nitride composition of claim 24 , wherein the boron nitride powder comprises hexagonal boron nitride platelets having an average diameter of from about 2 :m to about 20 :m.
29. The boron nitride composition of claim 24 , wherein the boron nitride powder comprises irregularly shaped agglomerates of hexagonal boron nitride platelets, having an average particle size of above 10 microns.
30. A polymer composite comprising a polymer matrix selected from the group of a thermoplastic resin, an epoxy resin, a silicone resin, and a filler material comprising particles of boron nitride treated with a coating layer comprising 0.5 to 10 wt. % of at least one of a zirconate coupling agent, a zirconium aluminate coupling agent, an organo-aluminate coupling agent selected from the group consisting of diisobutyl(oleyl)aceto acetyl aluminate and alkylacetoacetate aluminum diisopropylate, and mixtures thereof.
31. The polymer composite of claim 30 , wherein the polymer matrix comprises a silicone resin.
32. The polymer composite of claim 30 , wherein the polymer matrix comprises at least one of a liquid crystal polymer; polyethylene naphthalate, polyethylene terephthalate, polybutylene terephthalate; a polyamide; a polyimide; a polyphthalamide; a polyphenylene sulfide; a polycarbonate; a potyetheretherketone; a polyaryletherketone; a polyphenylene oxide; and a mixture thereof.
33. The polymer composite of claim 30 , wherein the boron nitride is treated with a coating layer comprising about 1 to about 5 wt. % of the zirconate coupling agent.
34. The polymer composite of claim 33 , wherein the zirconate coupling agent is selected from the group of an ethyleneically unsaturated zirconate containing compound, a neoalkoxy zirconate containing compound, and mixtures thereof.