Low-E coated articles having zirconium inclusive dielectric layer
View Patent ↗A heat treatable coated article (e.g., vehicle windshield, IG unit, etc.) is provided with a dual-silver low-E coating. Before and/or after heat treatment (HT), the coating and/or coated article has a visible transmittance of at least 70%, more preferably at least 75%. Moreover, the coating and/or coated article is designed so as to have approximately the same color when viewed over a wide range of viewing angles. In certain embodiments, at least one contact layer (e.g., of or including NiCrO x ) that contacts an infrared (IR) reflecting layer (e.g., Ag) is oxidation graded so that it progressively becomes less oxidized through its thickness as it nears the IR reflecting layer. In still other embodiments, a Si-rich silicon nitride layer(s) may be utilized to reduce haze.
1. A coated article that is a vehicle windshield, comprising:
a coating provided on a glass substrate, said coating comprising from the glass substrate outwardly:
a) at least one dielectric layer;
b) a first contact layer, and another layer provided between at least layers (a) and (b);
c) a first IR reflecting layer comprising Ag;
d) a second contact layer, said first IR reflecting layer contacting each of said first and second contact layers;
e) at least one dielectric layer;
f) a third contact layer;
g) a second IR reflecting layer comprising Ag;
h) a fourth contact layer, said second IR reflecting layer contacting each of said third and fourth contact layers;
i) at least one dielectric layer, and another layer provided between at least layers (h) and (i);
wherein after being heat treated (HT) and laminated in the form of a vehicle windshield said coated article has a visible transmittance of at least 70%, a T solar no greater than 50%, an R solar of at least 26%, a sheet resistance (R s ) of no greater than 8.0 ohms/sq, a glass side reflective color coordinate value a* G (normal viewing angle) in the range of from −2.0 to +2.0; and
wherein said glass side reflective color coordinate value a* G does not change by more than 3.0 upon a 60° change in viewing angle (VA) from normal; and
wherein said dielectric layer a) and/or said dielectric layer i) includes both Si and Zr and does not directly contact any contact layer, and wherein the metal portion of the dielectric layer a) and/or i), said metal portion not including Si because Si is a non-metal, consists of Zr.
2. The coated article of claim 1 , further characterized after lamination and heat treatment by:
Characteristic
Value Range
R g Y (normal VA):
<= 11%
R g Y (60° VA):
<= 18%
a* g (60° VA):
−2.0 to +2.0
Δa* (60° VA change):
<= 2.0.
3. The coated article of claim 2 , wherein after heat treatment and lamination said coated article has a reflective glass side b* value of from −1.0 to −12.0.
4. A coated article including a multi-layer coating supported by a glass substrate, the coating comprising from the substrate outwardly at least the following layers:
a) a dielectric layer;
b) a layer comprising zinc oxide, and another layer provided between at least layers (a) and (b);
c) a first layer comprising silver;
d) a layer comprising metal oxide;
e) a second layer comprising silver;
f) a contact layer;
g) a layer comprising zinc oxide;
h) a dielectric layer over and contacting the layer g);
wherein the coated article has a visible transmission of at least 70%, a T solar no greater than 50%, and sheet resistance (R s ) no greater than 8 ohms/square; and
wherein said dielectric layer h) includes both Si and Zr and does not contact any contact layer where a contact layer is a layer that contacts a layer comprising silver, and wherein the metal portion of the dielectric layer h), said metal portion not including Si because Si is a non-metal, consists of Zr.
5. The coated article of claim 4 , wherein the coated article is heat treated, and is provided in the context of an IG unit or a vehicle windshield.
6. The coated article of claim 4 , wherein the coated article has a glass side reflective color a* (normal viewing angle) of from −2 to +2.
7. The coated article of claim 4 , wherein glass side reflective color value a* of the coated article does not change by more than 3.0 upon a 60 degree change in viewing angle from normal.
8. The coated article of claim 4 , wherein the coated article is heat treated, and after heat treatment has a glass side reflective b* value of from −1.0 to −12.0.
9. The coated article of claim 4 , wherein layer a) comprises a nitride of Si and Zr.
10. The coated article of claim 4 , wherein layer h) further includes nitrogen.