Photoelectric ion source photocathode regeneration system
View Patent ↗An explosive detection system based on an ion mobility spectrometer detects the presence of trace molecules in air. Such instruments require an ion source to ionize the trace molecules. An ion source that does not require a radioactive source to operate can use the photoelectric effect to produce electrons. Such a photoelectric ion source will gradually be contaminated and lose its photoelectron emission properties when operated in the air. The photocathode of the ion source can be automatically regenerated by a heater in thermal communication with the photocathode. The heater may be activated when the photoelectron emission falls below a predetermined value ro may run or cycle continuously.
1. An ion mobility spectrometer, comprising:
a chamber;
a photocathode and an anode that provide an electric field within said chamber;
a source of ultraviolet wavelength photons in optical communication with said photocathode;
a heater in thermal communication with said photocathode; and
a temperature control system that raises the temperature of the photocathode independent of any other heaters provided with said ion mobility spectrometer, whereby said heater in thermal communication with said photocathode provides regeneration and cleaning of said photocathode.
2. An ion mobility spectrometer, according to claim 1 , wherein a flow of gas through said chamber includes at least one chemical to be analyzed by said ion mobility spectrometer and wherein residue from said at least one chemical is removed from said photocathode by said heater.
3. An ion mobility spectrometer, according to claim 1 , wherein said photocathode has a surface that is electrically conductive.
4. An ion mobility spectrometer, according to claim 3 , wherein said surface is at least one of: a noble metal and a semiconductor.
5. An ion mobility spectrometer, according to claim 3 , wherein said photocathode surface is at least one of: a semitransparent coating, a non-transparent coating, a solid plate, a needle, a wire, and a mesh.
6. An ion mobility spectrometer, according to claim 5 , wherein said surface is mounted on an optically transparent window.
7. An ion mobility spectrometer, according to claim 6 , wherein said optically transparent window consists of a material selected from one of: sapphire, quartz, calcium fluoride, and magnesium fluoride.
8. An ion mobility spectrometer, according to claim 1 , wherein said source of ultraviolet photons is selected from one of: an arc discharge in an inert gas and an ultraviolet emitting light emitting diode.
9. An ion mobility spectrometer, according to claim 1 , wherein said optical communication is provided by at least one of an optically transparent window, a fiber optic, a mirror, an optical waveguide, and a lens.
10. An ion mobility spectrometer, according to claim 1 , wherein said anode is charged to a voltage that is positive relative to said photocathode at least while said photocathode is illuminated with said ultraviolet wavelength photons.
11. An ion mobility spectrometer, according to claim 1 , wherein said heater heats said photocathode to a temperature greater than 175 degrees centigrade.
12. An ion mobility spectrometer, according to claim 1 , wherein said heater independently heats said photocathode to a temperature at least 50 degrees centigrade greater than the normal operating temperature of said ion mobility spectrometer in order to regenerate the photocathode.
13. An ion mobility spectrometer, according to claim 1 , wherein said independent temperature control system is operated to heat said photocathode in response to the rate of photoelectron emission falling below a predetermined value.
14. An ion mobility spectrometer, according to claim 1 , wherein the heater is a wire.
15. An ion mobility spectrometer, according to claim 1 , wherein the heater uses heater tape.
16. An ion mobility spectrometer, according to claim 1 , wherein the heater uses conductive ink.
17. A method of operating an ion mobility spectrometer, comprising:
providing sampling gas flow from an external gas sampling inlet of the ion mobility spectrometer proximal to an ion source;
providing ultraviolet photons to a photocathode to emit electrons therefrom;
accelerating electrons emitted from the photocathode using a voltage between an anode and the photocathode in order to produce ions therefrom;
accelerating ions through a drift tube to a current collector;
measuring current reaching the current collector; and
raising the temperature of the photocathode independent of any other heaters provided with the ion mobility spectrometer to provide regeneration and cleaning of the photocathode in response to the rate of photoelectron emission falling below a predetermined value.
18. A method, according to claim 17 , further comprising:
heating the photocathode to a temperature greater than 175 degrees centigrade.
19. A method, according to claim 17 , further comprising:
heating the photocathode to a temperature at least 50 degrees centigrade greater than the normal operating temperature of the ion mobility spectrometer in order to regenerate the photocathode.