Recording sheet for ink jet printing
View Patent ↗A method for the preparation of silicon dioxide dispersions is described, wherein the surface of the silicon dioxide is modified by a treatment with the reaction products of a compound of trivalent aluminum with least one aminoorganosilane. These reaction products are formed in a separate reaction step. The present invention also relates to recording sheets for ink jet printing having such a dispersion incorporated in an ink-receiving layer.
1. A recording sheet for ink jet printing having coated onto a support at least one ink-receiving layer consisting of at least one binder and at least one dispersion of surface modified silicon dioxide, wherein the surface of the silicon dioxide consists of the reaction products of a compound of trivalent aluminum selected from the group consisting of aluminum chloride, aluminum nitrate, aluminum acetate, aluminum formiate, aluminum chlorohydrate and mixtures thereof with at least one aminoorganosilane;
wherein said dispersion of surface modified silicon dioxide primary particle size is between 1 nm and 30 nm; a quantity of said compound of trivalent aluminum is between 0.1 percent by weight and 20 percent by weight relative to the quantity by weight of said silicon dioxide; a quantity of said aminoorganosilane is between 0.1 percent by weight and 10 percent by weight relative to the quantity by weight of said silicon dioxide; and a molar ratio of said compound of trivalent aluminum and said aminoorganosilane is between 0.1 and 2.0.
2. The recording sheet according to claim 1 , wherein said binder is selected from the group consisting of polyvinyl alcohol, gelatin, derivatives of polyvinyl alcohol, polyvinylpyrrolidone and mixtures thereof.
3. The recording sheet according to claim 1 , wherein the recording sheet is hardened with boric acid.
4. The recording sheet according to claim 1 , wherein the recording sheet contains a plurality of ink-receiving layers.
5. The recording sheet according to claim 4 , wherein each ink-receiving layer contains as the surface modified silicon dioxide a fumed silicon dioxide having a different specific surface area.
6. The recording sheet according to claim 4 , wherein each ink-receiving layer contains as the surface modified silicon dioxide a fumed silicon dioxide wherein the surface of the silicon dioxide consists of the reaction products of the compound of trivalent aluminum selected from the group consisting of aluminum chloride, aluminum nitrate, aluminum acetate, aluminum formiate, aluminum chlorohydrate and mixtures thereof with the at least one aminoorganosilane.
7. The recording sheet according to claim 4 , wherein each ink-receiving layer has a different ratio of binder to silicon dioxide.
8. The recording sheet according to claim 4 , wherein each ink-receiving layer is hardened with different amounts of boric acid.
9. The recording sheet according to claim 1 , wherein said support is selected from the group consisting of coated or uncoated paper, transparent or opaque polyester or polypropylene and fibrous textile materials.
10. The recording sheet according to claim 1 , wherein the recording sheet is manufactured by extrusion coating, air knife coating, doctor blade coating, cascade coating or curtain coating.
11. The recording sheet according to claim 1 , wherein said reaction products contain Al—O—Si linkages.
12. The recording sheet according to claim 1 , wherein the quantity of said compound of trivalent aluminum is from 0.5 to 10 percent by weight relative to the quantity by weight of silicon dioxide.
13. The recording sheet according to claim 1 , wherein the quantity of said aminoorganosilane is from 0.5 to 10 percent by weight relative to the quantity by weight of silicon dioxide.
14. The recording sheet according to claim 1 , wherein said silicon dioxide is fumed silicon dioxide.
15. The recording sheet according to claim 14 , wherein said fumed silicon dioxide has a specific surface area between 20 m 2 /g and 400 m 2 /g.