Method for obtaining bitumen from tar sands
View Patent ↗A method and a system for obtaining bitumen from tar sand are disclosed. The disclosed method can include two extraction steps, such as a first extraction step using a light aromatic solvent and a second extraction step using a volatile hydrocarbon solvent. The light aromatic solvent and the volatile hydrocarbon solvent both can be recycled and used in multiple extractions. Each extraction and recycling step can include a separation. The disclosed system can include separators configured to perform these separations. Some of these separators also can function as mixers. Using the disclosed method and system, it is possible to achieve a high degree of bitumen recovery while minimizing undesirable complications, such as swelling of clays in the tar sand and/or precipitation of asphaltenes.
1. A method for obtaining bitumen, comprising:
mixing a material comprising bitumen with a light aromatic solvent to form a first mixture;
separating the first mixture into a bitumen-enriched light aromatic solvent phase and a bitumen-depleted sand phase;
mixing the bitumen-depleted sand phase with a volatile hydrocarbon solvent to form a second mixture; and
separating the second mixture into a bitumen-enriched volatile hydrocarbon solvent phase and a residual sand phase.
2. The method according to claim 1 , wherein the material comprising bitumen is tar sand.
3. The method according to claim 1 , wherein mixing the material comprising bitumen with the light aromatic solvent comprises mixing the material comprising bitumen with the light aromatic solvent in a countercurrent process.
4. The method according to claim 1 , wherein separating the first mixture into the bitumen-enriched light aromatic solvent phase and the bitumen-depleted sand phase comprises settling the bitumen-depleted sand phase.
5. The method according to claim 1 , wherein separating the first mixture into the bitumen-enriched light aromatic solvent phase and the bitumen-depleted sand phase comprises filtering the bitumen-depleted sand phase from the first mixture.
6. The method according to claim 1 , wherein separating the first mixture into the bitumen-enriched light aromatic solvent phase and the bitumen-depleted sand phase comprises separating the bitumen-depleted sand phase by gravity drainage.
7. The method according to claim 1 , wherein mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent comprises mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent in a countercurrent process.
8. The method according to claim 1 , wherein mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent comprises mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent in a batch process.
9. The method according to claim 1 , wherein mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent comprises mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent at a pressure sufficient to maintain the volatile hydrocarbon solvent in a liquid form.
10. The method according to claim 1 , wherein mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent comprises mixing the bitumen-depleted sand phase with the volatile hydrocarbon solvent at a pressure between about 20 kPa and about 1000 kPa.
11. The method according to claim 1 , wherein separating the second mixture into the bitumen-enriched volatile hydrocarbon solvent phase and the residual sand phase comprises separating the second mixture in a batch process.
12. The method according to claim 1 , wherein the light aromatic solvent comprises kerosene, diesel, gas oil, naphtha or a combination or derivative thereof.
13. The method according to claim 1 , wherein the light aromatic solvent comprises naphtha.
14. The method according to claim 1 , wherein the light aromatic solvent comprises gas oil.
15. The method according to claim 1 , wherein the light aromatic solvent comprises benzene, toluene, an aromatic alcohol or a combination or derivative thereof.
16. The method according to claim 1 , wherein the light aromatic solvent has a boiling temperature less than about 200° C.
17. The method according to claim 1 , wherein the volatile hydrocarbon solvent comprises a cyclo- or iso-paraffin having between 3 and 9 carbons or a combination or derivative thereof.
18. The method according to claim 1 , wherein the volatile hydrocarbon solvent comprises butane.
19. The method according to claim 1 , wherein the volatile hydrocarbon solvent has a boiling temperature between about −20° C. and about 150° C.
20. The method according to claim 1 , wherein the material comprising bitumen has a bitumen concentration of between about 3% and about 20% by weight prior to mixing with the light aromatic solvent and the bitumen-depleted sand phase has a bitumen concentration of between about 0.5% and about 5% by weight prior to mixing with the volatile hydrocarbon solvent.
21. The method according to claim 1 , wherein the material comprising bitumen has a bitumen concentration of between about 3% and about 20% by weight prior to mixing with the light aromatic solvent and the residual sand phase has a bitumen concentration of between about 0.01% and about 2% by weight.
22. The method according to claim 1 , further comprising transporting the material comprising bitumen and the light aromatic solvent through a pipeline or mixing the material comprising bitumen and the light aromatic solvent in a pipeline.
23. The method according to claim 1 , further comprising removing a portion of the volatile hydrocarbon solvent or a portion of the light aromatic solvent from the residual sand phase after separating the second mixture into the bitumen-enriched volatile hydrocarbon solvent phase and the residual sand phase.
24. The method according to claim 1 , further comprising separating the bitumen-enriched light aromatic solvent phase into a bitumen product and a recovered light aromatic solvent.
25. The method according to claim 24 , wherein the material comprising bitumen is a first quantity of material comprising bitumen and further comprising mixing a second quantity of material comprising bitumen with the recovered light aromatic solvent.
26. The method according to claim 24 , wherein separating the bitumen-enriched light aromatic solvent phase into the bitumen product and the recovered light aromatic solvent comprises heating the bitumen-enriched light aromatic solvent phase to a temperature greater than or equal to about a boiling temperature of the light aromatic solvent.
27. The method according to claim 24 , wherein separating the bitumen-enriched light aromatic solvent phase into the bitumen product and the recovered light aromatic solvent comprises heating the bitumen-enriched light aromatic solvent phase to a temperature between about 70° C. and about 170° C.
28. The method according to claim 1 , further comprising separating the bitumen-enriched volatile hydrocarbon solvent phase into a bitumen product and a recovered volatile hydrocarbon solvent.
29. The method according to claim 28 , wherein the bitumen-depleted sand phase is a first quantity of bitumen-depleted sand phase and further comprising mixing a second quantity of bitumen-depleted sand phase with the recovered volatile hydrocarbon solvent.
30. The method according to claim 28 , wherein separating the bitumen-enriched volatile hydrocarbon solvent phase into the bitumen product and the recovered volatile hydrocarbon solvent comprises reducing the pressure of the bitumen-enriched volatile hydrocarbon solvent phase.
31. The method according to claim 1 , wherein the material comprising bitumen is at about room temperature when mixing the material comprising bitumen with the light aromatic solvent to form the first mixture.
32. A method for obtaining bitumen, comprising:
mixing a first quantity of tar sand with a light aromatic solvent to form a first mixture;
separating the first mixture into a bitumen-enriched light aromatic solvent phase and a first quantity of bitumen-depleted sand phase;
separating the bitumen-enriched light aromatic solvent phase into a first bitumen product and a recovered light aromatic solvent;
mixing the recovered light aromatic solvent with a second quantity of tar sand;
mixing the first quantity of bitumen-depleted sand phase with a volatile hydrocarbon solvent to form a second mixture;
separating the second mixture into a bitumen-enriched volatile hydrocarbon solvent phase and a residual sand phase;
separating the bitumen-enriched volatile hydrocarbon solvent phase into a second bitumen product and a recovered volatile hydrocarbon solvent; and
mixing the recovered volatile hydrocarbon solvent with a second quantity of bitumen-depleted sand phase.