Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom
View Patent ↗A thermoplastic composition comprising a polycarbonate, and an aromatic sulfonate compound of formula: Ar 1 —S(O) 2 —O—L—O—S(O) 2 —Ar 1 wherein each Ar 1 is each independently a substituted or unsubstituted C 6-20 aryl group, and L is a branched, substituted or unsubstituted divalent aliphatic hydrocarbon, wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
1. A thermoplastic composition comprising:
a polycarbonate, and
an aromatic sulfonate compound of formula:
Ar 1 —S(O) 2 —O—L—O—S(O) 2 —Ar 1
wherein each Ar 1 is independently a substituted or unsubstituted aryl group, and L is a substituted or unsubstituted, branched divalent aliphatic hydrocarbon wherein the branch is within three carbon atoms of a linking oxygen of a sulfonyl group, and
wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article.
2. The thermoplastic composition of claim 1 , comprising 0.001 to 500 mmol/Kg of the aromatic sulfonate compound, based on the total weight of the polycarbonate and aromatic sulfonate compound.
3. The thermoplastic composition of claim 1 , comprising 0.001 to 5 mmol/Kg of the aromatic sulfonate compound, with the proviso that the amount of aromatic sulfonate compound does not exceed 0.5 wt. % of the total weight of the polycarbonate and aromatic sulfonate compound.
4. The thermoplastic composition of claim 1 , wherein each Ar 1 is a C 1-8 alkyl-substituted phenyl group.
5. The thermoplastic composition of claim 1 , wherein L is a substituted or unsubstituted, branched, C 3-18 alkylene group; a substituted or unsubstituted, branched C 3-18 alkylidene group; or a substituted or unsubstituted, branched C 3-8 cycloalkylene group.
6. The thermoplastic composition of claim 1 , wherein L is an unsubstituted, branched C 3-18 alkylene group, or an unsubstituted, branched C 3-18 alkylidene group.
7. The thermoplastic composition of claim 1 , further comprising an ionizing radiation stabilizing additive.
8. The thermoplastic composition of claim 7 , wherein the ionizing radiation stabilizing additive is an aliphatic alcohol, an aromatic alcohol, an aliphatic diol, an aliphatic polyol, an aliphatic ether, an esters, a diketone, an alkene, a thiol, thioethers, a cyclic thioether, a sulfone, a dihydroaromatic, a diether, a nitrogen compound, or a combination comprising at least one of the foregoing.
9. The thermoplastic composition of claim 8 wherein the aliphatic diol has the structure:
HO—(C(A′)(A″)) c —S—(C(B′)(B″)) d —OH
wherein A′, A″, B′, and B″ are each individually H or C 1 -C 6 alkyl; and wherein S is C 1 -C 20 alkyl, C 2 -C 20 alkyleneoxy, C 3 -C 6 cycloalkyl, or C 3 -C 6 substituted cycloalkyl; and wherein c and d are each 0 or 1, with the proviso that, where c and d are each 0, S is selected such that both —OH groups are not connected directly to a single common carbon atom.
10. The thermoplastic composition of claim 1 , wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 78 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 15, when compared to the unexposed molded article.
11. The thermoplastic composition of claim 1 , wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 59 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 9, when compared to the unexposed molded article.
12. The thermoplastic composition of claim 1 , wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 32 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 5.5, when compared to the unexposed molded article.
13. The thermoplastic composition of claim 1 , further comprising a hydrolysis stabilizer, wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, the hydrolysis stabilizer, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article.
14. The thermoplastic composition of claim 13 , wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, the hydrolysis stabilizer, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 51 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 13, when compared to the unexposed molded article.
15. The thermoplastic composition of claim 1 , further comprising an impact modifier, filler, antioxidant, heat stabilizer, light stabilizer, ultraviolet light absorber, plasticizer, mold release agent, lubricant, antistatic agent, pigment, dye, flame retardant, anti-drip agent, or a combination comprising at least one of these.
16. The thermoplastic composition of claim 15 wherein the pigment is Pigment Blue 15:4, Pigment Blue 28, or a combination comprising at least one of the foregoing.
17. The thermoplastic composition of claim 1 , wherein the aromatic sulfonate compound is 2-methyl-2,4-butanediol-di-p-toluenesulfonate.
18. A thermoplastic composition comprising:
a polycarbonate,
0.001 to 500 mmol/Kg of an aromatic sulfonate compound of formula:
Ar 1 —S(O) 2 —O—L—O—S(O) 2 —Ar 1
wherein each Ar 1 is independently a substituted or unsubstituted aryl group, and L is a substituted or unsubstituted, branched divalent aliphatic hydrocarbon wherein the branch is within three carbon atoms of a linking oxygen of a sulfonyl group, and
an ionizing radiation stabilizing additive,
wherein the amount of aromatic sulfonate compound is based on the total weight of the polycarbonate and aromatic sulfonate compound.
19. A method of making a thermoplastic composition comprising melt-blending:
a polycarbonate, and
an aromatic sulfonate compound of formula:
Ar 1 —S(O) 2 —O—L—O—S(O) 2 —Ar 1
wherein each Ar 1 is independently a substituted or unsubstituted aryl group, and L is a substituted or unsubstituted, branched divalent aliphatic hydrocarbon wherein the branch is within three carbon atoms of a linking oxygen of a sulfonyl group, and
wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article.
20. A masterbatch composition comprising
a polycarbonate, and
5 to 500 mmol/Kg of an aromatic sulfonate compound of formula:
Ar 1 —S(O) 2 —O—L—O—S(O) 2 —Ar 1
wherein each Ar 1 is independently a substituted or unsubstituted aryl group, and L is a substituted or unsubstituted, branched divalent aliphatic hydrocarbon wherein the branch is within three carbon atoms of a linking oxygen of a sulfonyl group, and
wherein the amount of aromatic sulfonate compound is based on the total weight of the polycarbonate and aromatic sulfonate compound, and wherein a thermoplastic composition comprises the masterbatch composition and a polycarbonate resin.
21. A method of making a thermoplastic composition comprising melt-blending:
a masterbatch comprising
a polycarbonate, and
an aromatic sulfonate compound of formula:
Ar 1 —S(O) 2 —O—L—O—S(O) 2 —Ar 1
wherein each Ar 1 is independently a substituted or unsubstituted aryl group, and L is a substituted or unsubstituted, branched divalent aliphatic hydrocarbon wherein the branch is within three carbon atoms of a linking oxygen of a sulfonyl group; with
a polycarbonate resin,
wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, the polycarbonate resin, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article.
22. An article comprising the thermoplastic composition of claim 1 .
23. The article of claim 22 , wherein the article has a thickness of 3.2±0.12 millimeters and a transmission of greater than 95% according to ASTM D1003-00, and wherein these properties are maintained after gamma irradiation at a total dose of up to 83 kGy.