Transparent compositions, methods for the preparation thereof, and articles derived therefrom
View Patent ↗A reaction product comprises a first polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, a second polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, and a transesterification catalyst. The reaction product has a haze of less than 1.7%, specifically less than 1.0% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.
1. A reaction product obtained by melt blending a combination comprising:
a first polymer comprising
aromatic ester units of formula
wherein T is a divalent aromatic radical and D 1 is a divalent aromatic radical, and
carbonate units of formula
wherein at least 60% of the total number of D 2 groups are divalent aromatic radicals and the balance thereof are divalent aliphatic, alicyclic, or aromatic radicals; and
a second polymer comprising
aromatic ester units having the formula
wherein T is a divalent aromatic radical and D 3 is a divalent aromatic radical, and
carbonate units having the formula
wherein at least 60% of the total number of D 4 groups are divalent aromatic radicals and the balance thereof are divalent aliphatic, alicyclic, or aromatic radicals; and
a transesterification catalyst,
wherein the reaction product has a haze of less than 1.0% measured at a thickness of 3.2 mm according to ASTM D1003-00; and wherein the first and second polymers are selected such that, in the absence of the transesterification catalyst, the similarly melt blended combination has a haze of greater than 1.0% measured at a thickness of 3.2 mm according to ASTM D1003-00.
2. The reaction product of claim 1 , wherein the first polymer comprises greater than or equal to 75 mole % aromatic ester units, and less than 25 mole % carbonate units, and where in the second polymer comprises less than 25 mole % aromatic ester units, and greater than or equal to 75 mole % carbonate units.
3. The reaction product of claim 1 , wherein the first polymer comprises greater than or equal to 80 mole % aromatic ester units, and less than 20 mole % carbonate units, and where in the second polymer comprises less than 20 mole % aromatic ester units, and greater than or equal to 80 mole % carbonate units.
4. The reaction product of claim 1 , wherein the first polymer and second polymer each further comprises a second carbonate unit, and wherein the second carbonate unit is a resorcinol carbonate unit.
5. The reaction product of claim 1 , wherein T is a residue of a mixture of isophthalic acid and terephthalic acid, and wherein each D 1 and D 3 is independently a resorcinol.
6. The reaction product of claim 1 wherein the transesterification catalyst is a tetra C 1 -C 6 alkyl phosphonium hydroxide, C 1 -C 6 alkyl phosphonium phenoxide, or a combination comprising one or more of the foregoing catalysts.
7. The reaction product of claim 1 having no observable phase separated regions as determined using transmission electron microscopy at a magnification of 66,000×.
8. A method for forming a reaction product, comprising melt blending a combination comprising:
a first polymer comprising
aromatic ester units of formula
wherein T is a divalent aromatic radical and D 1 is a divalent aromatic radical, and
carbonate units of formula
wherein at least 60% of the total number of D 2 groups are divalent aromatic radicals and the balance thereof are divalent aliphatic, alicyclic, or aromatic radicals; and
a second polymer comprising
aromatic ester units having the formula
wherein T is a divalent aromatic radical and D 3 is a divalent aromatic radical, and
carbonate units having the formula
wherein at least 60% of the total number of D 4 groups are divalent aromatic radicals and the balance thereof are divalent aliphatic, alicyclic, or aromatic radicals; and
a transesterification catalyst,
wherein the reaction product has a haze of less than 1.0% measured at a thickness of 3.2 mm according to ASTM D1003-00; and wherein the first and second polymers are selected such that, in the absence of the transesterification catalyst, the similarly melt blended combination has a haze of greater than 1.0% measured at a thickness of 3.2 mm according to ASTM D1003-00.
9. The method of claim 8 , wherein the first polymer comprises greater than or equal to 75 mole % aromatic ester units, and less than 25 mole % carbonate units, and where in the second polymer comprises less than 25 mole % aromatic ester units, and greater than or equal to 75 mole % carbonate units.
10. The method of claim 8 wherein the transesterification catalyst is present in an amount of 40 to 220 ppm.
11. A thermoplastic composition formed by the reaction product of claim 1 .
12. An article comprising the thermoplastic composition of claim 11 .
13. A thermoplastic composition comprising:
a reaction product obtained by melt blending a combination comprising:
a first polymer comprising
aromatic ester units of formula
wherein T is a divalent aromatic radical and D 1 is a divalent aromatic radical, and
carbonate units of formula
wherein at least 60% of the total number of D 2 groups are divalent aromatic radicals and the balance thereof are divalent aliphatic, alicyclic, or aromatic radicals; and
a second polymer comprising
aromatic ester units having the formula
wherein T is a divalent aromatic radical and D 3 is a divalent aromatic radical, and
carbonate units having the formula
wherein at least 60% of the total number of D 4 groups are divalent aromatic radicals and the balance thereof are divalent aliphatic, alicyclic, or aromatic radicals; and
a transesterification catalyst,
wherein the reaction product has a haze of less than 1.0% measured at a thickness of 3.2 mm according to ASTM D1003-00; and wherein the first and second polymers are selected such that, in the absence of the transesterification catalyst, the similarly melt blended combination has a haze of greater than 1.0% measured at a thickness of 3.2 mm according to ASTM D1003-00.
14. The thermoplastic composition of claim 13 , further comprising an additive selected from the group consisting of additional polymers, impact modifiers, fillers, reinforcing agents, thermal stabilizers, antioxidants, light stabilizers, gamma-irradiation stabilizers, plasticizers, colorants, antistatic agents, lubricants, mold releasing agents, flame retardants, anti-drip agents, and a combination comprising one or more of the foregoing additives.
15. The thermoplastic composition of claim 14 , wherein the additional polymers comprise polyesters, polysiloxane-polycarbonates, or a combination comprising one or more of the foregoing polymers.
16. The thermoplastic composition of claim 13 , wherein the reaction product separated from the additive has a haze of less than 1.0% at a thickness of 3.2 mm, according to ASTM D1003-00.
17. The thermoplastic composition of claim 13 , wherein the first polymer comprises greater than or equal to 75 mole % aromatic ester units, and less than 25 mole % carbonate units, and where in the second polymer comprises less than 25 mole % aromatic ester units, and greater than or equal to 75 mole % carbonate units.
18. The reaction product of claim 17 , wherein the first polymer comprises greater than or equal to 80 mole % aromatic ester units, and less than 20 mole % carbonate units, and where in the second polymer comprises less than 20 mole % aromatic ester units, and greater than or equal to 80 mole % carbonate units.
19. An article comprising the thermoplastic composition of claim 13 .
20. A reaction product of a combination comprising
a first polyester-polycarbonate copolymer, comprising ester units of the formula:
wherein the ester units comprise a mixture of terephthalate and isophthalate having a weight ratio of 91:9 to 2:98, wherein the mole percent of r is greater than or equal to 75 mole %, the mole % of s is 1 to 25 mole %, and the mole % of t is less than 25 mole %, and the sum of r+s+t equals 100 mole %; and
a second polyester-polycarbonate copolymer, comprising ester units of the formula:
wherein the ester units comprise a mixture of terephthalate and isophthalate having a weight ratio of 91:9 to 2:98, wherein the mole percent of r is less than 25 mole %, the mole % of s is 1 to 25 mole %, and the mole % of t is greater than or equal to 75 mole %, and the sum of r+s+t equals 100 mole %; and
40 to 220 ppm of a transesterification catalyst,
wherein the reaction product has a haze of less than 1.0%, measured at a thickness of 3.2 mm according to ASTM D1003-00.