IP Library Granted Patent US 7,282,276
Granted Patent B2
US 7,282,276 · App. 11/266,303 · Granted Oct 16, 2007

Organic electroluminescent device

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Quick Facts
Patent No.
US 7,282,276
App. No.
11/266,303
Granted
Oct 16, 2007
Kind
B2
Abstract

An organic electroluminescent device, which has: at least one organic layer between a pair of electrodes, with at least one layer of the at least one organic layer being a light-emitting layer, and at least one compound that has a structure represented by formula (2), as the compound itself or as its partial structure, in at least one layer of the at least one organic layer: wherein, in formula (2), each of A 1 , A 2 , A 3 , A 4 , A 5 , A 6 , A 7 , A 8 , A 9 , A 10 , A 11 , A 12 , A 13 , A 14 , A 15 , and A 16 represents a nitrogen atom or a carbon atom that may optionally have a substituent, and at least one of A 1 , A 2 , A 3 , A 4 , A 5 , A 6 , A 7 , A 8 , A 9 , A 10 , A 11 , A 12 , A 13 , A 14 , A 15 and A 16 is a nitrogen atom.

Claims (18)

1. An organic electroluminescent device, which comprises:

at least one organic layer between a pair of electrodes, with at least one layer of the at least one organic layer being a light-emitting layer, and

at least one compound selected from the group consisting of (a) a compound having a structure represented by formula (2) and (b) a compound having, as its partial structure, a group corresponding to (a), in at least one layer of the at least one organic layer:

wherein, in formula (2), each of A 1 , A 2 , A 3 , A 4 , A 5 , A 6 , A 7 , A 8 , A 9 , A 10 , A 11 , A 12 , A 13 , A 14 , A 15 , and A 16 represents a nitrogen atom or a carbon atom that may optionally have a substituent, and at least one of A 1 , A 2 , A 3 , A 4 , A 5 , A 6 , A 7 , A 8 , A 9 , A 10 , A 11 , A 12 , A 13 , A 14 , A 15 , and A 16 is a nitrogen atom.

2. The organic electroluminescent device as claimed in claim 1 , wherein the compound having a structure represented by formula (2) has one tetraphenylene structure.

3. The organic electroluminescent device as claimed in claim 1 , wherein the compound having, as its partial structure, a group corresponding to (a) is a compound selected from a bonded compound, an oligomer compound, and a polymer compound, in each of which a plurality of compounds having a structure represented by formula (2) bond together.

4. The organic electroluminescent device as claimed in claim 1 , wherein, in a tetraphenylene structure of the at least one compound selected from the group consisting of (a) a compound having a structure represented by formula (2) and (b) a compound having, as its partial structure, a group corresponding to (a), the number of nitrogen atoms that one six-membered ring has is 2 or less.

5. The organic electroluminescent device as claimed in claim 1 , wherein, of six-membered rings forming the tetraphenylene structure of the at least one compound selected from the group consisting of (a) a compound having a structure represented by formula (2) and (b) a compound having, as its partial structure, a group corresponding to (a), a six-membered ring having a nitrogen atom has no substituent.

6. The organic electroluminescent device as claimed in claim 1 , containing a phosphorescent material.

7. The organic electroluminescent device as claimed in claim 6 , wherein the phosphorescent material and the at least one compound selected from the group consisting of (a) a compound having a structure represented by formula (2) and (b) a compound having, its partial structure, a group corresponding to (a) are contained in the same layer.

8. The organic electroluminescent device as claimed in claim 6 , wherein the phosphorescent material is a transition metal complex.

9. The organic electroluminescent device as claimed in claim 1 , wherein at least one atom selected from A 1 , A 4 , A 5 , A 8 , A 9 , A 12 , A 13 , and A 16 is a nitrogen atom.

10. The organic electroluminescent device as claimed in claim 1 , wherein T 1 level, an energy level in a lowest triplet excitation state of the at least one compound selected from the group consisting of (a) a compound having a structure represented by formula (2) and (b) a compound having, as its partial structure, a group corresponding to (a), is at least 188.3 kJ/mol but not more than 355.6 kJ/mol.

11. The organic electroluminescent device as claimed in claim 1 , wherein the at least one compound selected from the group consisting of (a) a compound having a structure represented by formula (2) and (b) a compound having, as its partial structure, a group corresponding to (a) is contained in an electron-transporting layer or the light-emitting layer.

12. The organic electroluminescent device as claimed in claim 1 , wherein a light emission maximum wavelength of the organic electroluminescent device is 390 nm to 495 nm.

13. The organic electroluminescent device as claimed in claim 1 , wherein the substituent is selected from the group consisting of a halogen atom, an alkyl group, a cycloalkyl group, a bicycloalkyl group, an alkenyl group, a cycloalkenyl group, a bicycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an alkoxy group, an aryloxy group, a silyloxy group, a heterocyclic oxy group, an acyloxy group, a carbamoyloxy group, an alkoxycarbonyloxy group, an aryloxycarbonyloxy group, an amino group, an acylamino group, an aminocarbonylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, a sulfamoylamino group, an alkylsulfonylamino, an arylsulfonylamino group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclic thio group, a sulfamoyl group, a sulfo group, an alkylsulfinyl, an arylsulfinyl group, an alkylsulfonyl, an arylsulfonyl group, an acyl group, an aryloxycarbonyl group, an alkoxycarbonyl group, a carbamoyl group, an arylazo, a heterocyclic azo group, an imido group, a phosphino group, a phosphinyl group, a phosphinyloxy group, a phosphinylamino group, and a silyl group.

14. The organic electroluminescent device as claimed in claim 1 , wherein the substituent is selected from the group consisting of an alkyl group having 1 to 3 carbon atoms, a halogen atom, a substituted or unsubstituted aryl group having 6 to 12 carbon atoms, and a substituted or unsubstituted heterocyclic group having 1 to 10 carbon atoms.

15. A display comprising the organic electroluminescent device as claimed in claim 1 .

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 1, 2012
From: FUJIFILM CORPORATION
To: UDC IRELAND LIMITED
Reel/Frame 028889/0636 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2007
From: FUJIFILM HOLDINGS CORPORATION
To: FUJIFILM CORPORATION
Reel/Frame 018934/0001 →
CHANGE OF NAME Recorded Feb 15, 2007
From: FUJI PHOTO FILM CO., LTD.
To: FUJIFILM HOLDINGS CORPORATION
Reel/Frame 018898/0872 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 7, 2006
From: UCHIDA, OSAMU; OGASAWARA, JUN; SANO, SATOSHI
To: FUJI PHOTO FILM CO., LTD.
Reel/Frame 017241/0026 →