Process for treating synthetic silica powder and synthetic silica powder treated thereof
View Patent ↗A process for producing a synthetic quartz glass powder which is substantially free of carbon contaminant, for reduced bubble density and improved stability of articles made from the synthetic quartz glass during fusion molding by maintaining the synthetic silica powder in an oxidizing environment, e.g., an atmosphere comprising at least 3 vol. % ozone at a temperature of less than 1400° C., causing carbon containing compounds to be reduced to less than 10 ppm.
1. A method of purifying natural or synthetic silica powder by treating the silica powder in an oxidizing atmosphere comprising at least 3 vol. % ozone at a temperature of greater than 260° C. and less than 1400° C., to reduce carbon containing compound concentration in the silica powder to less than 10 ppm.
2. The method of claim 1 , wherein the silica powder is treated in an atmosphere comprising at least 5 to 20 vol. % ozone to reduce carbon containing compound concentration in the silica powder to less than 5 ppm.
3. The method of claim 1 , wherein the silica powder is treated in an atmosphere comprising at least 5 to 20 vol. % ozone to reduce carbon containing compound concentration in the silica powder to less than 2.5 ppm.
4. The method of claim 1 , wherein the silica powder is treated in an atmosphere comprising from about 5 to about 20 vol. %. ozone to reduce carbon residuals to less than 2 ppm and OH group concentration to less than 50 ppm.
5. The method of claim 1 , wherein the silica powder is treated in an atmosphere comprising at least 5 to 20 vol. % ozone at a temperature about 500° C. to about 1000° C.
6. The method of claim 1 , wherein the silica powder is maintained in an atmosphere containing at least 3 vol. % ozone at a temperature of greater than 260° C. and less than 1400° C., for a period ranging from about 30 minutes to 15 hours.
7. The method of claim 1 , wherein the silica powder is maintained in an atmosphere containing from 5 to 20 vol. % ozone at a temperature about 500 to about 1100° C., for a period of less than 12 hours.
8. The method of claim 1 , wherein the silica powder is treated in an atmosphere containing at least 20 vol. % oxygen at a temperature of greater than 260° C. less than 1000° C. to reduce carbon containing compound concentration in the silica powder to less than 10 ppm.
9. The method of claim 1 , wherein the silica powder is treated in an atmosphere containing at least 50 vol. % oxygen at a temperature ranging from about 500° C. to about 1000° C. to reduce carbon containing compound in the silica powder to less than 5 ppm.
10. The method of claim 1 , wherein the silica powder is treated in an atmosphere containing at least 50 vol. % oxygen at a temperature ranging from about 500° C. to about 1000° C. to reduce carbon containing compound in the silica powder to less than 5 ppm.
11. The method of claim 1 , wherein the silica powder is treated in an atmosphere containing at least 50 vol. % oxygen at a temperature ranging from about 500° C. to about 1000° C. for at least 5 hours to reduce carbon containing compound in the silica powder to less than 2.5 ppm.
12. The method of claim 1 , wherein the silica powder is treated in an atmosphere comprising hot air ranging from about 500° C. to about 1000° C. reduce carbon containing compound concentration to less than 5 ppm.
13. The process of claim 1 , wherein the silica powder treatment is carried out in a fluidized bed and wherein the oxidizing atmosphere is in a form of a treatment gas which is passed generally upward through the fluidized bed and the silica powder to be treated at a specific flow velocity.
14. The process of claim 13 , wherein the temperature of the fluidized bed is maintained at a treatment temperature in a range of about 500° C. to about 1000° C.
15. The process of claim 13 , wherein the treatment gas is heated prior to being introduced to the fluidized bed, to a temperature above the treatment temperature.
16. The process of claim 13 , wherein the treatment gas has a flow velocity of at least 10 cm/s.
17. The process of claim 13 , further comprising a first cleaning stage for the removal of metallic contaminations.
18. A method of purifying natural or synthetic silica by maintaining the silica powder under an oxidizing atmosphere comprising at least 60 vol. % oxygen and ozone at a temperature of less than 1000° C., causing carbon containing compounds to be driven off in gaseous form.
19. A method of producing synthetic silica having a carbon content of less than 5 ppm by heating a synthetic silica powder containing at least 45 ppm carbon content in an atmosphere comprising at least 3 vol. % ozone at a temperature of at least 200° C.
20. The method of claim 19 , wherein said atmosphere comprises 3 to 10 vol. % ozone, 50 to 75 vol. % helium, and 20 to 40 vol. % oxygen.
21. The method of claim 19 , wherein said heating is at a temperature of 200 to 1400° C. and from 2 to 24 hrs.
22. A method of purifying natural or synthetic silica, said method comprising treating said silica powder at a temperature of greater than 260° C. and less than 1400° C. with a gaseous stream comprising a sufficient amount of ozone to reduce carbon containing purities to a level of less than 5 ppm.
23. The method of claim 22 , wherein said gaseous stream comprises an ozone concentration of less than 10 vol. %.
24. A quartz article comprising silica powder purified by the process of claim 1 .