Photothermographic material and image forming method
View Patent ↗A photothermographic material including, on at least one side of a support, an image forming layer including at least a photosensitive silver halide, a first organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer which is disposed on the same side as the image forming layer and farther from the support than the image forming layer, wherein 50% or more of a total projected area of the photosensitive silver halide is occupied by tabular grains having a silver iodide content of 40 mol % or higher and an aspect ratio of 2 or more, and the non-photosensitive layer comprises a second organic silver salt, and an image forming method using the same. The invention provides a photothermographic material and an image forming method excellent in image tone and image storability.
1. A photothermographic material comprising, on at least one side of a support, an image forming layer comprising at least a photosensitive silver halide, a first organic silver salt, a reducing agent, and a binder, and at least one non-photosensitive layer which is disposed on the same side as the image forming layer and farther from the support than the image forming layer, wherein:
50% or more of a total projected area of the photosensitive silver halide is occupied by tabular grains having a silver iodide content of 40 mol % or higher and an aspect ratio of 2 or more; and
the non-photosensitive layer comprises a second organic silver salt.
2. The photothermographic material according to claim 1 , wherein the second organic silver salt contained in the non-photosensitive layer is at least one selected from a silver salt of a fatty acid, a silver salt of a mercapto compound, and a silver salt of a nitrogen-containing heterocyclic compound.
3. The photothermographic material according to claim 2 , wherein the silver salt of a fatty acid is a silver salt of a saturated fatty acid having 11 to 27 carbon atoms.
4. The photothermographic material according to claim 3 , wherein the silver salt of a fatty acid is at least one selected from the group consisting of silver behenate, silver stearate, silver arachidinate, and silver laurate.
5. The photothermographic material according to claim 2 , wherein the silver salt of a nitrogen-containing heterocyclic compound is a silver salt of an azole compound.
6. The photothermographic material according to claim 5 , wherein the silver salt of an azole compound is a silver salt of a benzotriazole compound.
7. The photothermographic material according to claim 2 , wherein the silver salt of a mercapto compound is a silver salt of a nitrogen-containing heterocyclic mercapto compound.
8. The photothermographic material according to claim 1 , wherein 50% by weight or more of a solvent of a coating solution for the image forming layer is water.
9. The photothermographic material according to claim 8 , wherein 50% by weight or more of the binder in the image forming layer is formed by a hydrophobic polymer latex.
10. The photothermographic material according to claim 1 , wherein 50% by weight or more of a solvent of a coating solution for the non-photosensitive layer is water.
11. The photothermographic material according to claim 10 , wherein 50% by weight or more of binder in the non-photosensitive layer is formed by a hydrophobic polymer latex.
12. The photothermographic material according to claim 10 , wherein 50% by weight or more of binder in the non-photosensitive layer is formed by a hydrophilic polymer.
13. The photothermographic material according to claim 1 , which comprises a second non-photosensitive layer between the image forming layer and the non-photosensitive layer comprising the second organic silver salt, wherein 50% by weight or more of binder in the second non-photosensitive layer is formed by a hydrophobic polymer latex.
14. The photothermographic material according to claim 13 , wherein the hydrophobic polymer latex is a polymer latex comprising a monomer component represented by the following formula (M):
CH 2 ═CR 01 —CR 02 ═CH 2 Formula (M)
wherein R 01 and R 02 each independently represent one selected from a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a halogen atom, or a cyano group.
15. The photothermographic material according to claim 14 , wherein in formula (M), both of R 01 and R 02 are a hydrogen atom, or one of R 01 or R 02 is a hydrogen atom and the other is a methyl group.
16. The photothermographic material according to claim 1 , wherein a mean equivalent spherical diameter of the tabular grains is from 0.3 μm to 8.0 μm.
17. The photothermographic material according to claim 1 , further comprising a silver iodide complex-forming agent.
18. The photothermographic material according to claim 1 , further comprising a nucleator.
19. The photothermographic material according to claim 1 , which comprises the image forming layer and the non-photosensitive layer on both sides of the support.
20. An image forming method comprising: bringing the photothermographic material according to claim 1 into contact with a fluorescent intensifying screen; X-ray imagewise exposing the photothermographic material; and thermal developing the photothermographic material, wherein the fluorescent intensifying screen comprises a fluorescent substance in which 50% or more of the emission light has a wavelength of 350 nm to 420 nm.