Selective catalyst reduction of nitrogen oxides with hydrogen
View Patent ↗A system and method for reducing nitrous oxides in diesel exhaust with hydrogen and carbon monoxide over a palladium based catalyst. The catalyst comprises a compound represented by the formula: X % Pd—Y % V 2 O 5 /Z, where X is between about 0.1 to about 2.0, Y is between about 0.1 to about 7.0, and Z is an oxide support.
1. An emissions system for selective catalytic reduction of nitrous oxides (NO x ) in lean-burn diesel engine exhaust, the system comprising:
a catalytic converter having at least one inlet, at least one outlet, and an interior working environment adapted to receive and dispel an exhaust;
a source of a reducing agent comprising H 2 and CO;
a catalyst disposed in the interior working environment, the catalyst comprising a compound represented by the formula:
X % Pd—Y % V 2 O 5 /Z, where X is a weight percent between about 0.1 to about 2.0, Y is a weight percent between about 0.1 to about 7.0, and Z is a high surface area oxide support material, and
a mixing element having a first input coupled to the reducing agent source, a second input coupled for receipt of diesel engine exhaust, and an output for injecting the diesel engine exhaust mixed with the reducing agent into the interior working environment of the converter where the catalyst reduces nitrous oxides present in the exhaust.
2. A system according to claim 1 , wherein the oxide support material is selected from the group consisting of TiO 2 , Al 2 O 3 , TiO 2 —Al 2 O 3 , Zeolites, Ti-PILC, and combinations thereof.
3. A system according to claim 1 , wherein the oxide support material comprises TiO 2 —Al 2 O 3 .
4. A system according to claim 1 , wherein the oxide support material is present in an amount having a loading per unit volume of between about 0.5 to about 10 g/in 3 .
5. A system according to claim 1 , wherein the catalyst comprises 1% Pd-5% V 2 O 5 /TiO 2 —Al 2 O 3 .
6. A system according to claim 1 , having a NO x reduction efficiency of at least about 87%.
7. A system according to claim 6 , having a NOx reduction efficiency of greater than about 95%.
8. A system according to claim 1 , operating at a temperature between about 125 and about 650° C.
9. A system according to claim 1 , wherein the reducing agent comprises a ratio of H 2 :CO of about 3:1.
10. A system according to claim 1 , wherein the reducing agent further comprises at least one hydrocarbon.
11. A system according to claim 1 , further comprising a fuel reformer located on-board a vehicle for producing the reducing agent by converting diesel fuel, oxygen, and moisture into H 2 and CO.
12. A system according to claim 1 , wherein the catalyst further comprises at least one promoter selected from the group consisting of: Ce, Mn, Zr, La, Gd, Nb, Pr, Nd, Sm, Eu, and combinations thereof.
13. A system according to claim 12 , wherein the at least one promoter is present in an amount between about 0.01 to about 20% by weight.
14. A system according to claim 1 , operating with the exhaust having a space velocity through the interior working environment of between about 9,000 and about 70,000 hr −1 .
15. A system according to claim 1 , operating with the exhaust having a flow rate of between about 200 and about 700 kg/hr.
16. A system according to claim 1 , wherein the catalyst comprises a honeycomb structure.
17. A method of selective catalytic reduction of nitrous oxides (NOx) in lean burn diesel engine exhaust, the method comprising:
providing a catalytic converter having at least one inlet, at least one outlet, and an interior working environment housing a catalyst and configured to receive and dispel exhaust;
mixing a diesel engine exhaust with a reducing agent comprising H 2 and CO; and
injecting the mixture into the interior working environment of the converter, wherein nitrous oxides present in the exhaust are reduced by the catalyst comprising a compound represented by the formula:
X % Pd—Y % V 2 O 5 /Z, where X is a weight percent between about 0.1 to about 2.0, Y is a weight percent between about 0.1 to about 7.0, and Z is a high surface area oxide support material.
18. A method according to claim 17 , wherein the catalyst comprises 1% Pd-5% V 2 O 5 /TiO 2 —Al 2 O 3 .
19. A method according to claim 17 , wherein the reducing agent comprises H 2 and CO at a ratio of about 3:1.
20. A method according to claim 17 , wherein the catalyst further comprises at least one promoter selected from the group consisting of: Ce, Mn, Zr, La, Gd, Nb, Pr, Nd, Sm, Eu, and combinations thereof.
21. A method according to claim 20 , wherein the at least one promoter is present in an amount between about 0.01 to about 20% by weight.