Method and materials for bonding electrodes to interconnect layers in solid oxide fuel cell stacks
View Patent ↗A method and related bonding compositions for use in assembling a solid oxide fuel cell (“SOFC”) stack having thermally and chemically stable and electrically conductive bonds between alternating fuel cells and interconnect components in the stack. The improved method and materials allow for the assembly of solid oxide fuel cells having a stronger and more reliable bond with good electrical contact in situ between the SOFC interconnect layers (plates) and the electrodes. The bonding materials and method according to the invention provide good electrical performance while maintaining the mechanical and electrical integrity of SOFC stacks without requiring excessive mechanical compression of the stack as exemplified by prior art systems. The preferred bonding agents comprise a primary phase that provides the electrical conduction path during fuel cell operation, as well as the mechanical strength necessary to insure a reliable connection between the interconnect and the relevant anode or cathode surfaces of the fuel cell. Secondary phases can be added in small amounts to the primary phase to improve adhesion. An exemplary method according to the invention also contemplates various different steps for pre-treating the surfaces of the interconnect plates and electrodes to improve their surface bonding properties.
1. A method for assembling solid oxide fuel cells into an integrated solid oxide fuel cell stack of the type having a plurality of cells each with a cathode and an anode separated by an electrolyte and a plurality of metallic, non-ceramic interconnect plates, said method comprising the steps of:
(a) pre-treating the surfaces of said metallic interconnect plates by applying an oxide coating comprising LSM, LSF, LSC, La 2 O 3 , manganese oxides, cobalt oxides or Mn—Co spinels to the cathode side interconnect surface, and applying a Ni, NiO, Co, CoO, or Ni 0.5 Co 0.5 O coating to the anode side interconnect surface;
(b) pre-treating the surfaces of said anodes to improve the bonding properties by applying an anode paste or a coating of organo-metallic compounds comprising Bi, Ni, Mn, Cu, Ce, and Co;
(c) introducing a cathode bonding agent between each one of said cathodes and the cathode side of each one of said metallic interconnect plates;
(d) introducing an anode bonding agent between each one of said anodes and the anode side of each one of said metallic interconnect plates;
(e) combining said plurality of electrodes and metallic interconnect plates having said bonding agents applied thereon into an integrated oxide fuel cell stack; and
(f) uniformly heating said integrated solid oxide fuel cell stack without applying a compressive load to a temperature in the range of about 600-1000° C. and for a period of time sufficient to permanently bond said metallic interconnect plates to said cathodes and anodes.
2. The method according to claim 1 , wherein the steps of introducing said anode and cathode bonding agents includes combining one or more conductive metals or ceramics with an organic fluid to form said bonding agents and applying said bonding agents to said electrodes and metallic interconnect plates in the form of a paste or slurry.
3. The method according to claim 2 , wherein said heating steps burn away the organic fluid leaving an electrically conductive material bonded to said electrodes and said metallic interconnect plates.
4. The method according to claim 1 , wherein the steps of introducing said anode and cathode bonding agents is accomplished by using a flexible tape or transfer film.
5. The method according to claim 1 , wherein said step of pre-treating the surfaces of said anodes uses spin coating, screen-printing, spraying or brushing to apply said coating followed by firing to burn out any organics and form a thin metal or metal oxide layer bonded to the anode surfaces.
6. The method according to claim 1 , wherein said step of pre-treating the surfaces of said anodes includes the use of a slurry or paste of the anode bond material applied to the sintered surfaces of said anodes and then fired at a temperature between about 800 and 1,300° C. to form rough surfaces for bonding with corresponding metallic interconnect layers.
7. A method according to claim 1 , wherein said cathode bonding agent comprises doped lanthanum strontium manganites (LSM), praseodymium strontium manganites (PSM), lanthanum strontium ferrites (LSF), lanthanum strontium cobaltities (LSC), Mn—(Co, Cr, Ni) spinels and a conductive pervoskite in the general form (La, Ce, Pr)—Sr—(Fe, Co, Ni, Mn)O 3 .
8. A method according to claim 1 , wherein said cathode bonding agent further comprises noble metals Pt, Pd, Rh, Ag, and their oxides, CuO, La 2 O 3 , SrO, manganese oxides, cobalt oxides, Li 2 O, doped ceria, zirconium oxide and TiO 2 .
9. A method for assembling solid oxide fuel cells into an integrated solid oxide fuel cell stack of the type having a plurality of cells each with a cathode and an anode separated by an electrolyte and a plurality of metallic interconnect plates, said method comprising the steps of:
(a) pre-treating the surface of said metallic interconnect plates by applying an oxide coating comprising LSM, LSF, LSC, La 2 O 3 , manganese oxides, cobalt oxides or Mn—Co spinels to the cathode side of said metallic interconnect plates and Ni, NiO, Co, CoO, or Ni 0.5 Co 0.5 O to the anode side of said metallic interconnect plates;
(b) introducing a cathode bonding agent between each one of said cathodes and the cathode side of each one of said metallic interconnect plates;
(c) introducing an anode bonding agent between each one of said anodes and the anode side of each one of said metallic interconnect plates;
(d) combining said plurality of electrodes and metallic interconnect plates having said bonding agents applied thereon into an integrated oxide fuel cell stack; and
(e) uniformly heating said integrated solid oxide fuel cell stack without applying a compressive load to a temperature in the range of about 600-1000° C. and for a period of time sufficient to bond said metallic interconnect plates to said cathodes and anodes.