Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
View Patent ↗A method of treating a subterranean formation by injecting down a well an aqueous fluid containing a viscoelastic surfactant fluid comprising an enhanced shear recovery agent wherein shear recovery time of the viscoelastic surfactant fluid is reduced by the addition of the enhanced shear recovery agent, and a viscoelastic surfactant fluid composition thereof.
1. A viscoelastic surfactant fluid comprising:
(i) a surfactant selected from the group consisting of amphoteric surfactant, zwitterionic surfactant, anionic surfactant, nonionic surfactant, cationic surfactant, and combinations thereof; and
(ii) an enhanced shear recovery agent to reduce shear recovery time, whereby said enhanced shear recovery agent is an ethyleneglycolethyletheracrylate derived copolymer.
2. The fluid of claim 1 , further comprising a component selected from the group consisting of an anionic polymer, a propant, organic acids, organic acid salts, organic salts, inorganic salts and combinations thereof.
3. The fluid of claim 1 wherein said ethyleneglycolethyletheracrylate is selected from the group consisting of diethyleneglycolethyletheracrylate, nonethyleneglycolmethyletheracrylate, poly-23-ethyleneglycolethyletheracrylate, and combinations thereof.
4. The fluid of claim 1 , further comprising an acid selected from the group consisting of hydrochloric acid, hydrofluoric acid, formic acid, acetic acid, polylactic acid, polyglycolic acid, lactic acid, glycolic acid, sulfamic acid, malic acid, citric acid, tartaric acid, maleic acid, methylsulfamic acid, chloroacetic acid, and combinations thereof.
5. A method of treating a subterranean formation comprising: injecting down a well an aqueous fluid comprising a viscoelastic surfactant and an enhanced shear recovery agent comprising an ethyleneglycolethyletheracrylate derived copolymer.
6. An oilfield treatment method comprising the steps of:
a). providing a fluid comprising a viscoelastic surfactant selected from the group consisting of amphoteric surfactant, zwitterionic surfactant, anionic surfactant, nonionic surfactant, cationic surfactant, and combinations thereof,
b). adding to the fluid a rheology enhancer in a concentration sufficient to shorten the shear recovery time of said fluid, said rheology enhancer being selected an ethyleneglycolethyletheracrylate derived copolymer; and
c). injecting said fluid down a well.
7. The method of claim 6 further wherein said rheology enhancer increases the viscosity of said fluid.
8. The method of claim 6 wherein said fluid further comprises an acid selected from the group consisting of hydrochloric acid, hydrofluoric acid, formic acid, acetic acid, polylactic acid, polyglycolic acid, lactic acid, glycolic acid, sulfamic acid, malic acid, citric acid, tartaric acid, maleic acid, methylsulfamic acid, chloroacetic acid, and combinations thereof.
9. The fluid of claim 1 having a shear recovery time of not longer than 15 seconds.
10. The method of claim 6 comprising adding to the fluid sufficient of said rheology enhancer to shorten the shear recovery time of said fluid to 15 seconds or less.
11. The method of claim 5 wherein the enhanced shear recovery agent is present in sufficient amount to shorten the shear recovery time of said aqueous fluid to 15 seconds or less.