Magnetic alloy material and method of making the magnetic alloy material
View Patent ↗A magnetic alloy material according to the present invention has a composition represented by Fe 100-a-b-c RE a A b Co c , where RE is a rare-earth element always including La, A is either Si or Al, 6 at %≦a≦11 at %, 8 at %≦b≦18 at %, and 0 at %≦c≦9 at %, and has either a two phase structure consisting essentially of an α-Fe phase and an (RE, Fe, A) phase including 30 at % to 90 at % of RE or a three phase structure consisting essentially of the α-Fe phase, the (RE, Fe, A) phase including 30 at % to 90 at % of RE and an RE(Fe, A) 13 compound phase with an NaZn 13 -type crystal structure. The respective phases have an average minor-axis size of 40 nm to 2 μm.
1. A method of making a magnetic alloy material, the method comprising the steps of:
preparing a melt of an alloy material having a predetermined composition; and
rapidly quenching and solidifying the melt of the alloy material such that an average quenching rate is 2×10 4 ° C./s to 2×10 6 ° C./s within the temperature range of 1,500° C. to 600° C., thereby obtaining a rapidly solidified alloy in which each particle of the magnetic alloy material has a composition represented by the formula: Fe 100-a-b-c RE a A b Co c , where RE is a rare-earth element that always includes La, A is either Si or Al, 6 at %≦a≦11 at %, 8 at %≦b≦18 at %, and 0 at %≦c≦9 at %, and has either a two phase structure consisting essentially of an α-Fe phase and an (RE, Fe, A) phase including 30 at % to 90 at % of RE or a three phase structure consisting essentially of the α-Fe phase, the (RE, Fe, A) phase including 30 at % to 90 at % of RE and an RE(Fe, A) 13 compound phase with an NaZn 13 -type crystal structure, the respective phases having an average minor-axis size of 40 nm to 2 μm.
2. The method of claim 1 , wherein the mole fraction a in the general formula is from 7 at % to 9 at %.
3. The method of claim 1 , wherein the (RE, Fe, A) phase is an REFeSi compound phase.
4. A method of making a magnetic alloy material, the method comprising the steps of:
preparing a melt of an alloy material having a predetermined composition; and
rapidly quenching and solidifying the melt of the alloy material such that an average quenching rate is 2×10 4 ° C./s to 2×10 6 ° C./s within the temperature range of 1,500° C. to 600° C., thereby obtaining a rapidly solidified alloy in which each particle of the magnetic alloy material has a composition represented by the formula: Fe 100-a-b-c RE a A b Co c , where RE is a rare-earth element that always includes La, A is either Si or Al, 6 at %≦a≦11 at %, 8 at %≦b≦18 at %, and 0 at %≦c≦9 at %, and has either a two phase structure consisting essentially of an αFe phase and an (RE, Fe, A) phase including 30 at % to 90 at % of RE or a three phase structure consisting essentially of the α-Fe phase, the (RE, Fe, A) phase including 30 at % to 90 at % of RE and an RE(Fe, A) 13 compound phase with an NaZn 13 -type crystal structure, the respective phases having an average minor-axis size of 40 nm to 2 μm, wherein Co substitutes for Fe in at least one of the α-Fe phase, the (RE, Fe, A) phase and the RE(Fe, A) 13 compound phase.
5. The method of claim 1 , wherein the rapidly solidified alloy has a thickness of 2 μm to 200 μm.
6. The method of claim 1 , wherein the step of obtaining the rapidly solidified alloy includes setting a teeming temperature of the alloy material higher than the liquidus temperature of the alloy material by 50° C. to 150° C.
7. The method of claim 1 , wherein the step of obtaining the rapidly solidified alloy includes controlling the roller peripheral velocity of a chill roller within the range of 3 m/s to 30 m/s.
8. The method of claim 1 , further comprising the step of pulverizing the rapidly solidified alloy, thereby making a powder, of which the particles have minor-axis sizes of 2 μm to 200 μm.
9. The method of claim 8 , wherein particles of the powder have a minor-axis size of less than 10 μm.
10. A method of making a sintered body of a magnetic alloy, the method comprising the steps of:
making the powder by the method of claim 8 ;
compacting the powder to make a compact; and
sintering the compact; wherein
the only heat-treatment of the powder is the sintering step.
11. The method of claim 10 , wherein the step of sintering includes sintering the compact within the temperature range of 600° C. to less than 1,320° C.
12. The method of claim 11 , wherein the step of sintering includes sintering the compact within the temperature range for ten seconds to eight hours.
13. The method of claim 1 , wherein no heat-treatment is conducted before pulverizing the rapidly solidified alloy.
14. The method of claim 4 , wherein no heat-treatment is conducted before pulverizing the rapidly solidified alloy.