Ce,Pr-coactivated calcium pyrophosphate phosphor and lamp containing same
View Patent ↗A UV-emitting, Ce,Pr-coactivated calcium pyrophosphate phosphor is provided wherein the Pr activator increases the phosphor's sensitivity to excitation by 185 nm radiation. The improved sensitivity to the 185 nm radiation allows the phosphor to make better use of the approximate 10% of the UV radiation that is emitted at 185 nm by a low pressure mercury discharge.
1. A UV-emitting phosphor comprising calcium pyrophosphate activated with cerium and praseodymium.
2. The phosphor of claim 1 wherein the phosphor is represented by a formula Ca (2−w−x−y−z) Ce x A y Pr z P 2 O 7 , where: A is a 1+ metal cation; w ranges from 0 to about 0.1; x ranges from about 0.04 to about 0.16; y ranges from 0 to about 0.25; and z ranges from greater than 0 to about 0.06.
3. The phosphor of claim 2 wherein y ranges from x+z−0.01 to x+z+0.01.
4. The phosphor of claim 2 wherein y=x+z.
5. The phosphor of claim 1 wherein the phosphor contains sodium in an amount up to about 0.25 moles Na per mole of phosphor.
6. The phosphor of claim 2 wherein A is Na + .
7. The phosphor of claim 6 wherein y ranges from x+z−0.01 to x+z+0.01.
8. The phosphor of claim 2 wherein x ranges from about 0.07 to about 0.12.
9. The phosphor of claim 2 wherein z ranges from greater than 0 to about 0.04.
10. The phosphor of claim 2 wherein w is equal to about 0.06.
11. The phosphor of claim 1 wherein the phosphor is represented by a formula Ca (2−w−x−y−z) Ce x Na y Pr z P 2 O 7 , where: w ranges from 0 to about 0.1; x ranges from about 0.04 to about 0.16; y ranges from 0 to about 0.25; and z ranges from greater than 0 to about 0.06.
12. The phosphor of claim 11 wherein y ranges from x+z−0.01 to x+z+0.01.
13. The phosphor of claim 12 wherein x ranges from about 0.07 to about 0.12.
14. The phosphor of claim 12 wherein z ranges from greater than 0 to about 0.04.
15. The phosphor of claim 12 wherein w is equal to about 0.06.
16. The phosphor of claim 11 wherein x ranges from about 0.07 to about 0.12 and z ranges from greater than 0 to about 0.04.
17. The phosphor of claim 16 wherein y ranges from x+z−0.01 to x+z+0.01.
18. The phosphor of claim 16 wherein y=x+z.
19. A lamp comprising a glass envelope having a phosphor coating on an interior surface, the phosphor coating containing a UV-emitting phosphor comprising calcium pyrophosphate activated with cerium and praseodymium.
20. The lamp of claim 19 wherein the phosphor is represented by a formula Ca (2−w−x−y−z) Ce x A y Pr z P 2 O 7 , where: A is a 1+ metal cation; w ranges from 0 to about 0.1; x ranges from about 0.04 to about 0.16; y ranges from 0 to about 0.25; and z ranges from greater than 0 to about 0.06.
21. A lamp comprising a glass envelope having a phosphor coating on an interior surface, the envelope being hermetically sealed and containing an amount of mercury and an inert gas, and the phosphor coating containing a UV-emitting Ca 2 P 2 O 7 :Ce,Pr phosphor.