Superconductive element containing Nb
A superconductive element containing Nb 3 Sn, in particular a multifilament wire, comprising at least one superconductive filament ( 8 ) which is obtained by a solid state diffusion reaction from a preliminary filament structure ( 1 ), said preliminary filament structure ( 1 ) containing an elongated hollow pipe ( 2 ) having an inner surface ( 3 ) and an outer surface ( 4 ), wherein said hollow pipe ( 2 ) consists of Nb or an Nb alloy, in particular NbTa, wherein the outer surface ( 4 ) is in close contact with a surrounding bronze matrix ( 5 ) containing Cu and Sn, and wherein the inner surface ( 3 ) is in close contact with an inner bronze matrix ( 5 ) also containing Cu and Sn, is characterized in that the inner bronze matrix ( 5 ) of the preliminary filament structure ( 1 ) encloses in its central region an elongated core ( 6 ) consisting of a metallic material, said metallic material having at room temperature (=RT) a thermal expansion coefficient α core <17*10 −6 K −1 , preferably α core ≦8*10 −6 K −1 , said metallic material having at RT a yield strength R p0,2 >300 MPa, said metallic material having at RT an elongation at rupture A>20%, and wherein the metallic material of the core ( 6 ) is chemically inert with respect to the material of the inner bronze matrix ( 5 ) up to a reaction temperature T of the solid state diffusion reaction. This element has improved superconductive properties in a large volume fraction of its superconductive filaments, in particular a high critical temperature T c and a high critical magnetic filed strength B c2 , and is mechanically stable enough for commercial applications such as magnet coils.
1. A superconductive element containing Nb 3 Sn, in particular a multifilament wire,
comprising at least one superconductive filament which is obtained by a solid state diffusion reaction from a preliminary filament structure, said preliminary filament structure containing an elongated hollow pipe having an inner surface and an outer surface,
wherein said hollow pipe consists of Nb or an Nb alloy, in particular NbTa, wherein the outer surface is in close contact with a surrounding bronze matrix containing Cu and Sn,
and wherein the inner surface is in close contact with an inner bronze matrix also containing Cu and Sn,
characterized in
that the inner bronze matrix of the preliminary filament structure encloses in its region an elongated core consisting of a metallic material, said metallic material of Ta or Ta alloy having at room temperature (=RT) a thermal expansion coefficient α core <17*10 −6 K −1 , preferably α core ≦8*10 −6 K −1 , said metallic material having at RT a field strength R p0.2 >300 Mpa, said metallic material having at RT an elongation at rupture A>20%, and wherein said metallic material of the core is chemically inert with respect to the material of the inner bronze matrix up to a reaction temperature T of the solid state diffusion reaction.
2. A superconductive element according to claim 1 , characterized in that the metallic material of the core comprises tantalum in an atomic concentration C Ta, core ≧95%.
3. A superconductive element according to claim 1 , characterized in that the metallic material of the core comprises
tungsten (W) in an atomic concentration C W, core ≦5%,
and/or molybdenum (Mb) in an atomic concentration C Mb, core ≦5%
and/or titanium (Ti) in an atomic concentration C Ti, core ≦5%,
and/or vanadium (V) in an atomic concentration C V, core ≦5%.
4. A superconductive element according to claim 1 , characterized in that the core is arranged coaxial with respect to the hollow pipe.
5. A superconductive element according to claim 1 , characterized in that the hollow pipe has a maximum outer diameter
d max, pipe with 3 μm≦20 μm, preferably 10 μm≦d max, pipe ≦15 μm.
6. A superconductive element according to claim 1 , characterized in that a core >0.05 a inner surface, in particular a core >0.1 a inner surface, with a core the cross-sectional area of the core, and a inner surface the cross-sectional area enclosed by the inner surface of the hollow pipe.
7. A superconductive element according to claim 1 , characterized in that the hollow pipe has a wall thickness w with 0.5 μm<w<10 μm, preferably 2 μm<w<5 μm, in particular w≈3 μm.
8. A superconductive element according to claim 1 , characterized in that the superconducting filament is obtained by a solid state diffusion reaction which is performed at a reaction temperature T with 400° C.≦T≦800° C., preferably 550° C.≦T≦700° C., in particular wherein the solid state diffusion reaction is done by high temperature isostatic pressing (=HP).
9. A method for producing a superconductive element according to claim 1 , characterized in that the superconducting filament is obtained by a solid state diffusion reaction which is performed in an oxygen-free atmosphere with a partial pressure of oxygen P O2 <=10 −5 mbar or in an inert atmosphere having substantially the air pressure of the environment, wherein the inert atmosphere preferably comprises Ar and/or N2.
10. A method for producing a superconductive element according to claim 1 , characterized in that the reaction conditions of the solid state diffusion reaction, in particular the reaction temperature T, the reaction time t, and/or the heating rates R are selected such that all Nb contained in the hollow pipe of the preliminary filament structure is reacted to Nb3Sn.
11. A method for producing a superconductive element according to claim 10 , characterized in that he reaction conditions of the solid state diffusion reaction, in particular the reaction temperature T, the reaction time t, and/or heating rates R are selected such that the atomic concentration of Sn in the Nb3Sn phase of the superconductive filament is at least 23%, preferably at least 24%.