Integrated cracking and metathesis process
View Patent ↗An integrated method that comprises a hydrocarbon thermal cracking operation to form at least one olefin product, coupled with dimerization and metathesis operations, the dimerization operation forming additional feed material for the metathesis operation, and the metathesis operation forming additional amounts of olefin product.
1. An integrated method for cracking an ethane containing feed and metathesizing ethylene to propylene, comprising thermally cracking said feed to form a first stream ( 16 ) containing ethane, ethylene and hydrocarbons heavier than ethane and ethylene and including 2-butenes, subjecting said first stream to a first fractional distillation ( 17 ) to form a second stream ( 18 ) containing at least some of said ethane and ethylene in said first stream and a third stream ( 24 ) containing predominantly said hydrocarbons in said first stream that are heavier than ethane and ethylene, recovering chemical grade propylene ( 65 ) from said third stream as a product of the overall process, subjecting a first portion ( 60 ) of said second stream to an ethylene dimerization operation to form a dimerization product stream ( 43 ) that contains newly formed butenes, subjecting a second portion ( 61 ) of said second stream to a metathesis operation wherein 2-butenes are subjected to disproportionation conditions in the presence of ethylene to form a propylene containing stream ( 50 ), passing said propylene containing stream from said metathesis operation as feed to said first fractional distillation, passing said dimerization product stream to a butene recovery operation to form a first butene containing stream ( 48 ), passing said first butene containing stream as feed to said metathesis operation, separating a second butene containing stream ( 26 ) from said third stream, and passing said second butene containing stream to said butene recovery operation.
2. The method of claim 1 wherein an ethylene stream ( 22 ) is recovered from said second stream as a product of the overall process.
3. The method of claim 1 wherein said butene containing product ( 43 ) from said ethylene dimerization operation contains at least in part 2-butenes that were newly formed in said dimerization operation.
4. The method of claim 1 wherein said 2-butenes that are disproportionated in the presence of ethylene in said metathesis operation are derived from both said thermal cracking ( 26 ) and said ethylene dimerization ( 43 ).
5. The method of claim 1 wherein said ethylene dimerization conditions include a temperature of from about 80 to about 150 F., a pressure of from about 100 to about 300 psig, and a nonaqueous liquid phase catalyst that favors the dimerization of ethylene.
6. The method of claim 5 wherein said catalyst is selected from the group consisting of aluminum alkyl halides arid nickel salt-phosphine complexes.
7. The method of claim 1 wherein said metathesis conditions include a temperature of from about 300 to about 800 F., a pressure of from about 200 to about 600 psig, a catalyst that favors the disproportionation of 2-butene in the presence of ethylene to propylene, and a weight hourly space velocity of from about 1 to about 100 reciprocal hours.