Epoxidation catalyst
View Patent ↗Titanium or vanadium zeolite catalysts are prepared by reacting a titanium or vanadium compound, a silicon source, a templating agent, a hydrocarbon, and a surfactant at a temperature and for a time sufficient to form a molecular sieve. The catalyst is useful in olefin epoxidation with hydrogen peroxide.
1. A process for producing a titanium or vanadium zeolite comprising reacting a titanium or vanadium compound, a silicon source, a templating agent, a hydrocarbon and a surfactant at a temperature and for a time sufficient to form a molecular sieve.
2. The process of claim 1 wherein the titanium compound is selected from the group consisting of titanium halides, titanium alkoxides, and mixtures thereof.
3. The process of claim 1 wherein the silicon source is selected from the group consisting of colloidal silica, fumed silica, silicon alkoxides, and mixtures thereof.
4. The process of claim 1 wherein the templating agent is selected from the group consisting of tetraalkylammonium hydroxide, tetraalkylammonium halides, and mixtures thereof.
5. The process of claim 1 wherein the hydrocarbon is selected from the group consisting of C 5 -C 12 aliphatic hydrocarbons, C 6 -C 12 aromatic hydrocarbons, C 1 -C 10 halogenated aliphatic hydrocarbons, C 6 -C 10 halogenated aromatic hydrocarbons, and mixtures thereof.
6. The process of claim 1 wherein the surfactant is selected from the group consisting of polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkyl ether, polyoxyethylene alkylallyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene octylphenyl ether, alkylene oxide adducts of acetylenic diols, and mixtures thereof.
7. A process for producing an epoxide comprising reacting an olefin and hydrogen peroxide in the presence of a titanium or vanadium zeolite, wherein the titanium or vanadium zeolite is produced by reacting a titanium or vanadium compound, a silicon source, a templating agent, a hydrocarbon, and a surfactant at a temperature and for a time sufficient to form a molecular sieve.
8. The process of claim 7 wherein the titanium compound is selected from the group consisting of titanium halides, titanium alkoxides, and mixtures thereof.
9. The process of claim 7 wherein the silicon source is selected from the group consisting of colloidal silica, fumed silica, silicon alkoxides, and mixtures thereof.
10. The process of claim 7 wherein the templating agent is selected from the group consisting of tetraalkylammonium hydroxide, tetraalkylammonium halides, and mixtures thereof.
11. The process of claim 7 wherein the hydrocarbon is selected from the group consisting of C 5 -C 12 aliphatic hydrocarbons, C 6 -C 12 aromatic hydrocarbons, C 1 -C 10 halogenated aliphatic hydrocarbons, C 6 -C 10 halogenated aromatic hydrocarbons, and mixtures thereof.
12. The process of claim 7 wherein the surfactant is selected from the group consisting of polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkyl ether, polyoxyethylene alkylallyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene nonylphenyl ether, polyoxyethylene octylphenyl ether, alkylene oxide adducts of acetylenic diols, and mixtures thereof.
13. The process of claim 7 wherein the titanium or vanadium zeolite is titanium silicalite.
14. The process of claim 7 wherein the olefin is a C 2 -C 6 olefin.
15. The process of claim 7 wherein the olefin is propylene.
16. The process of claim 7 wherein reaction of olefin and hydrogen peroxide is performed in a solvent selected from the group consisting of water, C 1 -C 4 alcohols, CO 2 , and mixtures thereof.
17. The process of claim 7 wherein the hydrogen peroxide is formed by the in situ reaction of hydrogen and oxygen in the presence of a noble metal catalyst.
18. The process of claim 17 wherein the noble metal catalyst comprises a noble metal and a support.
19. The process of claim 18 wherein the noble metal is selected from the group consisting of palladium, platinum, and gold.
20. The process of claim 18 wherein the support is carbon, titania, zirconia, niobium oxides, silica, alumina, silica-alumina, tantalum oxides, molybdenum oxides, tungsten oxides, titania-silica, zirconia-silica, niobia-silica, and mixtures thereof.
21. A process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of a noble metal-containing titanium or vanadium zeolite comprising a noble metal and a titanium or vanadium zeolite, wherein the titanium or vanadium zeolite is produced by reacting a titanium or vanadium compound, a silicon source, a templating agent, a hydrocarbon, and a surfactant at a temperature and for a time sufficient to form a molecular sieve.
22. The process of claim 21 wherein the titanium or vanadium zeolite is titanium silicalite.
23. The process of claim 21 wherein the olefin is a C 2 -C 6 olefin.
24. The process of claim 21 wherein the olefin is propylene.
25. The process of claim 21 wherein reaction of olefin, hydrogen and oxygen is performed in a solvent selected from the group consisting of water, C 1 -C 4 alcohols, CO 2 , and mixtures thereof.