Aqueous dispersions containing ionomer resins and rust-preventive ionomeric coatings made therefrom
View Patent ↗The present invention is directed to an aqueous dispersion composition which comprises an ethylene-unsaturated carboxylic acid ionomer resin (A) neutralized with a mixture of ions including at least one divalent metal ion and at least one ammonium ion, (B) a non-water soluble vapor phase corrosion inhibitor, and (C) water. The dispersion exhibits good shelf-life and excellent rust-prevention properties. Durable corrosion resistant ionomeric coatings can be easily formed therefrom, which when applied to metal surfaces and baked, can form a rust-preventive coating layer showing excellent coating adhesion both to the metal surface and to an over coat paint. Such coatings are particularly useful when applied to a vehicle body or part thereof.
1. An aqueous dispersion composition consisting of: (A) an ionomer resin neutralized or partially neutralized with a mixture of bases consisting of a base whose cation is a divalent metal cation and a base whose cation is an ammonium ion (NH 4 + ), (B) a non-water soluble vapor phase corrosion inhibitor, (C) water, and, optionally, (D) one or more additives selected from the group consisting of: other film-forming and/or crosslinking resins and water-soluble covalent curing agents;
wherein said other film-forming and/or crosslinking resins are selected from the group consisting of water-soluble polyester polyols and acrylics; wherein said water-soluble covalent curing agents are selected from the group consisting of amino resins; and wherein said amino resins are selected from the group consisting of water-soluble melamine resin, hexamethoxymelamine, methylolated benzoguanamine resins and methylolated urea resins.
2. The aqueous dispersion of claim 1 wherein the ionomer resin is an ethylene-unsaturated carboxylic acid copolymer having an acid content of 5-40 wt%.
3. The aqueous dispersion of claim 1 wherein the ionomer resin is an ethylene-acrylic or methacrylic acid copolymer having an acid content of 10-35 wt%.
4. The aqueous dispersion of claim 1 wherein the divalent metal ion is selected from the group consisting of Zn.
5. The aqueous dispersion of claim 1 wherein the dispersion has a solids content of 10 to 45 wt%.
6. An ionomeric coating composition, comprising the aqueous dispersion of any of claims 1 to 5 .
7. The ionomeric coating composition of claim 6 , further comprising one or more other additives selected from the group consisting of pigments, fillers, extenders, organic and inorganic thickeners, surface active agents, water-soluble polyvalent or monovalent metal salts, rust-preventive assistants that are not water soluble metal salts, mildew proofing agents, fungicides, biocides, ultraviolet absorbers, heat stabilizers, foaming agents, and rheology control agents.