Liquid crystal medium
View Patent ↗Liquid crystal (LC) media based on a mixture of polar compounds having negative dielectric anisotropy, their use in electro-optical displays, especially those having active matrix addressing based on the ECB (electrically controlled birefringence) or VA (vertically aligned) mode or similar modes, and LC displays of these types, are described.
1. A liquid crystal medium comprising, by weight:
5 to 27% of one or more compounds of formula I,
2 to 45% of one or more compounds of formula II,
12 to 23% of one or more compounds of formula III,
5 to 10% of one or more compounds of formula IV,
18 to 28% of one or more compounds of formula V,
0 to 12% of one or more compounds of formula VI,
0 to 14% of one or more compounds of formula VII,
0 to 18% of one or more compounds of formula VIII,
in which
R 1 and R 4 are independently of each other methyl, ethyl, n-propyl, n-butyl, n-pentyl or n-hexyl, R4 can also be methoxy,
R 2 is methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, methoxy, ethoxy, n-propoxy, n-butoxy or n-pentoxy,
R 3 is vinyl or 1E-propenyl.
2. A liquid crystal medium according to claim 1 , which comprises:
one, two or three compounds of formula I, wherein R 1 is n-propyl or n-pentyl and R 2 is ethoxy or n-butoxy,
one, two, three or four compounds of formula II, wherein R 1 is n-propyl, n-butyl or n-pentyl and R 2 is ethoxy or n-propoxy,
optionally one or two compounds of formula II, wherein R 1 is ethyl or n-butyl and R 2 is methyl,
one or two compounds of formula III, wherein R 1 is ethyl or n-propyl and R 2 is ethoxy or n-propoxy,
one or two compounds of formula IV, wherein R 1 is ethyl or n-propyl and R 2 is n-propyl or n-butyl,
one, two or three compounds of formula V, wherein R 1 is n-propyl, n-butyl or n-pentyl and R 3 is vinyl or 1E-propenyl,
optionally one compound of formula VI, wherein R 3 vinyl and R 1 methyl, and
optionally one or two compounds of formula VII, wherein R 1 is n-propyl and R 4 is n-butyl, n-pentyl or methoxy,
optionally one or two compounds of formula VIII, wherein R 1 is n-propyl or n-pentyl and R 2 is methoxy or n-propyl.
3. A liquid crystal medium according to claim 1 , which has a birefringence Δn from 0.09 to 0.12.
4. A liquid crystal medium according to claim 2 , which has a birefringence Δn from 0.09 to 0.12.
5. A liquid crystal medium according to claim 1 , which has a dielectric anisotropy Δ∈ from −2.5 to −3.5.
6. A liquid crystal medium according to claim 2 , which has a dielectric anisotropy Δ∈ from −2.5 to −3.5.
7. A liquid crystal medium according to claim 3 , which has a dielectric anisotropy Δ∈ from −2.5 to −3.5.
8. A liquid crystal medium according to claim 1 , which has a value of the dielectric constant perpendicular to the longitudinal molecular axes ∈⊥ from 5.8 to 6.8.
9. A liquid crystal medium according to claim 1 , which has a value of the dielectric constant perpendicular to the longitudinal molecular axes ∈⊥ from 5.8 to 6.8.
10. A liquid crystal medium according to claim 2 , which has a value of the dielectric constant perpendicular to the longitudinal molecular axes ∈⊥ from 5.8 to 6.8.
11. A liquid crystal medium according to claim 3 , which has a value of the dielectric constant perpendicular to the longitudinal molecular axes ∈⊥ from 5.8 to 6.8.
12. A liquid crystal medium according to claim 5 , which has a value of the dielectric constant perpendicular to the longitudinal molecular axes ∈⊥ from 5.8 to 6.8.
13. An electro-optical liquid crystal display containing a liquid crystal medium according to claim 1 .
14. An electro-optical liquid crystal display containing a liquid crystal medium according to claim 2 .
15. An electro-optical liquid crystal display containing a liquid crystal medium according to claim 3 .
16. An electro-optical liquid crystal display containing a liquid crystal medium according to claim 5 .
17. An electro-optical liquid crystal display containing a liquid crystal medium according to claim 8 .
18. An electro-optical display according to claim 13 , which has active matrix addressing and is based on the ECB, VA or ASV mode.