A highly safety cell is provided in which short-circuiting is unlikely to occur. In order to prevent short-circuiting, for example, burrs generated when a laminate film used as an exterior packaging material is cut are prevented from penetrating an interior resin layer of the laminate film. When an electrode terminal extension side of the laminate film is thermal welded, heating and compression are performed by a heater head on a part of the laminate film apart from the edge portion thereof so that the thickness of the above edge portion is larger than that of a thermal welded portion. In addition, thermal welding is performed so that the thickness of a thermal welded portion including an electrode terminal is larger than that of a thermal welded portion including no electrode terminal, and as a result, short-circuiting can be more effectively prevented.
1. A cell comprising:
a cell element including
(a) a positive electrode having a belt-shaped metal foil and reaction layers provided on two surfaces thereof,
(b) a negative electrode having a belt-shaped metal foil and reaction layers provided on two surfaces thereof, and
(c) an electrolyte;
a laminate film enclosing the cell element, the laminate film having a sealing portion and being composed of (a) an exterior resin layer, (b) an interior resin layer, and (c) a metal layer provided between the exterior resin layer and the interior resin layer, the sealing portion being thermal welded on a part of the laminate film apart from an edge portion thereof to form a thermal welded portion for sealing the cell;
electrode terminals electrically connected to the cell element and extending outside through the sealing portion; and
sealant between the laminate film and the electrode terminals,
wherein,
a portion A of the laminate film, remote from an edge of the laminate film, is thermal welded, and a portion B at the edge portion of the laminate film is not thermal welded,
portion B increases in thickness along a lengthwise direction of the electrode terminals proceeding from the portion A to the edge of the laminate film,
a thickness of the sealant on the electrode terminals is less at said portion A than said portion B,
the edge of the laminate film on the electrode terminals is not thermal welded such that the edge of the laminate film is thicker than said portion A,
a thickness t 2 of the laminate film at the edge thereof is larger than a thickness t 1 of the thermal welded portion, and
when the thickness of the laminate film and the thickness of the interior resin layer are represented by t and p, respectively, the following equations are satisfied:
t× 2- p× 2+5< t 1 < t× 2-5 (μm) and
t 1 < t× 2≦ t 2 (μm).
2. The cell according to claim 1 , wherein
the exterior resin layer includes nylon or poly(ethylene terephthalate),
the metal layer includes an aluminum foil, and
the interior resin layer includes a polyolefin resin.
3. The cell according to claim 1 , wherein the metal foil of the positive electrode is a positive electrode collector, and the reaction layers of the positive electrode are positive electrode active material layers each including
lithium cobalt oxide,
poly(vinylidene fluoride), and
graphite.
4. The cell according to claim 1 , wherein
the metal foil of the negative electrode is a negative electrode collector, and
the reaction layers of the negative electrode are negative electrode active material layers each including poly(vinylidene fluoride), and graphite.
5. The cell according to claim 1 , wherein the electrolyte is a gel electrolyte including a poly(vinylidene fluoride) copolymer incorporating hexafluoropropylene.
6. The cell according to claim 1 , wherein
the electrolyte is an electrolyte solution including
ethylene carbonate,
propylene carbonate, and
LiPF 6 .
7. The cell according to claim 1 , wherein
the electrolyte is a gel electrolyte including
a poly(vinylidene fluoride) copolymer incorporating
hexafluoropropylene,
ethylene carbonate,
propylene carbonate,
LiPF 6 , and
dimethyl carbonate, and
the gel electrolyte is provided on two surfaces of the positive electrode and two surfaces of the negative electrode for forming gel electrolyte layers.
8. The cell according to claim 1 , wherein
the cell element further includes a separator of a polyolefin material selected from one of a polypropylene resin and a polyethylene resin.
9. The cell according to claim 1 ,
wherein the cell element further includes a separator provided between the positive electrode and negative electrode,
the electrolyte is a gel electrolyte and is provided on two surfaces of the positive electrode and two surfaces of the negative electrode so as to form gel electrolyte layers, the gel electrolyte including
a poly(vinylidene fluoride) copolymer incorporating hexafluoropropylene,
ethylene carbonate,
propylene carbonate,
LiPF 6 , and
dimethyl carbonate, and
the cell element is a winding type cell element formed by the step of winding the positive electrode provided with the two gel electrolyte layers, the negative electrode provided with the two gel electrolyte layers, and the separator provided between the positive electrode and the negative electrode in a longitudinal direction.
10. The cell according to claim 1 , wherein the cell element further includes a separator provided between the positive electrode and negative electrode,
the electrolyte is a gel electrolyte and is provided on two surfaces of the positive electrode and two surfaces of the negative electrode so as to form gel electrolyte layers, the gel electrolyte including
a poly(vinylidene fluoride) copolymer incorporating hexafluoropropylene,
ethylene carbonate,
propylene carbonate,
LiPF 6 , and
dimethyl carbonate,
the cell element is a winding type cell element formed by the step of winding the positive electrode provided with the two gel electrolyte layers, the negative electrode provided with the two gel electrolyte layers, and the separator provided between the positive electrode and the negative electrode in a longitudinal direction, and the winding type cell element is packaged in the laminate film by thermal welding under vacuum conditions.
11. A cell comprising:
a cell element including
(a) a positive electrode having a belt-shaped metal foil and reaction layers provided on two surfaces thereof,
(b) a negative electrode having a belt-shaped metal foil and reaction layers provided on two surfaces thereof, and
(c) an electrolyte;
a laminate film enclosing the cell element, the laminate film having a sealing portion and being composed of (a) an exterior resin layer, (b) an interior resin layer, and (c) a metal layer provided between the exterior layer and the interior resin layer, the sealing portion being thermal welded to form thermal welded portions for sealing the cell;
electrode terminals electrically connected to the cell element and extending outside through the sealing portion;
resin material layers covering the electrode terminals, and
sealant between the laminate film and the electrode terminals,
wherein,
a portion A of the laminate film, remote from an edge of the laminate film, is thermal welded, and a portion B at the edge portion of the laminate film is not thermal welded,
a thickness of the sealant on the electrode terminals is less at said portion A than said portion B,
a thickness of the portion B increases along a lengthwise direction of the electrode terminals proceeding from the portion A to the edge of the laminate film,
the edge of the laminate film on the electrode terminals is not thermal welded such that the edge of the laminate film is thicker than said portion A,
a thickness t 4 of thermal welded portions including the electrode terminals is larger than a thickness t 3 of thermal welded portions including no electrode terminals, and
when the thicknesses of the laminate film, the interior resin layer of the laminate film, the electrode terminal, and one side of each of the resin material layers covering the electrode terminals are represented by t, p, L, and S, respectively, the following equations are satisfied:
20< p <40 (μm),
t× 2- p× 2+5< t 3 < t× 2-5 (μm), and
t× 2- p× 2+5+(L+S)<t 4 < t× 2-5+(L+S) (μm).