Filled propylene polymer compositions having improved melt strength
View Patent ↗Filled propylene polymer compositions having significantly improved melt strength are provided. The compositions are blends of propylene polymer, mineral filler with an ethylene polymer component consisting of an ethylene plastomer and a silane-containing ethylene polymer.
1. A filled propylene polymer composition having improved melt strength comprising:
(a) 50 to 85 weight percent propylene-ethylene copolymer base resin having a melt flow rate from 0.1 to 30 g/10 min and containing from 1 to 30 weight percent ethylene;
(b) 5 to 35 weight percent mineral filler; and
(c) 5 to 25 weight percent ethylene polymer component consisting of
(i) an ethylene-C 4-8 α-olefin plastomer and
(ii) a silane-containing polymer having 0.1 to 20 weight percent vinyltrimethoxysilane or vinyltriethoxysilane incorporated by copolymerization or grafting, the weight ratio of (i) to (ii) ranging from 2:5:1 to 1:2.
2. The composition of claim 1 wherein the propylene-ethylene copolymer is a thermoplastic polyolefin comprised of a crystalline propylene homopolymer phase and an ethylene-propylene rubber phase and having an ethylene content from 6 to 20 weight percent.
3. The composition of claim 1 wherein the mineral filler is selected from the group consisting of calcium carbonate, clay, talc, kaolinite, wollastonite, pyrophillite, magnesium hydroxide, oxides of zinc and magnesium, silica and silicates.
4. The composition of claim 3 wherein the mineral filler is talc having an average particle size between 0.2 and 10 microns.
5. The composition of claim 1 wherein the ethylene-C 4-8 α-olefin plastomer has a density of 0.86 to 0.92 g/cm 3 and melt index from 0.1 to 50 g/10 min.
6. The composition of claim 5 wherein the plastomer is a copolymer of ethylene and butene-1, hexene-1 or octene-1 and has a density of 0.86 to 0.90 g/cm 3 and melt index of 1 to 20 g/10 min.
7. The composition of claim 1 wherein the silane-containing polymer is a high density polyethylene or low density polyethylene grafted with from 0.25 to 7.5 weight percent vinyltrimethoxysilane.
8. The composition of claim 1 wherein the silane polymer is a copolymer of ethylene and 0.25 to 7.5 weight percent vinyltrimethoxysilane.
9. The composition of claim 1 which additionally contains 0.01 to 1 weight percent of a dispersing aid selected from the group consisting of maleated polypropylenes, silanes, neoalkoxy titanates, fatty acid metal soaps, fatty acid amides, fatty acid esters and low molecular weight aliphatic resins.
10. The composition of claim 1 which additionally contains 0.001 to 0.5 weight percent of a promoter selected from the group consisting of dibutyltin dilaurate, dioctyltin maleate, dibutyltin diacetate, dibutyltin dioctoate, stannous acetate, stannous octoate, lead naphthenate, zinc caprylate and cobalt naphthenate.
11. The composition of claim 1 comprised of 55 to 80 weight percent (a), 7.5 to 30 weight percent (b) and 7.5 to 20 weight percent (c).
12. The composition of claim 11 wherein (a) is a thermoplastic polyolefin comprised of a crystalline propylene homopolymer phase and an ethylene-propylene rubber phase and having an ethylene content from 1 to 30 weight percent, (b) is talc, (c) (i) is a copolymer of ethylene and butene-1, hexene-1 or octene-1 and has a density of 0.86 to 0.90 g/cm 3 and melt index of 1 to 20 g/10 min, and (c) (ii) is a copolymer of ethylene and 0.25 to 7.5 weight percent vinyltrimethoxysilane.
13. The composition of claim 11 having a melt flow rate of 0.1 to 30 g/10 min.