Molding compositions based on a thermoplastic polyester with improved flowability
This invention relates to thermoplastic molding compositions with improved flowability based on a thermoplastic polyester and on at least one copolymer composed of at least one olefin with at least one methacrylic ester or acrylic ester of an aliphatic alcohol, the MFI of the copolymer being not less than 50 g/10 min, to a process for preparation of these molding compositions, and also the use of these molding compositions for production of moldings for the electrical, electronics, telecommunications, motor vehicle or computer industry, in sports, in the household, in medicine or for the entertainment industry.
1. A thermoplastic molding composition comprising
A) from 99.9 to 10 parts by weight of at least one thermoplastic polyester and
B) from 0.1 to 20 parts by weight of at least one copolymer comprising at least one olefin and at least one methacrylic ester or acrylic ester of an aliphatic alcohol, the Melt Flow Index (MAI) of the copolymer B) being not less than 50 g/10 min.
2. The thermoplastic molding composition according to claim 1 , wherein less than 4% by weight of the copolymer B) is composed of monomer units containing further reactive functional groups selected from the group consisting of epoxides, oxetanes, anhydrides, imides, aziridines, furans, acids, amines, and oxazolines.
3. The thermoplastic molding composition according to claim 1 , wherein the methacrylic ester or acrylic ester of an aliphatic alcohol in the copolymer B) is 2-ethylhexyl acrylate.
4. The thermoplastic molding composition according to claim 3 , wherein the olefin in the copolymer B) is ethene.
5. The thermoplastic molding composition according to claim 1 , wherein the MFI of The copolymer B) is in The range between 80 and 900 g/10 min.
6. The thermoplastic molding composition according to claim 1 , further comprising one or more components chosen from the series of:
C) from 0.001 to 70 parts by weight of at least one filler or reinforcing material,
D) from 0.001 to 50 parts by weight of at least one flame retardant additive,
E) from 0.001 to 80 parts by weight of at least one elastomer modifier,
F) from 0.001 to 80 parts by weight of a polycarbonate, and
G) from 0.001 to 10 parts by weight of other conventional additives.
7. A process for preparing the thermoplastic molding composition according to claim 1 , comprising mixing the appropriate proportions by weight of components A) and B) of claim 1 .
8. A molding or a semifinished product obtained by injection molding or extrusion of the thermoplastic molding composition according to claim 1 .
9. A thermoplastic molding composition according to claim 1 , wherein the methacrylic ester or acrylic ester of en aliphatic alcohol in the copolymer B) is n-butyl acrylate.
10. A process for forming a molding or a semifinished product comprising:
providing the thermoplastic molding composition of claim 1 to an injection molding apparatus, and
injection molding said thermoplastic molding composition into said molding or semifinished product.
11. A process for forming a molding or a semifinished product comprising:
providing the thermoplastic molding composition of claim 1 to an extrusion apparatus, and
extruding said thermoplastic molding composition into said molding or semifinished product.
12. A molded article comprising:
a wall having a wall-thickness of less than 2.5 mm and wherein said molding article is formed of the thermoplastic molding composition of claim 1 .
13. A process for forming multiple moldings comprising:
providing the thermoplastic molding composition of claim 1 to a multi-tooling molding apparatus, wherein said multi-tooling molding apparatus includes a runner system capable of charging at least four molds; and
charging said four molds with said thermoplastic molding composition via said runner system.