Copper collector for secondary battery comprising Cu-nitrile compound complex formed on surface thereof
View Patent ↗Disclosed are copper foil or net comprising a Cu-nitrile compound complex formed on the surface thereof, a method for preparing the same, and a lithium secondary battery that comprises an electrode using the same copper foil or net as a collector. The lithium secondary battery, which uses a copper collector comprising a Cu-nitrile compound complex formed on the surface thereof through the application of a certain voltage level, can prevent the corrosion of Cu occurring at a voltage of 3.6V or higher under overdischarge conditions away from the normal drive condition, and thus can significantly improve the capacity restorability after overdischarge.
1. A method for preparing a copper foil or net comprising a Cu-nitrile compound complex formed on the surface thereof, the method comprising: contacting an entire surface of a copper foil or net, which is not coated with an electrode active material, with a nitrile compound-containing solution; and then
applying a reduction potential of less than or equal to 1.9 volts to greater than about 0.2 volts versus lithium metal to the copper foil or net to form the copper foil or net comprising a Cu-nitrile compound complex formed on the surface thereof.
2. The method according to claim 1 , further comprising disposing an electrode active material on the copper foil or net comprising a Cu-nitrile compound complex formed on a surface thereof.
3. The method of claim 1 , wherein the nitrile compound is a compound represented by the formula R—CN or CN—R—CN, wherein R is a C 2 to C 15 alkyl group or a C 2 to C 15 alkylene group.
4. A method of preparing an electrode, the method comprising:
contacting an entire surface of a copper foil or net with a solution comprising a nitrile compound; then
applying a reduction potential of less than or equal to 1.9 volts to greater than about 0.2 volts versus lithium metal to the copper foil or net; and then
disposing an electrode active material on the copper foil or net to prepare the electrode,
wherein the nitrile compound is a compound represented by the formula CN—R—CN, wherein R is a C 2 to C 15 alkylene group.