Production process of inkjet ink composition and inkjet composition
View Patent ↗A process for producing an inkjet ink composition is provided and includes dispersion-treating a coloring material in a non-aqueous solvent with a dispersant having no coloring material-dispersing property, the coloring material being covered with a resin insoluble in the non-aqueous solvent. An inkjet ink composition produced by the production process is provided.
1. A process for producing an inkjet ink composition, which comprises dispersing a coloring material in a non-aqueous solvent with a dispersant having no coloring material-dispersing property, the coloring material being covered with a resin insoluble in the non-aqueous solvent, wherein the dispersant is a graft polymer comprising a repeating unit of formula (1) in a main chain of the graft polymer:
wherein R represents a hydrogen atom or a methyl group; X represents a halogen atom, OR 1 , —COOR 1 , —CON(R 1 )(R 2 ) or —OCOR 1 ; R 1 represents an organic group having a carbon number of 1 to 10; and R 2 represents a hydrogen atom or an organic group having a carbon number of 1 to 10.
2. The process for producing an inkjet ink composition according to claim 1 , wherein the dispersing is performed at a temperature higher than a glass transition point of the resin insoluble in the non-aqueous solvent.
3. The process for producing an inkjet ink composition according to claim 1 , wherein the inkjet ink composition is an electrostatic-inkjet ink composition.
4. An inkjet ink composition comprising: a non-aqueous solvent; a coloring material covered with a resin insoluble in the non-aqueous solvent; and a dispersant having no coloring material-dispersing property, wherein the dispersant is a graft polymer comprising a repeating unit of formula (1) in a main chain of the graft polymer:
wherein R represents a hydrogen atom or a methyl group; X represents a halogen atom, OR 1 , —COOR 1 , —CON(R 1 )(R 2 )or —OCOR 1 ; R 1 represents an organic group having a carbon number of 1 to 10; and R 2 represents a hydrogen atom or an organic group having a carbon number of 1 to 10.
5. The inkjet ink composition according to claim 4 , wherein the graft polymer has a weight-average molecular weight of 1,000 or more, and the graft polymer further comprises a repeating unit of formula (2):
wherein R 21 and R 22 each independently represents a hydrogen atom or a methyl group; X 21 represents a single bond or a divalent linking group comprising two or more atoms selected from the group consisting of C, H, N, O, S and P, the divalent group having a total atom number of 50 or less; and G represents a polymer component having a weight-average molecular weight of 500 or more, the polymer comprising a repeating of formula (3), or a polydimethylsiloxane group having a weight-average molecular weight of 500 or more:
wherein R 31 and R 32 each represents a hydrogen atom or a methyl group; R × represents a hydrogen atom or a hydrocarbon group having a carbon number of 1 to 30; and X 31 represents a single bond or a divalent linking group comprising two or more atoms selected from the group consisting of C, H, N, O, S and P, the divalent group having a total atom number of 50 or less.
6. The inkjet ink composition according to claim 4 , which has a proportion of the coloring material having an average particle diameter of 0.2 μm or less of 5% or less by volume.
7. The inkjet ink composition according to claim 4 , which is an electrostatic-inkjet ink composition.