Fiber reinforced polypropylene compositions
View Patent ↗The present invention is directed generally to fiber reinforced polypropylene compositions, and the beneficial mechanical properties imparted by such compositions. The fiber reinforced polypropylene compositions include at least 25 wt % polypropylene based polymer, from 5 to 60 wt % organic fiber, and from 0 to 60 wt % inorganic filler. Lubricant may also be optionally incorporated into the composition. Articles molded from these fiber reinforced polypropylene compositions have a flexural modulus of at least 300,000 psi, and exhibit ductility during instrumented impact testing. The fiber reinforced polypropylene compositions of the present invention are particularly suitable for making molded articles including, but not limited to household appliances, automotive parts, and boat hulls.
1. A polypropylene resin composition comprising:
(a) at least 30 wt %, based on the total weight of the composition, polypropylene based polymer, wherein said polypropylene based polymer has a melt flow rate of at least 400 g/10 minutes;
(b) from 10 to 15 wt %, based on the total weight of the composition, pre-cut organic fiber chosen from polyalkylene terephalates, polyalkylene naphthalates and combinations thereof; and
(c) from 5 to 40 wt %, based on the total weight of the composition, inorganic filler;
wherein said composition is substantially lubricant-free;
wherein an article molded from said composition has a flexural modulus of at least 300,000 psi and exhibits ductility during instrumented impact testing.
2. The polypropylene resin composition of claim 1 wherein said polypropylene based polymer is selected from the group consisting of polypropylene homopolymers, propylene-ethylene random copolymers, propylene-α-olefin random copolymers, propylene impact copolymers, and combinations thereof.
3. The polypropylene resin composition of claim 2 wherein said polypropylene based polymer is polypropylene homopolymer.
4. The polypropylene resin composition of claim 1 wherein said polypropylene based polymer further comprises from about 0.01 wt % to less than about 0.1 wt % of a modifier selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid or esters thereof, maleic anhydride, itaconic anhydride, and combinations thereof.
5. The polypropylene resin composition of claim 1 wherein said organic fiber is dispersed randomly within said polypropylene based polymer.
6. The polypropylene resin composition of claim 5 wherein said organic fiber is a polyalkylene tereplithalate.
7. The polypropylene resin composition of claim 6 wherein said organic fiber is polyethylene terephthalate.
8. The polypropylene resin composition of claim 1 wherein said inorganic filler is selected from group consisting of talc, calcium carbonate, calcium hydroxide, barium sulfate, mica, calcium silicate, clay, kaolin, silica, alumina, wollastonite, magnesium carbonate, magnesium hydroxide, titanium oxide, zinc oxide, zinc sulfate, and combinations thereof.
9. The polypropylene resin composition of claim 8 wherein said inorganic filler is talc or wollastonite.
10. The polypropylene resin composition of claim 1 wherein said article molded from said composition has a flexural modulus of at least 450,000 psi.
11. A polypropylene resin composition comprising:
(a) at least 25 wt %, based on the total weight of the composition, polypropylene based polymer with a melt flow rate of at least 400 g/10 minutes;
(b) from 5 to 15 wt %, based on the total weight of the composition, pre-cut organic fiber chosen from polyalkylene terephalates, polyalkylene naplithalates and combinations thereof; and
(c) from 10 to 60 wt %, based on the total weight of the composition, inorganic filler;
wherein said composition is substantially lubricant free;
wherein an article molded from said composition has a flexural modulus of at least about 300,000 psi and exhibits ductility during instrumented impact testing.
12. The polypropylene resin composition of claim 11 wherein said polypropylene based polymer is selected from the group consisting of polypropylene homopolymers, propylene-ethylene random copolymers, propylene-β-olefin random copolymers, propylene impact copolymers, and combinations thereof.
13. The polypropylene resin composition of claim 12 wherein said polypropylene based polymer is polypropylene homopolymer with a melt flow rate of about 1500 g/10 minutes.
14. The polypropylene resin composition of claim 11 wherein said polypropylene based polymer further comprises from about 0.1 wt % to less than about 10 wt % of a polypropylene based polymer modified with a grafting agent, wherein said grafting agent is selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid or esters thereof, maleic anhydride, itaconic anhydride, and combinations thereof
15. The polypropylene resin composition of claim 11 wherein said organic fiber is dispersed randomly within said polypropylene based polymer.
16. The polypropylene resin composition of claim 15 wherein said organic fiber is a polyalkylene terephthalate.
17. The polypropylene resin composition of claim 16 wherein said organic fiber is polyethylene terephthalate at a loading from about 7.5% to about 15 wt %.
18. The polypropylene resin composition of claim 11 wherein said inorganic filler is selected from group consisting of talc, calcium carbonate, calcium hydroxide, barium sulfate, mica, calcium silicate, clay, kaolin, silica, alumina, wollastonite, magnesium carbonate, magnesium hydroxide, titanium oxide, zinc oxide, zinc sulfate, and combinations thereof.
19. The polypropylene resin composition of claim 18 wherein said inorganic filler is talc or wollastonite at a loading from about 20% to about 60 wt %.
20. The polypropylene resin composition of claim 19 wherein the size of said talc is from about 1 to about 100 microns.
21. The propylene resin composition of claim 11 wherein said article molded from said composition has a flexural modulus of at least about 600,000 psi.
22. The propylene resin composition of claim 11 wherein said article molded from said composition has a flexural modulus of at least about 1,000,000 psi.
23. A polypropylene resin composition comprising:
(a) at least 30 wt %, based on the total weight of the composition, polypropylene based polymer, wherein said polypropylene based polymer has a melt flow rate of at least 400 g/10 minutes;
(b) from 5 to 15 wt %, based on the total weight of the composition, pre-cut organic fiber chosen from polyalkylene terephalates, polyalkylene naphthalates and combinations thereof;
(c) from 10 to 60 wt %, based on the total weight of the composition, inorganic filler, and (d) from 0.01 to 0.1 wt %, based on the total weight of the composition, modifier;
wherein said composition is substantially lubricant free;
wherein an article molded from said composition has a flexural modulus of at least about 300,000 psi and exhibits ductility during instrumented impact testing.
24. The polypropylene resin composition of claim 23 wherein said modifier is selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid or esters thereof, maleic anhydride, itaconic anhydride, and combinations thereof.
25. The polypropylene resin composition of claim 23 wherein said polypropylene based polymer is polypropylene homopolymer.
26. The polypropylene resin composition of claim 23 wherein said organic fiber is dispersed randomly within said polypropylene based polymer.
27. The polypropylene resin composition of claim 26 wherein said organic fiber is polyethylene terephthalate.
28. The polypropylene resin composition of claim 27 wherein said inorganic filler is talc or wollastonite.
29. A polypropylene resin composition comprising:
(a) at least 25 wt %, based on the total weight of the composition, polypropylene based polymer, wherein said polypropylene based polymer has a melt flow rate of at least 400 g/10 minutes;
(b) from 5 to 15 wt %, based on the total weight of the composition, pre-cut organic fiber chosen from polyalkylene terephalates, polyalkylene naphthalates and combinations thereof; and
(c) from 50 to 60 wt %, based on the total weight of the composition, talc or wollastonite;
wherein said composition is substantially lubricant free;
wherein an article molded from said composition has a flexural modulus of at least about 750,000 psi and exhibits ductility during instrumented impact testing.
30. The polypropylene resin composition of claim 29 wherein said polypropylene based polymer is selected from the group consisting of polypropylene homopolymers. propylene-ethylene random copolymers, propylene-β-olefin random copolymers. propylene impact copolymers, and combinations thereof.
31. The polypropylene resin composition of claim 30 wherein said polypropylene based polymer is polypropylene homopolymer with a melt flow rate of about 1500 g/10 minutes.
32. The polypropylene resin composition of claim 29 wherein said polypropylene based polymer further comprises from about 0.1 wt % to less than about 10 wt % of a polypropylene based polymer modified with a grafting agent, wherein said grafting agent is selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid or esters thereof, maleic anhydride, itaconic anhydride, and combinations thereof.
33. The polypropylene resin composition of claim 29 wherein said organic fiber is dispersed randomly within said polypropylene based polymer.
34. The polypropylene resin composition of claim 33 wherein said organic fiber is a polyalkylene terephthalate.
35. The polypropylene resin composition of claim 34 wherein said organic fiber is polyethylene terephthalate.
36. The polypropylene resin composition of claim 35 wherein, the size of said talc is from 1 to about 100 microns.
37. The polypropylene resin composition of claim 36 wherein said article molded from said composition has a flexural modulus of at least about 1,000,000 psi.
38. A polypropylene resin composition comprising:
(a) at least 40 wt %, based on the total weight of the composition, polypropylene based polymer, wherein said polypropylene based polymer has a melt flow rate of at least 400 g/10 minutes;
(b) from 10 to 15 wt %, based on the total weight of the composition, pre-cut organic fiber chosen from polyalkylene terephalates, polyalkylene naphthalates and combinations thereof; and (c) from 10 to 30 wt %, based on the total weight of the composition, talc or wollastonite
wherein said composition is substantially lubricant free;
wherein an article molded from said composition has a flexural modulus of at least about 325,000 psi and exhibits ductility during instrumented impact testing.
39. The polypropylene resin composition of claim 38 wherein said polypropylene based polymer is selected. from the group consisting of polypropylene homopolymers, propylene-ethylene random copolymers, propylene-β-olefin random copolymers, propylene impact copolymers, and combinations thereof.
40. The polypropylene resin composition of claim 39 wherein said polypropylene based polymer is polypropylene homopolymer with a melt flow rate of about 1500 g/10 minutes.
41. The polypropylene resin composition of claim 38 wherein said polypropylene based polymer further comprises from about 0.1 wt % to less than about 10 wt % of a polypropylene based polymer modified with a grafting agent, wherein said grafting agent is selected from the group consisting of acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid or esters thereof, maleic anhydride, itaconic anhydride, and combinations thereof.
42. The polypropylene resin composition of claim 38 wherein said organic fiber is dispersed randomly within said polypropylene based polymer.
43. The polypropylene resin composition of claim 42 wherein said organic fiber is a polyalkylene terephthalate.
44. The polypropylene resin composition of claim 43 wherein said organic fiber is polyethylene terephthalate.
45. The polypropylene resin composition of claim 44 wherein the size of said talc is from about 1 to about 100 microns.
46. The polypropylene resin composition of claim 45 wherein said article molded from said composition has a flexural modulus of at least about 375,000 psi.