A secure tag comprising: a carrier doped with one or more rare earth ions, and a barrier material associated with the carrier and substantially blocking low-wavelength radiation to shield the rare earth ions from low-wavelength radiation. This enables a secure tag to be fabricated that does not photoluminescence strongly in response to a low-wavelength excitation radiation source.
1. secure tag comprising: a carrier doped with one or more rare earth ions, and a barrier material associated with the carrier and substantially blocking low-wavelength radiation to shield the rare earth ions from low-wavelength radiation, wherein low wavelength radiation comprises radiation having a wavelength of 450 nm or less, the barrier material comprises polyimide, which is dissolved in tetrahydrofuran.
2. A secure tag according to claim 1 , wherein the barrier material is a highly reflective and/or scattering material.
3. A secure tag according to claim 1 , wherein the barrier material has a high absorptivity in the ultra-violet region of the electromagnetic spectrum and a low absorptivity in the visible region of the electromagnetic spectrum.
4. A secure tag according to claim 1 , wherein the barrier material microencapsulates the doped carrier.
5. A secure tag according to claim 1 , wherein the carrier comprises a glass.
6. A secure tag according to claim 1 , wherein the barrier material is included in a liquid in which the secure tag is suspended.
7. A secure tag comprising: a carrier doped with one or more rare earth ions, the doped carrier being microencapsulated by a barrier material having a coefficient of absorption above 6.0 for radiation having a wavelength of 450 nm or less.
8. A method of manufacturing a secure tag comprising a carrier doped with one or more rare earth ions, the method comprising: (i) ascertaining an excitation radiation wavelength that stimulates a plurality of transitions within the doped carrier; (ii) selecting an additive having a higher absorption coefficient at the ascertained excitation radiation wavelength than the carrier or the rare earth ions; and (iii) manufacturing a secure tag incorporating the selected additive by microencapsulating the doped carrier with the selective additive to ensure that little to no low-wavelength radiation reaches the rare earth ions to stimulate emission there from, the selective additive is a barrier material comprising an ultraviolet absorbing substance.
9. A method according to claim 8 , wherein ascertaining an excitation radiation wavelength includes ascertaining an excitation radiation wavelength that would stimulate the highest number of transitions within the secure tag.
10. A method according to claim 8 , wherein manufacturing a secure tag incorporating the selected additive comprises encapsulating the doped carrier in the selected additive.
11. A method according to claim 8 , wherein manufacturing a secure tag incorporating the selected additive comprises including the additive as part of starting ingredients for the secure tag.