Toner for developing electrostatic image and resin particle disperision solution for toner for developing electrostatic image
View Patent ↗A toner for developing an electrostatic image of the present invention contains toner particles obtained by forming coagulated particles by mixing a resin particle dispersion solution containing dispersed resin particles and a coloring agent dispersion solution containing dispersed coloring agent particles and fusing the coagulated particles by heating them and is characterized in that at least the surfaces of the toner particles have a chemical structure formed by reaction with a compound having a carbodiimido group. The invention also provides a resin particle dispersion solution to be used for the production of toner.
1. A toner for developing an electrostatic image comprising toner particles obtained by:
forming coagulated particles by mixing a resin particle dispersion solution in which resin particles are dispersed and a coloring agent dispersion solution in which coloring agent particles are dispersed, and
fusing the coagulated particles by heating them, wherein:
the surfaces of the toner particles have a chemical structure formed by reaction with a compound having a carbodiimido group;
a size distribution index GSDv of a volume average particle diameter of the toner particles is 1.30 or lower; and
a shape factor SF 1 of the toner particles is between 100 and 140.
2. The toner for developing an electrostatic image according to claim 1 , wherein the resin particles contain a crystalline resin obtained by polymerization of a condensation polymerizable monomer and having a melting point of at least 50° C. and less than 120° C.
3. The toner for developing an electrostatic image according to claim 2 , wherein the crystalline resin is a crystalline polyester resin.
4. The toner for developing an electrostatic image according to claim 3 , wherein the crystalline polyester resin is a polyester resin obtained by reaction of 1,9-nonanediol with 1,10-decamethylenedicarboxylic acid or by reaction of 1,6-hexanediol with sebacic acid.
5. The toner for developing an electrostatic image according to claim 1 , wherein the resin particles contain a non-crystalline resin having a glass transition temperature Tg of 50° C. to 80° C.
6. The toner for developing an electrostatic image according to claim 1 , wherein the compound having carbodiimido group is polycarbodiimide resin.
7. The toner for developing an electrostatic image according to claim 1 , wherein the coagulated particles further contain releasing agent particles.
8. The toner for developing an electrostatic image according to claim 1 , wherein the toner particles have a volume average particle diameter D 50V in a range of between 3.0 to 9.0 μm.
9. The toner for developing an electrostatic image according to claim 8 , wherein the toner particles have a volume average particle diameter D 50V in a range of between 3.0 to 5.0 μm.
10. The toner for developing an electrostatic image according to claim 1 , wherein the shape factor SF 1 of the toner particles is between 110 to 135.
11. A resin particle dispersion solution for a toner for developing an electrostatic image comprising dispersed resin particles obtained by:
emulsifying or dispersing monomers comprising a condensation polymerizable monomer by mixing them in a water-based medium; and
condensation-polymerizing the mixed monomers, wherein:
the surfaces of the resin particles contain a compound having a carbodiimido group;
a size distribution index GSDv of a volume average particle diameter of the resin particles is 1.30 or lower; and
a shape factor SF 1 of the resin particles is between 100 and 140.
12. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 11 , wherein the resin particles contain a crystalline resin obtained by polymerization of a condensation polymerizable monomer and having a melting point of at least 50° C. and less than 120° C.
13. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 11 , wherein the volume average particle diameter of the resin particles in the resin particle dispersion solution is in a range of 0.05 to 2.0 μm.
14. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 11 , wherein a catalyst to be used for the condensation polymerization is an acid having a surface activation effect.
15. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 14 , wherein the acid having a surface activation effect is dodecylbenzenesulfonic acid, isopropylbenzenesulfonic acid, or camphersulfonic acid.
16. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 11 , wherein a catalyst to be used for the condensation polymerization is a metal catalyst containing a rare earth element.
17. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 16 , wherein the metal catalyst containing a rare earth element includes an alkylbenzene sulfonic acid salt, an alkylsulfuric acid ester salt, or a triflate structure.
18. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 11 , wherein a catalyst to be used for the condensation polymerization is a hydrolyzing enzyme.
19. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 18 , wherein the hydrolyzing enzyme is lipase.
20. The resin particle dispersion solution for a toner for developing an electrostatic image according to claim 11 , wherein the resin particles have a volume average particle diameter D 50V in a range of between 3.0 to 9.0 μm.