Fuel cell support structure
View Patent ↗A plurality of tubular solid oxide fuel cells are embedded in a solid phase porous foam matrix that serves as a support structure for the fuel cells. The foam matrix has multiple regions with at least one property differing between at least two regions. The properties include porosity, electrical conductivity, and catalyst loading.
1. A solid oxide fuel cell stack comprising
(a) at least one tubular solid oxide fuel cell comprising a tubular inner electrode layer, a tubular outer electrode layer, and a tubular electrolyte layer sandwiched between the inner and other electrode layers, and
(b) a matrix in which the at least one fuel cell is embedded, the matrix having multiple solid phase porous regions comprising first and second solid phase porous foam matrix regions, wherein the first matrix region is electrically conductive and the second matrix region is electrically insulating; and
wherein the solid oxide fuel cell stack comprises multiple fuel cells and some of the fuel cells are embedded in the first matrix region and the remaining fuel cells are embedded in the second matrix region.
2. A fuel cell stack as claimed in claim 1 wherein the second matrix region has a composition including a material selected from the group consisting of oxide ceramics, carbide ceramics, and nitride ceramics.
3. A fuel cell stack as claimed in claim 2 wherein the second matrix region has a composition including a material selected from the group consisting of alumina, mullite, silicon nitride, and aluminum nitride.
4. A fuel cell stack as claimed in claim 1 wherein the first matrix region has a composition including a material selected from the group consisting of electrically conductive materials consisting of: lanthanum strontium manganate (LSM); lanthanum strontium ferrite (LSF); samarium strontium cobaltite (SSC); 316 and 316L stainless steels; oxide and carbide ceramics; austenitic nickel-chromium-based super-alloy; super-alloy; ferritic steel; SiC; MoSi 2 ; silver; silver-copper-palladium alloy; silver-palladium alloy; silver-platinum alloy; silver-palladium-platinum alloy; silver-gold-platinum alloy; silver-gold-palladium alloy; gold and gold alloys; copper and copper alloys; and, cermets of austenitic nickel-chromium-based super-alloy, super-alloy, ferritic steel, SiC, MoSi 2 , silver, silver-copper-palladium alloy, silver-palladium alloy, silver-platinum alloy, silver-palladium-platinum alloy, silver-gold-platinum alloy, silver-gold-palladium alloy, gold and gold alloys, and copper and copper alloys.
5. A fuel cell stack as claimed in 1 wherein the outer electrode layer is an anode and the first matrix region has a composition selected from the group of electrically conductive materials consisting of: Ni-Yttria stabilized zirconia cermet; Ni and doped zirconia cermet; Ni and doped —CeO 2 cermet; and Cu and doped-ceria cermet.
6. A fuel cell stack as claimed in claim 1 wherein the matrix comprises an electrically insulating solid phase porous foam base structure partially coated with an electrically conductive material, such that uncoated portions of the base structure form an electrically insulating first matrix region, and the coated portions of the base structure form an electrically conductive second matrix region.
7. A fuel cell stack as claimed in claim 1 wherein the first or second matrix region has a composition including a material selected from the group of high emissitivity materials consisting of surface oxidized steel, super alloys and bulk SiC, and LSM.
8. A fuel cell stack as claimed in claim 7 wherein the first or second matrix region comprises a low emissitivity base structure coated with a material selected from the group of high emissitivity materials consisting of surface oxidized steel, super alloys and bulk SiC, and LSM.
9. A fuel cell stack as claimed in claim 1 wherein the outer electrode is a cathode, and the first matrix region is a) electrically conductive, b) contacts the cathode, and c) comprises a catalytic material that promotes oxygen ionization electrochemical reaction or catalytically burns a fuel-oxidant mixture.
10. A fuel cell stack as claimed in claim 9 wherein the catalytic material is selected from the group consisting of: LSM, LSF, Pt, Pd, Pt—Pd, Pt-alloys, and Pd-alloys.
11. A fuel cell stack a claimed in claim 1 wherein the outer electrode layer is an anode, and the first matrix region is electrically conductive, contacts the anode, and is coated with a catalyst material that promotes a fuel reforming reaction.
12. A fuel cell stack as claimed in claim 11 wherein the catalytic material is selected from the group consisting of: Cu/ZnO alloys, Ni and its alloys, Pt and its alloys, and Pd and its alloys.
13. A fuel cell stack as claimed in claim 12 wherein the first matrix region is further coated with a catalyst material that promotes an electrochemical reaction.
14. A fuel cell stack as claimed in claim 9 wherein the second matrix region comprises a lower loading of catalyst material than the first matrix region.
15. A fuel cell stack as claimed in claim 1 wherein the first matrix region is a tubular solid state porous foam layer surrounding at least one fuel cell, and the second matrix region is a solid state porous foam support structure in which the first matrix region is embedded.
16. A solid oxide fuel cell stack comprising:
(a) at least one tubular solid oxide fuel cell comprising a tubular inner electrode layer, a tubular outer electrode layer, and a tubular electrolyte layer sandwiched between the inner and outer electrode layers; and
(b) a matrix in which the at least one fuel cell is embedded, the matrix having multiple solid phase porous regions comprising first and second matrix regions, wherein the first matrix region is a tubular solid state porous foam layer surrounding at least one fuel cell, and the second matrix region is a solid state porous foam support structure in which the first matrix region is embedded, wherein electrical conductivity is different between the first and second matrix regions, and wherein the porosity of the second matrix region is greater than the porosity of the first matrix region.
17. A furl cell stack as claimed in claim 16 wherein the first and second matrix regions are bonded at their interface by a bonding phase.
18. A fuel cell stack as claimed in claim 17 wherein the first matrix region is electrically conductive and the second matrix region is electrically insulating.
19. A solid oxide fuel cell comprising:
(a) at least one tubular solid oxide fuel cell comprising a tubular inner electrode layer, a tubular outer electrode layer, and a tubular electrolyte layer sandwiched between the inner and outer electrode layers; and
(b) a matrix in which the at least one fuel cell is embedded the matrix having multiple solid phase porous regions comprising first and second matrix regions, wherein the first matrix region is a tubular solid state porous foam layer surrounding at least one fuel cell, and the second matrix region is a solid state porous foam support structure in which the first matrix region is embedded, and wherein electrical conductivity is different between the first and second matrix regions;
wherein the stack comprises multiple fuel cells of which some fuel cells are surrounded by the first matrix region, and at least some of the remaining fuel cells are surrounded by the second matrix region.
20. A fuel cell stack as claimed in claim 19 wherein the first matrix region is electrically insulating and the second matrix region is electrically conductive.
21. A solid oxide fuel cell stack comprising:
(a) at least one tubular solid oxide fuel cell comprising a tubular inner electrode layer, a tubular outer electrode layer, and a tubular electrolyte layer sandwiched between the inner and outer electrode layers;
(b) a matrix in which the at least one fuel cell is embedded, the matrix having multiple solid phase porous regions comprising first and second matrix regions, wherein the first matrix region is a tubular solid state porous foam layer surrounding at least one fuel cell, and the second matrix region is a solid state porous foam support structure in which the first matrix region is embedded, and wherein electrical conductivity is different between the first and second matrix regions; and
(c) a buffering matrix region surrounding the second matrix region and comprising a material selected from the group consisting of a solid state porous foam and a porous metal mesh.
22. A fuel cell stack as claimed in claim 11 wherein the second matrix region is coated with a lower loading of catalyst material than the first matrix region.
23. A solid oxide fuel cell stack comprising:
(a) at least one tubular solid oxide fuel cell comprising a tubular inner electrode layer, a tubular outer electrode layer, and a tubular electrolyte layer sandwiched between the inner and outer electrode layers; and
(b) a matrix in which the at least one fuel cell is embedded, the matrix having multiple solid phase porous regions comprising first and second matrix regions, wherein electrical conductivity is different between the first and second matrix regions and wherein porosity is different between the first and second matrix regions.
24. A fuel cell stack as claimed in claim 1 wherein catalytic loading is different between the first and second matrix regions.