Novel red color emitting compounds and organic electroluminescent device using them
The present invention relates to a novel red color emitting compound of formula (I), an organic electroluminescent device using the compound, and a method for manufacturing the device. The present invention also relates to a red organic electroluminescent emitting device having high chromaticity and high brightness by using the compounds of the following formula (I) having high luminescence efficiency; wherein R 1 is independently selected from the group consisting of hydrogen atom and substituted or unsubstituted C 1-6 alkyl; X represents N, S, or O; and Y represents hydrogen atom, substituted or unsubstituted C 1-6 alkyl, or substituted or unsubstituted C 1-6 alkoxy.
1 . A compound represented by formula (I):
wherein
R 1 is independently selected from the group consisting of hydrogen atom and substituted or unsubstituted C 1-6 alkyl;
X represents N, S, or O; and
Y represents hydrogen atom, substituted or unsubstituted C 1-6 alkyl, or substituted or unsubstituted C 1-6 alkoxy.
2 . The compound according to claim 1 , wherein R 1 is methyl.
3 . The compound according to claim 1 , wherein X is S.
4 . The compound according to claim 1 , wherein Y is methyl.
5 . The compound according to claim 1 , wherein R 1 is methyl, X is S, and Y is hydrogen or methyl.
6 . The compound according to claim 1 , wherein the compound is a red color emitting material.
7 . An organic electroluminescent device, comprising:
a first electrode;
a second electrode opposing said first electrode; and
at least one organic layer located between the first electrode and the second electrode, the organic layer comprising at least one compound according to formula (I):
wherein
R 1 is independently selected from the group consisting of hydrogen atom and substituted or unsubstituted C 1-6 alkyl;
X represents N, S, or O; and
Y represents hydrogen atom, substituted or unsubstituted C 1-6 alkyl, or substituted or unsubstituted C 1-6 alkoxy.
8 . The organic electroluminescent device according to claim 7 , wherein the organic layer comprises a light-emitting layer.
9 . The organic electroluminescent device according to claim 7 , wherein the organic layer is located between an anode that injects holes and a cathode that injects electrons.
10 . The organic electroluminescent device according to claim 7 , wherein one or more compound represented by formula (I) is used as a dopant and/or a host material.
11 . The organic electroluminescent device according to claim 5 , wherein the organic electroluminescent device comprises a substrate, an anode over the substrate, a hole injection layer over the anode, a hole transportation layer over the hole injection layer, an emitting layer over the transportation layer, an electron transporting layer over the emitting layer and a cathode over the electron transporting layer; and the compound of formula (I) is contained in at least the emitting layer.
12 . The organic electroluminescent device according to claim 5 , wherein in the compound of formula (I), R 1 is methyl.
13 . The organic electroluminescent device according to claim 5 , wherein in the compound of formula (I), X is S.
14 . The organic electroluminescent device according to claim 5 , wherein in the compound of formula (I), Y is methyl.
15 . The organic electroluminescent device according to claim 5 , wherein in the compound of formula (I), R 1 is methyl, X is S, and Y is hydrogen or methyl.
16 . The organic electroluminescent device according to claim 5 , wherein the compound of formula (I) is a red color emitting material.
17 . A method of manufacturing an organic electroluminescent device, comprising:
(a) providing a substrate;
(b) forming a first electrode;
(c) forming at least one layer on said first electrode, the layer comprising a compound of formula (I):
wherein
R 1 is independently selected from the group consisting of hydrogen atom and substituted or unsubstituted C 1-6 alkyl;
X represents N, S, or O; and
Y represents hydrogen atom, substituted or unsubstituted C 1-6 alkyl, or substituted or unsubstituted C 1-6 alkoxy; and
(d) forming a second electrode on the layer comprising the compound of formula (I).
18 . The method of manufacturing an organic electroluminescent device according to claim 17 , wherein in the compound of formula (I), R 1 is methyl.
19 . The method of manufacturing an organic electroluminescent device according to claim 17 , wherein in the compound of formula (I), X is S.
20 . The method of manufacturing an organic electroluminescent device according to claim 17 , wherein in the compound of formula (I), Y is methyl.