IP Library Granted Patent US 7,608,327
Granted Patent B2
US 7,608,327 · App. 11/312,033 · Granted Oct 27, 2009

High tear strength film

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Quick Facts
Patent No.
US 7,608,327
App. No.
11/312,033
Granted
Oct 27, 2009
Kind
B2
Abstract

A thick film produced from a polyolefin blend is disclosed. The film is prepared from a blend having a density from 0.935 to 0.955 g/cm 3 and comprising LLDPE and greater than 50% by weight HDPE having a density greater than 0.955 g/cm 3 . The film has a modulus in the machine direction from about 75,000 to about 130,000 psi and improved machine direction tear strength.

Claims (15)

1. A film produced from a polyolefin blend that has a density from 0.935 to 0.955 g/cm 3 , said blend comprising:

(a) greater than 50 wt. % of HDPE having a density greater than 0.955 g/cm 3 and an MI 2 less than 1.0 dg/min.; and

(b) LLDPE having a density from 0.900 to 0.925 g/cm 3 and an MI 2 less than 5.0 dg/min.;

wherein the film has a thickness from 50 to 200 microns, a modulus in the machine direction (mod MD ) from about 75,000 to about 130,000 psi, a tear strength in the transverse direction (TS TD ) greater than in the machine direction (TS MD ), and a TS MD expressed in grams and measured at a film thickness of 100 microns, defined by:

TS MD >1544−(11.2)(mod MD /1000 psi).

2. The film of claim 1 wherein the LLDPE is an ethylene-hexene copolymer.

3. The film of claim 1 wherein the polyolefin blend has from about 10 to about 49 percent by weight LLDPE.

4. The film of claim 1 wherein the polyolefin blend is prepared by melt extrusion.

5. The film of claim 1 wherein the polyolefin blend has a density from 0.940 to 0.950 g/cm 3 .

6. The film of claim 1 wherein the LLDPE has an MI 2 from 0.5 to 2.0 dg/min.

7. The film of claim 1 having a thickness from 100 to 200 microns.

8. A film produced from a polyolefin blend that has a density from 0.935 to 0.955 g/cm 3 , said blend comprising:

(a) greater than 50 wt. % of HDPE having a density greater than 0.955 g/cm 3 and an MI 2 less than 1.0 dg/min.; and

(b) LLDPE having a density from 0.900 to 0.925 g/cm 3 and an MI 2 less than 5.0 dg/min.;

wherein the film has a thickness from 50 to 200 microns, and a tear strength in the machine direction (TS MD ) greater by at least 20% than that of a film with the same modulus prepared from a single polyethylene resin.

Assignments (18)
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032112/0786 →
APPOINTMENT OF SUCCESSOR ADMINISTRATIVE AGENT Recorded Jan 22, 2014
From: UBS AG, STAMFORD BRANCH
To: BANK OF AMERICA, N.A.
Reel/Frame 032112/0863 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: CITIBANK, N.A.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0644 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: DEUTSCHE BANK TRUST COMPANY AMERICAS
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0684 →
RELEASE OF SECURITY INTEREST Recorded Jan 22, 2014
From: BANK OF AMERICA, N.A.
To: EQUISTAR CHEMICALS, LP
Reel/Frame 032113/0730 →
SECURITY AGREEMENT Recorded May 19, 2010
From: EQUISTAR CHEMICALS, LP
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 024402/0655 →
SECURITY AGREEMENT Recorded May 18, 2010
From: EQUISTAR CHEMICALS, LP
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 024397/0861 →
SECURITY AGREEMENT Recorded May 7, 2010
From: EQUISTAR CHEMICALS. LP
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 024351/0001 →
SECURITY AGREEMENT Recorded May 6, 2010
From: EQUISTAR CHEMICALS, LP
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024342/0443 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0705 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
To: EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0186 →
RELEASE OF SECURITY INTEREST Recorded May 5, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: LYONDELL CHEMICAL TECHNOLOGY, L.P.; EQUISTAR CHEMICALS, LP
Reel/Frame 024337/0856 →
RELEASE OF SECURITY INTEREST Recorded May 4, 2010
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: EQUISTAR CHEMICALS, LP
Reel/Frame 024329/0535 →
SECURITY AGREEMENT Recorded Oct 30, 2009
From: EQUISTAR CHEMICALS, LP
To: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
Reel/Frame 023449/0687 →
SECURITY AGREEMENT Recorded Apr 9, 2009
From: EQUISTAR CHEMICALS, LP
To: CITIBANK, N.A., AS ADMINISTRATIVE AGENT AND COLLATERAL AGENT
Reel/Frame 022678/0860 →
SECURITY AGREEMENT Recorded Aug 4, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; BASELL POLYOLEFIN GMBH; LYONDELL CHEMICAL COMPANY; EQUISTAR CHEMICALS, L.P.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 021354/0708 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS AND PATENT APPLICATIONS Recorded Mar 26, 2008
From: BASELL POLYOLEFINE GMBH; ARCO CHEMICAL TECHNOLOGY L.P.; ARCO CHEMICAL TECHNOLOGY, INC.; ATLANTIC RICHFIELD COMPANY; BASELL NORTH AMERICA, INC.; EQUISTAR CHEMICALS. LP.; LYONDELL CHEMICAL COMPANY; LYONDELL CHEMICAL TECHNOLOGY, L.P.; LYONDELL PETROCHEMICAL COMPANY; NATIONAL DISTILLERS AND CHEMICAL CORPORATION; OCCIDENTAL CHEMICAL CORPORATION; OLIN CORPORATION; QUANTUM CHEMICAL CORPORATION; BASELL POLYOLEFIN GMBH
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 020704/0562 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 16, 2006
From: MAVRIDIS, HARILAOS
To: EQUISTAR CHEMICALS, LP
Reel/Frame 017567/0505 →