Toughened poly(ethylene terephthalate) compositions
View Patent ↗Toughened poly(ethylene terephthalate) compositions which contain functionalized polymeric tougheners, and wherein the poly(ethylene terephthalate) contains little or no antimony, have superior heat stability and retain their toughness for longer periods at higher temperatures. The compositions are useful for molded and shaped parts, such as mechanical parts, automotive parts and electrical parts.
1. A toughened poly(ethylene terephthalate) composition which comprises a functionalized polymeric toughener dispersed in a continuous matrix of said poly(ethylene terephthalate) wherein said improvement comprises said poly(ethylene terephthalate) contains less than 25 ppm of antimony.
2. The composition as recited in claim 1 wherein said poly(ethylene terephthalate) has a melting point of about 240° C. or more, and a weight average molecular weight of about 20,000 or more.
3. The composition as recited in claim 1 wherein said toughener comprises epoxy or carboxylic anhydride groups.
4. The composition as recited in claim 1 wherein said toughener is a copolymer of ethylene and one or more (meth)acrylate monomers.
5. The composition as recited in claim 4 wherein said toughener comprises epoxy groups.
6. The composition as recited in claim 1 wherein said toughener is about 3 to about 25 percent by weight of the total composition.
7. The composition as recited in claim 1 additionally comprising 1 to about 70 weight percent of filler/reinforcing agent based on the total weight of the composition.
8. A shaped part comprising the composition of claim 1 .
9. The shaped part as recited in claim 8 which is an appearance part.
10. The composition of claim 1 wherein the poly(ethylene terephthalate) contains less than 10 ppm antimony.
11. A process for melt forming into a shaped part a toughened poly(ethylene terephthalate) composition which comprises a functionalized polymeric toughener dispersed in a continuous matrix of said poly(ethylene terephthalate) wherein said improvement comprises said poly(ethylene terephthalate) contains less than 25 ppm of antimony.
12. The process as recited in claim 11 wherein said poly(ethylene terephthalate) has a melting point of about 240° C. or more, and a weight average molecular weight of about 20,000 or more.
13. The process as recited in claim 11 wherein said toughener comprises epoxy or carboxylic anhydride groups.
14. The process as recited in claim 11 wherein said toughener is a copolymer of ethylene and one or more (meth)acrylate monomers.
15. The process as recited in claim 14 wherein said toughener comprises epoxy groups.
16. The process as recited in claim 11 wherein said toughener is about 3 to about 25 percent by weight of the total composition.
17. The process as recited in claim 11 additionally comprising 1 to about 70 weight percent of filler/reinforcing agent based on the total weight of the composition.
18. The process as recited in claim 11 wherein one or more active ingredients, and optionally one or more inactive ingredients, are to be mixed in to form said composition, comprising the step of:
(a) a first mixing step comprising mixing said polymer and said toughener;
(b) in a second mixing or subsequent mixing step mixing the product of step (a) with said one or more active ingredients;
provided that any inactive ingredients to be mixed in are mixed in during the first and/or second or subsequent mixing steps.
19. The process as recited in claim 11 wherein said poly(ethylene terephthalate) contains less than 10 ppm antimony.