Vapor permeable liquid-applied membrane
View Patent ↗Exemplary membranes, liquid compositions, and methods of the invention involve the use of a hydrophobic acrylic polymer and at least one water-soluble polymer (e.g., PVOH) for providing a water vapor permeable air barrier on construction surfaces. Unlike prior art vapor barriers, the present invention provides membranes having good crack-bridging and non-water-absorption characteristics.
1. A liquid composition for providing a vapor permeable air barrier membrane by spray coating onto a construction surface, comprising:
an emulsion comprising at least one hydrophobic acrylic polymer having a repeating group represented by the formula —(CH 2 —CH(COOR)—)— wherein R represents a C 2 -C 8 alkyl group, said at least one acrylic polymer having a glass transition temperature of −55° C. to 0° C. and being present in an amount no less than 50% and no greater than 97% by weight based on total solids in the composition;
said liquid composition further comprising at least one inorganic filler selected from the group of calcium carbonate, talc, clay, silica, and titanium dioxide, said at least one inorganic filler being present in an amount of 5% to 30% by weight based on total solids in said liquid composition; the total amount of all inorganic filler contained within said liquid composition being present in an amount such that pigment volume concentration (PVC) is no greater than 16%;
said liquid composition further comprising water in an amount no less than 30% and no greater than 50% by total weight of said liquid composition; and
said liquid composition further comprising at least one water-soluble polymer being present in an amount no less than 5% and no greater than 17% by weight based on total solids in said liquid composition, and said at least one-water-soluble polymer having a solution viscosity, at 4% by weight in water, of no less than 2 centipoise and no greater than 50 centipoise.
2. The composition of claim 1 wherein said at least one-water-soluble polymer is selected from the group consisting of
polyvinyl alcohol having a number average molecular weight no less than 5,000 and no greater than 50,000;
a polyethylene oxide having an average molecular weight no less than 5,000 and no greater than 200,000; and
a methyl ether or ethyl ether of cellulose having a number average molecular weight no less than 3,000 and no greater than 20,000.
3. The composition of claim 1 wherein said at least one-water-soluble polymer is a polyvinyl alcohol having a number average molecular weight no less than 5,000 and no greater than 50,000.
4. The composition of claim 1 wherein said at least one-water-soluble polymer is a polyethylene oxide having an average molecular weight no less than 5,000 and no greater than 200,000.
5. The composition of claim 1 wherein said at least one-water-soluble polymer is a methyl ether or ethyl ether of cellulose having a number average molecular weight no less than 3,000 and no greater than 20,000.
6. The composition of claim 1 wherein, in said at least one hydrophobic acrylic polymer, R represents an ethyl, propyl, butyl, octyl or ethyl hexyl.
7. The composition of claim 1 further comprising a hydrophobic meth(acrylic) polymer.
8. The composition of claim 1 wherein said at least one hydrophobic acrylic polymer is a butyl acrylate polymer.
9. The composition of claim 1 wherein at least one hydrophobic polymer is a copolymer of butyl acrylate and styrene.
10. The composition of claim 9 wherein the molar ratio of butyl acrylate/styrene is greater than 1.5.
11. The composition of claim 1 wherein said inorganic filler is calcium carbonate.
12. The composition of claim 1 wherein said inorganic filler has an average particle size no less than 0.1 um and no greater than 50 um.
13. The composition of claim 3 wherein said polyvinyl alcohol has a degree of hydrolysis of 80 to 90 percent.
14. The composition of claim 3 wherein said polyvinyl alcohol has a degree of hydrolysis of 90 to 100 percent.
15. A membrane made by spray coating a substrate surface with the composition of claim 1 and allowing the composition to dry.
16. A method for forming a moisture vapor permeable membrane, comprising: spray coating onto a cementitious, wood, or gypsum substrate the composition of claim 1 and allowing the composition to dry.
17. A composite comprising a building panel or cementitious body coated with the composition of claim 1 .
18. The membrane of claim 15 having an average thickness no less than 20 mils and no greater than 100 mils thick.
19. The membrane of claim 15 having an average thickness no less than 40 mils.
20. The membrane of claim 15 having an average thickness of no less than 40 mils and no greater than 100 mils thick, a vapor permeability of no less than 2 perms and no greater than 20 perms in accordance with ASTM E-96; and an elongation of no less than 200% and no greater than 1000%; and a water absorption value of less than 50% after one day immersion in water.
21. The method of claim 16 wherein the moisture vapor permeable membrane has an average thickness of 20 mils to 100 mils.
22. The composite of claim 17 wherein the coated composition, after drying, forms a moisture vapor permeable membrane having an average thickness of 20 mils to 100 mils.