Blends of ethylene copolymers with high-frequency weldability
View Patent ↗Disclosed are high frequency-active blends comprising (a) copolymers of ethylene and maleic anhydride or its functional equivalents and (b) ethylene copolymers with polar comonomers such as ethylene/vinyl acetate copolymers, ethylene/alkyl(meth)acrylate copolymers and ethylene/(meth)acrylate/carbon monoxide terpolymers; and films, powders, multilayer structures, and articles prepared therefrom.
1. A low haze polymeric film having a thickness of up to 25 mil that is high-frequency weldable and optically clear consisting of:
(a) a first ethylene copolymer prepared by high pressure free radical copolymerization consisting essentially of copolymerized units of ethylene and 3-15 weight % copolymerized units of a comonomer selected from the group consisting of maleic anhydride, maleic acid monoesters, maleic acid diesters, fumaric acid monoesters, itaconic acid monoesters and mixtures thereof, said first ethylene copolymer being present in the polymeric blend composition in an amount of from about 5 to about 95 weight % of the polymeric blend composition; and
(b) at least one second ethylene copolymer, different from said first ethylene copolymer, consisting essentially of copolymerized units of ethylene and copolymerized units of a polar monomer selected from the group consisting of vinyl acetate, alkyl acrylates, alkyl methacrylates, carbon monoxide and mixtures of two or more thereof, wherein said polar comonomer is present in the second ethylene copolymer in an amount of from 6 to 40 weight %, the second ethylene copolymer being present in the polymeric blend composition in an amount from about 5 to about 95 weight % of the polymeric blend composition
wherein the haze value of the film is 11 or less.
2. The film of claim 1 wherein the first ethylene copolymer of (a) is obtained from copolymerization of ethylene and maleic anhydride.
3. The film of claim 1 wherein the first ethylene copolymer is obtained from copolymerization of ethylene and a comonomer selected from the group consisting of maleic acid diesters, maleic acid monoesters, fumaric acid monoesters, itaconic acid monoesters, and mixtures of two or more thereof.
4. The film of claim 3 wherein the maleic diesters or monoesters are esters of maleic acid and C 1 to C 4 alcohols.
5. The film of claim 4 wherein the first ethylene copolymer is obtained from copolymerization of ethylene and a maleic acid monoester.
6. The film of claim 5 wherein the maleic acid monoester is ethyl hydrogen maleate.
7. The film of claim 2 wherein the second ethylene copolymer of component (b) is an ethylene/vinyl acetate copolymer.
8. The film of claim 2 wherein the second ethylene copolymer of component (b) is an ethylene/alkyl(meth)acrylate copolymer.
9. The film of any of claims 1 through 8 , wherein said film has a heat resistance greater than 80° C., wherein heat resistance is the temperature at which a film sample press-molded at 190° C. that has been heat-aged in an oven with temperature varied from 70° C.-100° C. in 5-degree increments and having a thickness of 10 mils, a length of six inches and a width of one inch and an attached 100-gram weight breaks or deforms with more than 10% elongation.