Low smoke polycarbonate composition and laminates, method of manufacture and product made therefrom
View Patent ↗A laminate contains a first layer and a second layer. The first layer contains a first composition that contains polycarbonate, polycarbonate-polysiloxane copolymer, impact modifier and polyetherimide, wherein the polycarbonate constitutes at least about 50% by weight of the composition and a 3.2 millimeter thick, 7.6 centimeter square sample of the first composition produces a smoke density (Ds) of less than 275 after a 4-minute burn, measured according to ASTM E 662-03. The first composition may contain about 50 wt. % to about 97 wt. % polycarbonate, about 0.5 wt. % to about 25 wt. % polycarbonate-polysiloxane copolymer, about 0.5 wt. % to about 20 wt. % impact modifier, and about 2 wt. % to about 15 wt. % polyetherimide, by weight. An article may contain a sheet or film made from such a composition. A laminate or article may be made to include a first layer or sheet that includes such a composition.
1. A laminate comprising:
a first layer; and
a second layer;
wherein the first layer comprises a first thermoplastic composition comprising a polycarbonate;
a polycarbonate-polysiloxane copolymer;
an impact modifier; and
a polyetherimide;
wherein the polycarbonate comprises greater than or equal to about 50% by weight of the combined weights of the polycarbonate, polycarbonate-polysiloxane copolymer, impact modifier and polyetherimide in the first thermoplastic composition;
wherein a 3.2 millimeter thick, 7.6 centimeter square sample of the first thermoplastic composition produces a smoke density (Ds) of less than 275 after a 4-minute burn, measured according to ASTM L 662-03; and wherein a 3.2-mm thick molded NII bar comprising the first thermoplastic composition has a notched Izod impact strength of greater than or equal to about 150 J/m, determined in accordance with ASTM D256-05 (method A) at 23° C., wherein the second layer comprises a second composition different from the composition of the first thermoplastic composition.
2. The laminate of claim 1 , wherein a 3.2 millimeter thick, 7.6 centimeter square sample of the layer comprising the first thermoplastic composition produces a smoke density (Ds) of less than 200 after a 4 minute burn, measured according to ASTM E 662-03.
3. The laminate of claim 1 , wherein a 3.2 millimeter thick, 7.6 centimeter square sample of the layer comprising the first thermoplastic composition produces a smoke density (Ds) of less than 200 after a 4 minute burn and produces a smoke density (Ds) of less than 100 after a 1.5 minute burn, measured according to ASTM L 662-03.
4. An article comprising the laminate of claim 1 wherein the article is produced by molding the laminate into a shaped article.
5. The laminate of claim 1 , wherein a 3.2-mm thick molded NII bar comprising the first thermoplastic composition has a notched Izod impact strength of greater than or equal to about 150 J/m, determined in accordance with ASTM D256-05 (method A) at 0° C.
6. The laminate of claim 1 , wherein the first thermoplastic composition has a melt volume rate (MVR) of about 2.5 cm 3 /10 minutes to about 20 cm 3 /10 minutes, measured at 260° C./2.16 kg in accordance with ASTM D1238-04c (procedure B).
7. The laminate of claim 1 , wherein a flat, 3.2 mm thick molded tensile bar formed from the first thermoplastic composition has a Heat Deflection Test (HDT) temperature of greater than 100° C., determined at 1.82 MPa per ASTM D648-04 (method B).
8. The laminate of claim 1 wherein the first thermoplastic composition comprises a phosphorus-containing flame retardant.
9. The laminate of claim 8 , wherein samples of the first thermoplastic composition configured for testing according to UL94 and having a thickness of 2 millimeters achieve at least a UL94 V1 rating.
10. The laminate of claim 8 , wherein samples of the first thermoplastic composition configured for testing according to UL94 and having a thickness of 2 millimeters achieve at least a UL94 V1 rating with a p(FTP)≧0.85.
11. The laminate of claim 8 wherein samples of the first thermoplastic composition configured for testing according to UL94 5VB and having a thickness of at least 1.5 mm, when subjected to an open flame for 5 second intervals spaced 5 seconds apart, do not drip for at least 55 seconds.
12. The laminate of claim 1 wherein the first thermoplastic composition comprises about 0.5 wt. % to about 10 wt. % phosphorus-containing flame retardant and polycarbonate-polysiloxane copolymer that provides about 2.4 wt. % to about 4 wt. % siloxane, by weight of the combined weights of the polycarbonate, polycarbonate-polysiloxane copolymer, impact modifier, polyetherimide and flame retardant.
13. The laminate of claim 12 wherein the first thermoplastic composition comprises about 0.5 wt. % to about 5 wt. % phosphorus-containing flame retardant and polycarbonate-polysiloxane copolymer that provides about 2.4 wt, % to about 3.5 wt. % siloxane, by weight of the combined weights of the polycarbonate, polycarbonate-polysiloxane copolymer, impact modifier, polyetherimide and flame retardant.
14. The laminate of claim 1 , wherein the first thermoplastic composition further comprises a polyetherimide-polysiloxane copolymer.
15. A laminate comprising:
a first layer; and
a second layer;
wherein the first layer comprises a first thermoplastic composition comprising about 50 wt. % to about 97 wt. % polycarbonate;
about 0.5 wt. % to about 25 wt. % polycarbonate-polysiloxane copolymer;
about 0.5 wt. % to about 20 wt. % impact modifier; and
about 2 wt. % to about 15 wt. % polyetherimide, by weight of the first thermoplastic composition wherein a 3.2-mm thick molded NII bar comprising the first thermoplastic composition has a notched Izod impact strength of greater than or equal to about 150 J/m, determined in accordance with ASTM D256-05 (method A) at 23° C. and wherein the second layer comprises a second composition different from the composition of the first thermoplastic composition.
16. The laminate of claim 15 , wherein the first thermoplastic composition comprises about 0.5 wt. % to about 10 wt, % phosphorous-containing flame retardant, by weight.
17. A method for forming a laminate, comprising co-injecting molding, co-extrusion lamination, co-extrusion blow film molding, co-extrusion, overmolding, multi-shot injection molding, or sheet molding a plurality of layers comprising a first layer that comprises a first thermoplastic composition and a second layer that comprises a second thermoplastic composition, the first layer comprising:
a polycarbonate;
a polycarbonate-polysiloxane copolymer;
an impact modifier; and
a polyetherimide;
wherein the polycarbonate comprises greater than or equal to about 50% by weight of the combined weights of the polycarbonate, polycarbonate-polysiloxane copolymer, impact modifier and polyetherimide in the first thermoplastic composition;
wherein a 3.2 millimeter thick, 7.6 centimeter square sample of the first thermoplastic composition produces a smoke density (Ds) of less than 275 after a 4-minute burn, measured according to ASTM L 662-03; wherein a 3.2-mm thick molded NII bar comprising the first thermoplastic composition has a notched Izod impact strength of greater than or equal to about 150 J/m, determined in accordance with ASTM D256-05 (method A) at 23° C.; and wherein the second thermoplastic composition comprises polycarbonate, polyester, polycarbonate-polyester, polyimide, polyetherimide, polysiloxane, polyetherimide-siloxane, polyimide-polysiloxane, polyimide-polyester, polyetherimide-polyester, polyimide-polycarbonate, polyetherimide-polycarbonate, polyimide-polyacrylate, polyetherimide-polyacrylate, polyimide-fluoropolymer, polyetherimide-fluoropolymer, fiber reinforced polymer, polyurethane foam, fiber reinforced polyurethane, polypropylene, and fiber reinforced polypropylene.